(a) Interpretation: The shift of the equilibrium is to be found when the pressure for the given reaction C 2 H 4 ( g ) + C l 2 ( g ) ⇄ C 2 H 4 C l 2 ( g ) is increased. Concept Introduction: If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium. With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

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Answer 1

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Chapter 6.6, Problem 6.23P

Interpretation Introduction

(a)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is increased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

Interpretation Introduction

(b)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is decreased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

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32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention to your units. A. What is the partition function for this system? B. What are the populations of each level? Now instead, consider a system with energy levels of 0 J mol C. Now what is the partition function? D. And what are the populations of the two levels? E. Finally, repeat the second calculation at 500 K. and 500 J mol 1 at 300 K. F. What do you notice about the populations as you increase the temperature? At what temperature would you expect the states to have equal populations?

30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in class, but the partition function that describes the translational and rotational motion of a homonuclear diatomic molecule is given by Itrans (V,T) = = 2πmkBT h² V grot (T) 4π²IKBT h² Where h is Planck's constant and I is molecular moment of inertia. The overall partition function is qmolec Qtrans qrot. Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a volume of 1 m³. Here is some useful data: Moment of inertia: I2 I 7.46 x 10- 45 kg m² 2 O2 I 1.91 x 101 -46 kg m²

K for each reaction step. Be sure to account for all bond-breaking and bond-making steps. HI HaC Drawing Arrows! H3C OCH3 H 4 59°F Mostly sunny H CH3 HO O CH3 'C' CH3 Select to Add Arrows CH3 1 L H&C. OCH3 H H H H Select to Add Arrows Q Search Problem 30 of 20 H. H3C + :0: H CH3 CH3 20 H2C Undo Reset Done DELL

Answer 2

Question

Chapter 6.6, Problem 6.23P

Interpretation Introduction

(a)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is increased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

Interpretation Introduction

(b)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is decreased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

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Answer 3

Question

Chapter 6.6, Problem 6.23P

Interpretation Introduction

(a)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is increased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

Interpretation Introduction

(b)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is decreased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

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Answer 4

Question

Chapter 6.6, Problem 6.23P

Interpretation Introduction

(a)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is increased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

Interpretation Introduction

(b)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is decreased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

Expert Solution & Answer

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Answer 5

Chapter 6.6, Problem 6.23P

Interpretation Introduction

(a)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is increased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

Interpretation Introduction

(b)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is decreased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

Answer 6

Chapter 6.6, Problem 6.23P

Interpretation Introduction

(a)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is increased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

Answer 7

Chapter 6.6, Problem 6.23P

Interpretation Introduction

(a)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is increased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is decreased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The shift of the equilibrium is to be found when the pressure for the given reaction C2H4(g)+Cl2(g)⇄C2H4Cl2(g) is decreased.

Concept Introduction:

If there is an increase or decrease in the amount of pressure, then the equilibrium will move to a certain side to attain equilibrium.

With the help of Le Chatellier's principle, the effect of change of pressure on equilibrium can be predicted.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 6.1 - Prob. 6.1P Ch. 6.1 - Prob. 6.2P Ch. 6.1 - Prob. 6.3P Ch. 6.1 - Prob. 6.4P Ch. 6.2 - Using the values in Table 6.2, give H for each...Ch. 6.2 - Prob. 6.6P Ch. 6.2 - Answer the following questions using the given...Ch. 6.2 - Given the H and balanced equation in Sample...Ch. 6.2 - Prob. 6.9P Ch. 6.3 - Prob. 6.10P

Solution Summary: The author explains that the equilibrium shifts when the pressure for the given reaction is increased. Le Chatellier's principle predicts the effect of change of pressure on equilibrium.

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