The major product obtained from addition of H B r with the given compounds should be determined. Concept introduction: Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Question

13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)! Google

Answer 1

Question

Chapter 6.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)! Google

Print Last Name, First Name Initial Statifically more chances to abstract one of these 6H 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 4th total • 6H total 래 • 4H total 21 total ZH 2H Statistical H < 3° C-H weakest - product abstraction here bund leads to thermo favored a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? Product 6 Number of Unique Mono-Chlorinated Products Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary H H-Cl Waterfox

10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation → depicted below Use proper curved arrow notation that explicitly illustrates all bonds being broken, and all bonds formed in the transformation. Also, be sure to include all lone pairs and formal charges on all atoms involved in the flow of electrons. CH3O II HA H CH3O-H H ①

Answer 2

Question

Chapter 6.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

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Answer 3

Question

Chapter 6.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Expert Solution & Answer

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Answer 4

Question

Chapter 6.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Expert Solution & Answer

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Answer 5

Chapter 6.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 6

Chapter 6.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 7

Chapter 6.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 8

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 9

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 18

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Ch. 6.1 - Draw the mechanism for the reaction of cyclohexene...Ch. 6.2 - a. How many bond orbitals are avilable for...Ch. 6.2 - Prob. 3P Ch. 6.2 - Prob. 4P Ch. 6.3 - Prob. 5P Ch. 6.4 - Prob. 6P Ch. 6.4 - Prob. 7P Ch. 6.4 - What alkene should be used to synthesize each of...Ch. 6.5 - The pKa of a protonated alcohol is about 2.5, and...Ch. 6.5 - Prob. 10P

Solution Summary: The author explains Markovnikov's Addition Rule: the unsymmetrical alkene reacts with hydrogen halide in a way, where he attacks and bonds to the more substitution position of carbon-carbon

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