The major product obtained from addition of H B r with the given compounds should be determined. Concept introduction: Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Question

(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

Answer 1

Question

Chapter 6.4, Problem 6P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

with full details solution please

Answer 2

Question

Chapter 6.4, Problem 6P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Chapter 6.4, Problem 6P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Chapter 6.4, Problem 6P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 5

Chapter 6.4, Problem 6P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 6

Chapter 6.4, Problem 6P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 7

Chapter 6.4, Problem 6P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 8

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 9

(b)

Interpretation Introduction

Interpretation:

From the given compounds, the compound with high regioselective ability towards addition of HBr should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The major product obtained from addition of HBr with the given compounds should be determined.

Concept introduction:

Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 21

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 22

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 23

Trending nowThis is a popular solution!

Answer 24

Trending nowThis is a popular solution!

Answer 25

Trending nowThis is a popular solution!

Answer 26

Trending now

Answer 27

This is a popular solution!

Answer 28

See solution

Check out sample textbook solution

Answer 29

Ch. 6.1 - Draw the mechanism for the reaction of cyclohexene...Ch. 6.2 - a. How many bond orbitals are avilable for...Ch. 6.2 - Prob. 3P Ch. 6.2 - Prob. 4P Ch. 6.3 - Prob. 5P Ch. 6.4 - Prob. 6P Ch. 6.4 - What alkene should be used to synthesize each of...Ch. 6.4 - Prob. 8P Ch. 6.5 - The pKa of a protonated alcohol is about 2.5, and...Ch. 6.5 - Prob. 10P

Solution Summary: The author explains Markovnikov's Addition Rule: the unsymmetrical alkene reacts with hydrogen halide in a way, where he attacks and bonds to the more substitution position of carbon-carbon

Concept explainers

Videos

Chapter 6 Solutions