Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 6.10, Problem 15P
Interpretation Introduction

Interpretation:

The chemical equation which shows the preparation reaction of octadecyl p-tolunesulfonate from the ethanol and p-tolunesulfonyl chloride is to be written.

Concept Introduction:

The nucleophilic substitution reaction occurs when alcohol reacts with appropriate sulfonyl chloride in the presence of pyridine to yield alkyl sulfonate derivative.

The leaving group is replaced by nucleophile during the nucleophilic substitution reaction.

The oxygen atom in ethanol acts as nucleophile and p-tolunesulfonyl chloride acts as an electrophile.

In nucleophilic substitution reaction nucleophile attacks on the electrophile and formed principal organic compound.

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A. B. b. Now consider the two bicyclic molecules A. and B. Note that A. is a dianion and B. is a neutral molecule. One of these molecules is a highly reactive compound first characterized in frozen noble gas matrices, that self-reacts rapidly at temperatures above liquid nitrogen temperature. The other compound was isolated at room temperature in the early 1960s, and is a stable ligand used in organometallic chemistry. Which molecule is the more stable molecule, and why?
Where are the chiral centers in this molecule? Also is this compound meso yes or no?
PLEASE HELP! URGENT!
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