Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
7th Edition
ISBN: 9780133900811
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Textbook Question
Chapter 6, Problem 6.99MP
Consider the electronic structure of the element bismuth.
(a) The first ionization energy of bismuth is
(b) Write the electron configurations of neutral Bi and the
(c) What are the n and 1 quantum numbers of the electron removed when Bi is ionized to
(d) Would you expect element 115 to have an ionization energy greater than, equal to, or less than that of bismuth? Explain.
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Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 6 Solutions
Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
Ch. 6 - Prob. 6.1PCh. 6 - APPLY 6.2 Which of the following sets of ions are...Ch. 6 - Prob. 6.3PCh. 6 - Conceptual APPLY 6.4 Which of the following...Ch. 6 - Prob. 6.5PCh. 6 - Prob. 6.6ACh. 6 - Prob. 6.7PCh. 6 - Conceptual APPLY 6.8 The figure on the right...Ch. 6 - Prob. 6.9PCh. 6 - Conceptual APPLY 6.10 Which of the indicated three...
Ch. 6 - Prob. 6.11PCh. 6 - Prob. 6.12ACh. 6 - Prob. 6.13PCh. 6 - APPLY 6.14 Calculate the energy of electrostatic...Ch. 6 - Prob. 6.15PCh. 6 - Conceptual APPLY 6.16 One of the following...Ch. 6 - Prob. 6.17PCh. 6 - PROBLEM 6.18 Compare the following two ionic...Ch. 6 - PROBLEM 6.19 An ionic liquid consisting of a bulky...Ch. 6 - Where on the periodic table would you find the...Ch. 6 - Which of the following spheres is likely to...Ch. 6 - Circle the approximate part or parts of the...Ch. 6 - Prob. 6.23CPCh. 6 - This figure represents the successive ionization...Ch. 6 - In the following drawings, red spheres represent...Ch. 6 - Which of the following drawings is more likely to...Ch. 6 - Prob. 6.27CPCh. 6 - Which of the following alkali metal halides has...Ch. 6 - Which of the following alkali metal halides has...Ch. 6 - Three binary compounds are represented on the...Ch. 6 - Given the following values for the formation of...Ch. 6 - What is the difference between a covalent bond and...Ch. 6 - Prob. 6.33SPCh. 6 - What is the difference between a molecule and an...Ch. 6 - Prob. 6.35SPCh. 6 - How many protons and electrons are in each of the...Ch. 6 - What is the identity of the element X in the...Ch. 6 - Prob. 6.38SPCh. 6 - Prob. 6.39SPCh. 6 - Prob. 6.40SPCh. 6 - Prob. 6.41SPCh. 6 - What doubly positive ion has the following...Ch. 6 - Prob. 6.43SPCh. 6 - Prob. 6.44SPCh. 6 - Which element in the transition-metal series Sc...Ch. 6 - Prob. 6.46SPCh. 6 - Prob. 6.47SPCh. 6 - Prob. 6.48SPCh. 6 - Prob. 6.49SPCh. 6 - Prob. 6.50SPCh. 6 - Prob. 6.51SPCh. 6 - Prob. 6.52SPCh. 6 - Prob. 6.53SPCh. 6 - Prob. 6.54SPCh. 6 - Prob. 6.55SPCh. 6 - Prob. 6.56SPCh. 6 - Prob. 6.57SPCh. 6 - Prob. 6.58SPCh. 6 - Prob. 6.59SPCh. 6 - What is the relationship between the electron...Ch. 6 - Prob. 6.61SPCh. 6 - Prob. 6.62SPCh. 6 - Prob. 6.63SPCh. 6 - Prob. 6.64SPCh. 6 - Prob. 6.65SPCh. 6 - Prob. 6.66SPCh. 6 - Prob. 6.67SPCh. 6 - Prob. 6.68SPCh. 6 - Prob. 6.69SPCh. 6 - Prob. 6.70SPCh. 6 - Prob. 6.71SPCh. 6 - Prob. 6.72SPCh. 6 - Prob. 6.73SPCh. 6 - Prob. 6.74SPCh. 6 - Prob. 6.75SPCh. 6 - Find the lattice energy of LiBr(s) in Table 6.3,...Ch. 6 - Prob. 6.77SPCh. 6 - Prob. 6.78SPCh. 6 - Prob. 6.79SPCh. 6 - Prob. 6.80SPCh. 6 - Prob. 6.81SPCh. 6 - Prob. 6.82SPCh. 6 - Prob. 6.83SPCh. 6 - Use the data and the result in Problem 6.78 to...Ch. 6 - Prob. 6.85SPCh. 6 - Prob. 6.86CPCh. 6 - Prob. 6.87CPCh. 6 - Prob. 6.88CPCh. 6 - Prob. 6.89CPCh. 6 - Prob. 6.90CPCh. 6 - Prob. 6.91CPCh. 6 - Prob. 6.92CPCh. 6 - Prob. 6.93CPCh. 6 - Prob. 6.94CPCh. 6 - Prob. 6.95CPCh. 6 - Prob. 6.96CPCh. 6 - Prob. 6.97CPCh. 6 - Prob. 6.98CPCh. 6 - Consider the electronic structure of the element...Ch. 6 - Prob. 6.100MPCh. 6 - Prob. 6.101MP
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