Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
7th Edition
ISBN: 9780133900811
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 6, Problem 6.71SP
Interpretation Introduction
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-Page: 8
nsition metal ions have high-spin aqua complexes except one: [Co(HO)₁]".
What is the d-configuration, oxidation state of the metal in [Co(H:O))"? Name and draw the geometry
of [Co(H2O)]?
b)
Draw energy diagrams showing the splitting of the five d orbitals of Co for the two possible electron
configurations of [Co(H2O)]:
Knowing that A = 16 750 cm and Пl. = 21 000 cm, calculate the configuration energy (.e., balance
or ligand-field stabilization energy and pairing energy) for both low spin and high spin configurations of
[Co(H2O)]. Which configuration seems more stable at this point of the analysis? (Note that 349.76 cm = 1
kJ/mol)
Exchange energy (IT) was not taken into account in part (d), but it plays a role. Assuming exchange
an occur within t29 and within eg (but not between tz, and ea), how many exchanges are possible in the low
in configuration vs in the high spin configuration? What can you say about the importance of exchange energy
07
Draw everything please on a piece of paper explaining each step
Define crystalline, polycrystalline and amorphous materials
What crystal system and Bravais lattices are shown in the figure immediately below? What do a, b,
C, a, ẞ and y represent and what are their values? You can label the Bravais lattices directly above or under the
figure.
C
a
Chapter 6 Solutions
Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
Ch. 6 - Prob. 6.1PCh. 6 - APPLY 6.2 Which of the following sets of ions are...Ch. 6 - Prob. 6.3PCh. 6 - Conceptual APPLY 6.4 Which of the following...Ch. 6 - Prob. 6.5PCh. 6 - Prob. 6.6ACh. 6 - Prob. 6.7PCh. 6 - Conceptual APPLY 6.8 The figure on the right...Ch. 6 - Prob. 6.9PCh. 6 - Conceptual APPLY 6.10 Which of the indicated three...
Ch. 6 - Prob. 6.11PCh. 6 - Prob. 6.12ACh. 6 - Prob. 6.13PCh. 6 - APPLY 6.14 Calculate the energy of electrostatic...Ch. 6 - Prob. 6.15PCh. 6 - Conceptual APPLY 6.16 One of the following...Ch. 6 - Prob. 6.17PCh. 6 - PROBLEM 6.18 Compare the following two ionic...Ch. 6 - PROBLEM 6.19 An ionic liquid consisting of a bulky...Ch. 6 - Where on the periodic table would you find the...Ch. 6 - Which of the following spheres is likely to...Ch. 6 - Circle the approximate part or parts of the...Ch. 6 - Prob. 6.23CPCh. 6 - This figure represents the successive ionization...Ch. 6 - In the following drawings, red spheres represent...Ch. 6 - Which of the following drawings is more likely to...Ch. 6 - Prob. 6.27CPCh. 6 - Which of the following alkali metal halides has...Ch. 6 - Which of the following alkali metal halides has...Ch. 6 - Three binary compounds are represented on the...Ch. 6 - Given the following values for the formation of...Ch. 6 - What is the difference between a covalent bond and...Ch. 6 - Prob. 6.33SPCh. 6 - What is the difference between a molecule and an...Ch. 6 - Prob. 6.35SPCh. 6 - How many protons and electrons are in each of the...Ch. 6 - What is the identity of the element X in the...Ch. 6 - Prob. 6.38SPCh. 6 - Prob. 6.39SPCh. 6 - Prob. 6.40SPCh. 6 - Prob. 6.41SPCh. 6 - What doubly positive ion has the following...Ch. 6 - Prob. 6.43SPCh. 6 - Prob. 6.44SPCh. 6 - Which element in the transition-metal series Sc...Ch. 6 - Prob. 6.46SPCh. 6 - Prob. 6.47SPCh. 6 - Prob. 6.48SPCh. 6 - Prob. 6.49SPCh. 6 - Prob. 6.50SPCh. 6 - Prob. 6.51SPCh. 6 - Prob. 6.52SPCh. 6 - Prob. 6.53SPCh. 6 - Prob. 6.54SPCh. 6 - Prob. 6.55SPCh. 6 - Prob. 6.56SPCh. 6 - Prob. 6.57SPCh. 6 - Prob. 6.58SPCh. 6 - Prob. 6.59SPCh. 6 - What is the relationship between the electron...Ch. 6 - Prob. 6.61SPCh. 6 - Prob. 6.62SPCh. 6 - Prob. 6.63SPCh. 6 - Prob. 6.64SPCh. 6 - Prob. 6.65SPCh. 6 - Prob. 6.66SPCh. 6 - Prob. 6.67SPCh. 6 - Prob. 6.68SPCh. 6 - Prob. 6.69SPCh. 6 - Prob. 6.70SPCh. 6 - Prob. 6.71SPCh. 6 - Prob. 6.72SPCh. 6 - Prob. 6.73SPCh. 6 - Prob. 6.74SPCh. 6 - Prob. 6.75SPCh. 6 - Find the lattice energy of LiBr(s) in Table 6.3,...Ch. 6 - Prob. 6.77SPCh. 6 - Prob. 6.78SPCh. 6 - Prob. 6.79SPCh. 6 - Prob. 6.80SPCh. 6 - Prob. 6.81SPCh. 6 - Prob. 6.82SPCh. 6 - Prob. 6.83SPCh. 6 - Use the data and the result in Problem 6.78 to...Ch. 6 - Prob. 6.85SPCh. 6 - Prob. 6.86CPCh. 6 - Prob. 6.87CPCh. 6 - Prob. 6.88CPCh. 6 - Prob. 6.89CPCh. 6 - Prob. 6.90CPCh. 6 - Prob. 6.91CPCh. 6 - Prob. 6.92CPCh. 6 - Prob. 6.93CPCh. 6 - Prob. 6.94CPCh. 6 - Prob. 6.95CPCh. 6 - Prob. 6.96CPCh. 6 - Prob. 6.97CPCh. 6 - Prob. 6.98CPCh. 6 - Consider the electronic structure of the element...Ch. 6 - Prob. 6.100MPCh. 6 - Prob. 6.101MP
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