Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 6, Problem 6.29AP
Interpretation Introduction

(a)

Interpretation:

The line-and-wedge representation for the given compound is to be drawn.

Concept introduction:

The line-and-wedge representation of an organic molecule is the representation in which bonds are represented in three different ways. The bold bond represents the bond that is projecting outwards the plane. The dash bond represents the bond that is projecting backward the plane. The lines represent the bonds that are in the plane.

Interpretation Introduction

(b)

Interpretation:

The line-and-wedge representation for the given compound is to be drawn.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A carbon atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral carbon atom.

Interpretation Introduction

(c)

Interpretation:

The line-and-wedge representation for the given compound is to be drawn.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also called as asymmetric or stereogenic centers. A carbon atom that does not have four nonequivalent atoms or groups attached to it is known as an achiral carbon atom.

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Question 19 0/2 pts 3 Details You have a mixture of sodium chloride (NaCl) and potassium chloride (KCl) dissolved in water and want to separate out the Cl- ions by precipitating them out using silver ions (Ag+). The chemical equation for the net ionic reaction of NaCl and KCl with silver nitrate, AgNO3, is shown below. Ag+(aq) + Cl(aq) → AgCl(s) The total mass of the NaCl/KCl mixture is 1.299 g. Adding 50.42 mL of 0.381 M solution precipitates out all of the Cl-. What are the masses of NaCl and KCl in the mixture? Atomic masses: g: Mass of NaCl g: Mass of KCL Ag = 107.868 g mol- 1 Cl = 35.453 g mol- 1 K = 39.098 g mol- N = 14.007 g mol−1 Na = 22.99 g mol−1 0 = 15.999 g mol 1 Question Help: ✓ Message instructor Submit Question
Part 1. Draw monomer units of the following products and draw their reaction mechanism (with arrow pushing) Polyester fiber Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol B)pthalic anhydride + anhydrous sodium acetate + glycerol
Identify the missing starting materials/ reagents/ products in the following reactions. Show the stereochemistry clearly in the structures, if any. If there is a major product, draw the structures of the major product with stereochemistry clearly indicated where applicable. Show only the diastereomers (you do not have to draw the pairs of enantiomers). If you believe that multiple products are formed in approximately equal amounts (hence neither is the major product), draw the structures of the products, and show the detailed mechanism of these reactions to justify the formation of the multiple products. If you believe no product is formed, explain why briefly. (6 mark for each, except f and g, which are 10 mark each)
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