Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 6, Problem 60E
Which atom would be expected to have a half-filled 6p subshell?
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 6 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 6 - The light produced by a red neon sign is due to...Ch. 6 - An FM radio station found at 103.1 on the FM dial...Ch. 6 - FM-95, an FM radio station, broadcasts at a...Ch. 6 - A bright violet line occurs at 435.8 nm in the...Ch. 6 - Light with a wavelength of 614.5 nm looks orange....Ch. 6 - Heated lithium atoms emit photons of light with an...Ch. 6 - A photon of light produced by a surgical laser has...Ch. 6 - When rubidium ions are heated to a high...Ch. 6 - The emission spectrum of cesium contains two lines...Ch. 6 - Photons of infrared radiation are responsible for...
Ch. 6 - One of the radiographic devices used in a...Ch. 6 - The eyes of certain reptiles pass a single visual...Ch. 6 - RGB color television and computer displays use...Ch. 6 - Answer the following questions about a Blu-ray...Ch. 6 - What is the threshold frequency for sodium metal...Ch. 6 - Why is the electron in a Bohr hydrogen atom bound...Ch. 6 - What does it mean to say that the energy of the...Ch. 6 - Using the Bohr model, determine the energy, in...Ch. 6 - The electron volt (eV) is a convenient unit of...Ch. 6 - Using the Bohr model, determine the lowest...Ch. 6 - Using the Bohr model, determine the lowest...Ch. 6 - Using the Bohr model, determine the energy of an...Ch. 6 - Using the Bohr model, determine the energy of an...Ch. 6 - How far from the nucleus in angstroms (1 angstrom...Ch. 6 - What is the radius, in angstroms, of the orbital...Ch. 6 - Using the Bohr model, determine the energy in...Ch. 6 - Using the Bohr model, determine the energy in...Ch. 6 - Consider a large number of hydrogen atoms with...Ch. 6 - How are the Bohr model and the Rutherford model of...Ch. 6 - The spectra of hydrogen and of calcium are shown...Ch. 6 - How are the Bohr model and the quantum mechanical...Ch. 6 - What are the allowed values for each of the four...Ch. 6 - Describe the properties of an electron associated...Ch. 6 - Answer the following questions: (a) Without using...Ch. 6 - Identify the subshell in which electrons with the...Ch. 6 - Which of the subshells described in the previous...Ch. 6 - Identify the subshell in which electrons with the...Ch. 6 - Which of the subshells described in the previous...Ch. 6 - Sketch the boundary surface of a dx2y2 and a py...Ch. 6 - Sketch the px and dxz orbitals. Be sure to show...Ch. 6 - Consider the orbitals shown here in outline. (a)...Ch. 6 - State the Heisenberg uncertainty principle....Ch. 6 - How many electrons could be held in the second...Ch. 6 - Which of the following equations describe...Ch. 6 - Write a set of quantum numbers for each of the...Ch. 6 - Read the labels of several commercial products and...Ch. 6 - Read the labels of several commercial products and...Ch. 6 - Using complete subshell notation (not...Ch. 6 - Using complete subshell notation ( 1s22s22p6, and...Ch. 6 - Is 1s22s22p6 the symbol for a macroscopic property...Ch. 6 - What additional information do we need to answer...Ch. 6 - Draw the orbital diagram for the valence shell of...Ch. 6 - Use an orbital diagram to describe the electron...Ch. 6 - Using complete subshell notation ( 1s22s22p6, and...Ch. 6 - Which atom has the electron configuration...Ch. 6 - Which atom has the electron configuration...Ch. 6 - Which ion with a +1 charge has the electron...Ch. 6 - Which of the following atoms contains only three...Ch. 6 - Which of the following has two unpaired electrons?...Ch. 6 - Which atom would be expected to have a half-filled...Ch. 6 - Which atom would be expected to have a half-filled...Ch. 6 - In one area of Australia, the cattle did not...Ch. 6 - Thallium was used as a poison in the Agatha...Ch. 6 - Write the electron configurations for the...Ch. 6 - Cobalt60 and iodine131 are radioactive isotopes...Ch. 6 - Write a set of quantum numbers for each of the...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Atoms of which group in the periodic table have a...Ch. 6 - Atoms of which group in the periodic table have a...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - List the following ions in order of increasing...Ch. 6 - Which atom and/or ion is (are) isoelectronic with...Ch. 6 - Which of the following atoms and ions is (are)...Ch. 6 - Compare both the numbers of protons and electrons...Ch. 6 - Of the five elements Al, Cl, I, Na, Rb, which has...Ch. 6 - Of the five elements Sn, Si, Sb, O, Te, which has...Ch. 6 - The ionic radii of the ions S2, Cl, and K+ are...Ch. 6 - Which main group atom would be expected to have...Ch. 6 - Explain why Al is a member of group 13 rather than...
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