Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 6, Problem 18E
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Lewis Structure, Hybridization & Molecular Geometry
a) Draw the Lewis Structure of the molecules; Label the hybridization of each carbon atom;
Predict the approximate molecular geometry around each carbon atom.
CH3CHO
CH3CN
b) Draw the Lewis Structure of Nitromethane; Predict the approximate molecular geometry
around the nitrogen atom.
CH3NO2
c) Draw the Lewis Structure; Label the hybridization of the boron atom; Predict the
approximate molecular geometry.
BF3
BF4
a. The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3 " is
best described as a hybrid of several contributing resonance forms, two of which
are shown here.
HO
:0:
HO
+
:Ö:
Bicarbonate is crucial for the control of body pH (for example, blood pH
7.4). A more self-indulgent use is in baking soda, where it serves as a
source of CO2 CO2 gas, which gives bread and pastry their fluffy
constituency.
(i) Draw at least one additional resonance form.
=
(ii) Using curved "electron-pushing" arrows, show how these Lewis structures may
be interconverted by movement of electron pairs. (iii) Determine which form or
forms will be the major contributor(s) to the real structure of bicarbonate,
explaining your answer on the basis of the criteria in Section 1-5.
Calibri
11
+
BIL
NAME: Jaylena M
A student is investigating the ctect of volume on pressure during a lab activity. The student uses the
following volumes (mL). 12, 13, 14, 16, 17, 18, 19, 20, 21, 22, 23, 24, 26, 28, 30, 33, 34, 35, 38, 40, 42, 44.
46, and 50. As the volume changed they measured the following pressures (atm) 11.0, 10.5, 10.0, 9.2.
8.5, 78, 75, 7.0, 6.8, 6.5, 6.0, 5.9, 5.5, 5.0, 4.8, 4.5, 4.2, 3.9, 3.8, 3.5, 3.3, 3.2, 3.0, 2.9.
What is the independent variable? Volume Imla
What is the dependent variable? Pressure Jatm
Use the data and make a PROPER data table.
Volume 1mL)
Pressure latm
110
Chapter 6 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 6 - The light produced by a red neon sign is due to...Ch. 6 - An FM radio station found at 103.1 on the FM dial...Ch. 6 - FM-95, an FM radio station, broadcasts at a...Ch. 6 - A bright violet line occurs at 435.8 nm in the...Ch. 6 - Light with a wavelength of 614.5 nm looks orange....Ch. 6 - Heated lithium atoms emit photons of light with an...Ch. 6 - A photon of light produced by a surgical laser has...Ch. 6 - When rubidium ions are heated to a high...Ch. 6 - The emission spectrum of cesium contains two lines...Ch. 6 - Photons of infrared radiation are responsible for...
Ch. 6 - One of the radiographic devices used in a...Ch. 6 - The eyes of certain reptiles pass a single visual...Ch. 6 - RGB color television and computer displays use...Ch. 6 - Answer the following questions about a Blu-ray...Ch. 6 - What is the threshold frequency for sodium metal...Ch. 6 - Why is the electron in a Bohr hydrogen atom bound...Ch. 6 - What does it mean to say that the energy of the...Ch. 6 - Using the Bohr model, determine the energy, in...Ch. 6 - The electron volt (eV) is a convenient unit of...Ch. 6 - Using the Bohr model, determine the lowest...Ch. 6 - Using the Bohr model, determine the lowest...Ch. 6 - Using the Bohr model, determine the energy of an...Ch. 6 - Using the Bohr model, determine the energy of an...Ch. 6 - How far from the nucleus in angstroms (1 angstrom...Ch. 6 - What is the radius, in angstroms, of the orbital...Ch. 6 - Using the Bohr model, determine the energy in...Ch. 6 - Using the Bohr model, determine the energy in...Ch. 6 - Consider a large number of hydrogen atoms with...Ch. 6 - How are the Bohr model and the Rutherford model of...Ch. 6 - The spectra of hydrogen and of calcium are shown...Ch. 6 - How are the Bohr model and the quantum mechanical...Ch. 6 - What are the allowed values for each of the four...Ch. 6 - Describe the properties of an electron associated...Ch. 6 - Answer the following questions: (a) Without using...Ch. 6 - Identify the subshell in which electrons with the...Ch. 6 - Which of the subshells described in the previous...Ch. 6 - Identify the subshell in which electrons with the...Ch. 6 - Which of the subshells described in the previous...Ch. 6 - Sketch the boundary surface of a dx2y2 and a py...Ch. 6 - Sketch the px and dxz orbitals. Be sure to show...Ch. 6 - Consider the orbitals shown here in outline. (a)...Ch. 6 - State the Heisenberg uncertainty principle....Ch. 6 - How many electrons could be held in the second...Ch. 6 - Which of the following equations describe...Ch. 6 - Write a set of quantum numbers for each of the...Ch. 6 - Read the labels of several commercial products and...Ch. 6 - Read the labels of several commercial products and...Ch. 6 - Using complete subshell notation (not...Ch. 6 - Using complete subshell notation ( 1s22s22p6, and...Ch. 6 - Is 1s22s22p6 the symbol for a macroscopic property...Ch. 6 - What additional information do we need to answer...Ch. 6 - Draw the orbital diagram for the valence shell of...Ch. 6 - Use an orbital diagram to describe the electron...Ch. 6 - Using complete subshell notation ( 1s22s22p6, and...Ch. 6 - Which atom has the electron configuration...Ch. 6 - Which atom has the electron configuration...Ch. 6 - Which ion with a +1 charge has the electron...Ch. 6 - Which of the following atoms contains only three...Ch. 6 - Which of the following has two unpaired electrons?...Ch. 6 - Which atom would be expected to have a half-filled...Ch. 6 - Which atom would be expected to have a half-filled...Ch. 6 - In one area of Australia, the cattle did not...Ch. 6 - Thallium was used as a poison in the Agatha...Ch. 6 - Write the electron configurations for the...Ch. 6 - Cobalt60 and iodine131 are radioactive isotopes...Ch. 6 - Write a set of quantum numbers for each of the...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Atoms of which group in the periodic table have a...Ch. 6 - Atoms of which group in the periodic table have a...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - Based on their positions in the periodic table,...Ch. 6 - List the following ions in order of increasing...Ch. 6 - Which atom and/or ion is (are) isoelectronic with...Ch. 6 - Which of the following atoms and ions is (are)...Ch. 6 - Compare both the numbers of protons and electrons...Ch. 6 - Of the five elements Al, Cl, I, Na, Rb, which has...Ch. 6 - Of the five elements Sn, Si, Sb, O, Te, which has...Ch. 6 - The ionic radii of the ions S2, Cl, and K+ are...Ch. 6 - Which main group atom would be expected to have...Ch. 6 - Explain why Al is a member of group 13 rather than...
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