The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules. Concept introduction: Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis . Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement. Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon. Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Question

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Answer 1

Question

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

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Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

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Answer 3

Question

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

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Answer 4

Question

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

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Answer 5

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 6

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 7

Chapter 6, Problem 41PP

(a)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 18

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 19

(g)

Interpretation Introduction

Interpretation:

The rearrangement of carbocation and the curved arrow pattern should be identified for the given molecules.

Concept introduction:

Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it is a vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. This type of carbocation undergoes inter or intra molecule reactions and it form more stable product this type of rearrangement called carbocation rearrangement.

Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.

Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation as shown below.

Answer 20

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Answer 21

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Answer 31

Ch. 6.1 - Prob. 1LTS Ch. 6.1 - Prob. 1PTS Ch. 6.1 - Prob. 2ATS Ch. 6.2 - Prob. 3CC Ch. 6.3 - Prob. 4CC Ch. 6.3 - Prob. 5CC Ch. 6.4 - Prob. 6CC Ch. 6.6 - Prob. 7CC Ch. 6.7 - Prob. 2LTS Ch. 6.7 - Prob. 8PTS

Chapter 6 Solutions