Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134293936
Author: Nivaldo J. Tro
Publisher: PEARSON
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Textbook Question
Chapter 6, Problem 39E
Consider the structure of the amino acid alanine Indicate the hybridization about each interior atom.
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The reaction sequence shown in Scheme 5 demonstrates the synthesis of a
substituted benzene derivative Q.
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NH2
NaNO2, HCI
(apexe) 13× (1
HNO3, H2SO4
C6H5CIN2
0°C
HOTE
CHINO₂
N
O
*O₂H (
PO
Q
Я
Scheme 5
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(i)
Draw the structure of intermediate O.
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(ii) Draw the mechanism for the transformation of aniline N to intermediate O.
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(b)
[6 marks]
(iii) Identify the reagent X used to convert compound O to the iodinated compound
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P.
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(iv) Identify the possible structures of compound Q.
[2 marks]
[2 marks]
[shom 2]
(v)
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Draw the mechanism for the transformation of intermediate P to compound Q.
[5 marks]
vi
(vi) Account for the regiochemical outcome observed in the reaction forming
compound Q.
[3 marks]
PROBLEM 4 Solved
Show how 1-butanol can be converted into the following compounds:
a.
PROBLEM 5+
b.
d.
-C=
N
Which alkene is the major product of this dehydration?
OH
H2SO4
heat
Chapter 6 Solutions
Chemistry: Structure and Properties (2nd Edition)
Ch. 6 - Prob. 1ECh. 6 - What is a chemical bond according to valence bond...Ch. 6 - In valence bond theory, what determines the...Ch. 6 - In valence bond theory, the interaction energy...Ch. 6 - What is hybridization? Why is hybridization...Ch. 6 - How does hybridization of the atomic orbitals in...Ch. 6 - How is the number of hybrid orbitals related to...Ch. 6 - Sketch each hybrid orbital sp sp2 sp3 sp3d sp3d2Ch. 6 - Prob. 9ECh. 6 - Name the hybridization scheme that corresponds to...
Ch. 6 - What is a chemical bond according to molecular...Ch. 6 - Explain the difference between hybrid atomic...Ch. 6 - What is a bonding molecular orbital?Ch. 6 - Prob. 14ECh. 6 - What is the role of wave interference in...Ch. 6 - Prob. 16ECh. 6 - Prob. 17ECh. 6 - Prob. 18ECh. 6 - Prob. 19ECh. 6 - Prob. 20ECh. 6 - Prob. 21ECh. 6 - When applying molecular orbital theory to...Ch. 6 - In molecular orbital theory, what is a nonbonding...Ch. 6 - Write a short paragraph describing chemical...Ch. 6 - The valence electron configurations of several...Ch. 6 - The valence electron configurations of several...Ch. 6 - Draw orbital diagrams (boxes with arrows in them)...Ch. 6 - Draw orbital diagrams (boxes with arrows in them)...Ch. 6 - Prob. 29ECh. 6 - Draw orbital diagrams (boxes with arrows in them)...Ch. 6 - Which hybridization scheme allows the formation of...Ch. 6 - Which hybridization scheme allows the central atom...Ch. 6 - Write a hybridization and bonding scheme for each...Ch. 6 - Write a hybridization and bonding scheme for each...Ch. 6 - Write a hybridization and bonding scheme for each...Ch. 6 - Write a hybridization and bonding scheme for each...Ch. 6 - Write a hybridization and bonding scheme for each...Ch. 6 - Write a hybridization and bonding scheme for each...Ch. 6 - Consider the structure of the amino acid alanine...Ch. 6 - Consider the structure of the amino acid aspartic...Ch. 6 - Sketch the bonding molecular orbital that results...Ch. 6 - Sketch the antibonding molecular orbital that...Ch. 6 - Draw an MO energy diagram and predict the bond...Ch. 6 - Draw an MO energy diagram and predict the bond...Ch. 6 - Sketch the bonding and antibonding molecular...Ch. 6 - Sketch the bonding and antibonding molecular...Ch. 6 - Using the molecular orbital energy ordenng for...Ch. 6 - Using the molecular orbital energy ordering for...Ch. 6 - Apply molecular orbital theory to predict if each...Ch. 6 - Apply molecular orbital theory to predict if each...Ch. 6 - According to MO theory, which molecule or ion has...Ch. 6 - According to MO theory, which molecule or ion has...Ch. 6 - Draw an MO energy diagram for CO. (Use the energy...Ch. 6 - Draw an MO energy diagram for HCI. Predict the...Ch. 6 - For each compound, draw the Lewis structure,...Ch. 6 - For each compound, draw the Lewis structure,...Ch. 6 - Amino acids are biological compounds that link...Ch. 6 - The genetic code is based on four different bases...Ch. 6 - The structure of caffeine, present in coffee and...Ch. 6 - The structure of acetylsalicylic acid (aspirin) is...Ch. 6 - Draw a molecular orbital energy diagram for CIF....Ch. 6 - Draw Lewis structures and MO diagrams for CN+, CN,...Ch. 6 - Bromine can form compounds or ions with any number...Ch. 6 - The compound C3H4 has two double bonds. Describe...Ch. 6 - How many hybrid orbitals do we use to describe...Ch. 6 - Prob. 66ECh. 6 - In VSEPR theory, which uses the Lewis model to...Ch. 6 - The resuts of a molecular orbital calculation for...Ch. 6 - Prob. 69ECh. 6 - cis-2-Butene isomerizes (changes its structure) to...Ch. 6 - The ion CH5 + can form under very special...Ch. 6 - Neither the VSEPR model nor the hybridization...Ch. 6 - Prob. 73ECh. 6 - The most stable forms of the nonmetals in groups...Ch. 6 - Consider the bond energies of three iodine...Ch. 6 - How many atomic orbitals form a set of sp3hybrid...Ch. 6 - Have each group member pick one of these...Ch. 6 - Divide your group into two subgroups. Have one...Ch. 6 - A molecular orbital calculation for Hi results in...Ch. 6 - Determine the hybridization about 0 in CH3OH.Ch. 6 - Determine the hybridization about C in H2CO.Ch. 6 - According to the valance bond theory, which kind...Ch. 6 - Use molecular orbital theory to determine the bond...Ch. 6 - Use molecular orbital theory to predict which...Ch. 6 - Use molecular orbital theory to determine which...Ch. 6 - Which hybridization scheme occurs about nitrogen...Ch. 6 - Prob. 8SAQCh. 6 - Prob. 9SAQCh. 6 - Prob. 10SAQCh. 6 - Which type of orbitals overlap to form the sigma...
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