An energy diagram for the molecular orbitals of period 2 diatomic molecules should be drawn and the difference in ordering for B 2 , C 2 and N 2 should be compared to O 2 , F 2 and Ne 2 . Concept introduction: MOT is more accurate theory than VBT . VBT fails to explain the magnetic behavior and bonding in electron-deficient compound. According to this theory, atomic orbitals combine to form molecular orbitals. The number of the molecular orbital is equal to atomic orbital according to this theory. ( i ) The molecular orbitals are formed by the linear combination of atomic orbitals. There are two type of combination ( a ) constructive ( b ) destructive interference ( ii )Molecular orbitals formed by constructive interference is known as bonding molecular orbital, and its energy is less than atomic orbital ( iii ) Molecular orbital formed by destructive interference is known as anti bonding molecular orbital and its energy is greater than atomic orbital. ( iv ) Electrons in molecular orbitals are filled according to Aufbau’s rule, Pauli’s Exclusion Principle, and Hund’s rule.

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Answer 1

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Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 6, Problem 19E

Interpretation Introduction

Interpretation:

An energy diagram for the molecular orbitals of period 2 diatomic molecules should be drawn and the difference in ordering for B₂, C₂ and N₂ should be compared to O₂, F₂ and Ne₂.

Concept introduction:

MOT is more accurate theory than VBT. VBT fails to explain the magnetic behavior and bonding in electron-deficient compound. According to this theory, atomic orbitals combine to form molecular orbitals. The number of the molecular orbital is equal to atomic orbital according to this theory.

(i) The molecular orbitals are formed by the linear combination of atomic orbitals. There are two type of combination (a) constructive (b) destructive interference

(ii)Molecular orbitals formed by constructive interference is known as bonding molecular orbital, and its energy is less than atomic orbital

(iii) Molecular orbital formed by destructive interference is known as anti bonding molecular orbital and its energy is greater than atomic orbital.

(iv) Electrons in molecular orbitals are filled according to Aufbau’s rule, Pauli’s Exclusion Principle, and Hund’s rule.

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If the viscosity of hydrogen gas (at 0oC and 1 atm) is 8.83x10-5 P. If we assume that the molecular sizes are equal, calculate the viscosity of a gas composed of deuterium.

Answer 2

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 6, Problem 19E

Interpretation Introduction

Interpretation:

An energy diagram for the molecular orbitals of period 2 diatomic molecules should be drawn and the difference in ordering for B₂, C₂ and N₂ should be compared to O₂, F₂ and Ne₂.

Concept introduction:

MOT is more accurate theory than VBT. VBT fails to explain the magnetic behavior and bonding in electron-deficient compound. According to this theory, atomic orbitals combine to form molecular orbitals. The number of the molecular orbital is equal to atomic orbital according to this theory.

(i) The molecular orbitals are formed by the linear combination of atomic orbitals. There are two type of combination (a) constructive (b) destructive interference

(ii)Molecular orbitals formed by constructive interference is known as bonding molecular orbital, and its energy is less than atomic orbital

(iii) Molecular orbital formed by destructive interference is known as anti bonding molecular orbital and its energy is greater than atomic orbital.

(iv) Electrons in molecular orbitals are filled according to Aufbau’s rule, Pauli’s Exclusion Principle, and Hund’s rule.

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Answer 3

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 6, Problem 19E

Interpretation Introduction

Interpretation:

An energy diagram for the molecular orbitals of period 2 diatomic molecules should be drawn and the difference in ordering for B₂, C₂ and N₂ should be compared to O₂, F₂ and Ne₂.

Concept introduction:

MOT is more accurate theory than VBT. VBT fails to explain the magnetic behavior and bonding in electron-deficient compound. According to this theory, atomic orbitals combine to form molecular orbitals. The number of the molecular orbital is equal to atomic orbital according to this theory.

(i) The molecular orbitals are formed by the linear combination of atomic orbitals. There are two type of combination (a) constructive (b) destructive interference

(ii)Molecular orbitals formed by constructive interference is known as bonding molecular orbital, and its energy is less than atomic orbital

(iii) Molecular orbital formed by destructive interference is known as anti bonding molecular orbital and its energy is greater than atomic orbital.

(iv) Electrons in molecular orbitals are filled according to Aufbau’s rule, Pauli’s Exclusion Principle, and Hund’s rule.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 4

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 6, Problem 19E

Interpretation Introduction