Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 6, Problem 34E
If 0.1718 L of a 0.3556-M C3H7OH solution is diluted to a concentration of 0.1222 M, what is the volume of the resulting solution?
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 6 Solutions
Chemistry Atoms First2e
Ch. 6 - What is the total mass (amu) of carbon in each of...Ch. 6 - What is the total mass of hydrogen in each of the...Ch. 6 - Calculate the molecular or formula mass of each of...Ch. 6 - Determine the molecular mass of the following...Ch. 6 - Determine the molecular mass of the following...Ch. 6 - Which molecule has a molecular mass of 28.05 amu?Ch. 6 - What information do we need to determine the...Ch. 6 - Calculate the following to four significant...Ch. 6 - Determine the following to four significant...Ch. 6 - Determine the percent ammonia, NH3, in Co(...
Ch. 6 - Determine the percent water in CuSO45H2O to three...Ch. 6 - Determine the empirical formulas for compounds...Ch. 6 - Determine the empirical formulas for compounds...Ch. 6 - A compound of carbon and hydrogen contains 92.3% C...Ch. 6 - Dichioroethane, a compound that is often used for...Ch. 6 - Determine the empirical and molecular formula for...Ch. 6 - Polymers are large molecules composed of simple...Ch. 6 - A major textile dye manufacturer developed a new...Ch. 6 - Explain what changes and what stays the same when...Ch. 6 - What information do we need to calculate the...Ch. 6 - A 200-mL sample and a 400-mL sample of a solution...Ch. 6 - Determine the molarity for each of the following...Ch. 6 - Determine the molarity of each of the following...Ch. 6 - Consider this question: What is the mass of the...Ch. 6 - Consider this question: What is the mass of solute...Ch. 6 - Calculate the number of moles and the mass of the...Ch. 6 - Calculate the number of moles and the mass of the...Ch. 6 - Consider this question: What is the molarity of...Ch. 6 - Consider this question: What is the molarity of...Ch. 6 - Calculate the molarity of each of the following...Ch. 6 - Calculate the molarity of each of the following...Ch. 6 - There is about 1.0 g of calcium, as Ca2+, in LO L...Ch. 6 - What volume of a 1.00MFe( NO3)3 solution can be...Ch. 6 - If 0.1718 L of a 0.3556-M C3H7OH solution is...Ch. 6 - If 4.12 L of a 0.850 MH3PO4 solution is be diluted...Ch. 6 - What volume of a 0.33MC12H22O11 solution can be...Ch. 6 - What is the concentration of the NaCl solution...Ch. 6 - What is the molarity of the diluted solution when...Ch. 6 - What is the final concentration of the solution...Ch. 6 - A 2.00-L bottle of a solution of concentrated HCl...Ch. 6 - An experiment in a general chemistry laboratory...Ch. 6 - What volume of a 0.20MK2SO4 solution contains 57 g...Ch. 6 - The US Environmental Protection Agency (EPA)...Ch. 6 - Consider this question: What mass of a...Ch. 6 - What mass of a 4.00% NaOH solution by mass...Ch. 6 - What mass of solid NaOH (97.0% NaOH by mass) is...Ch. 6 - What mass of HCl is contained in 45.0 mL of an...Ch. 6 - The hardness of water (hardness count) is usually...Ch. 6 - The hardness of water (hardness count) is usually...Ch. 6 - In Canada and the United Kingdom, devices that...Ch. 6 - A throat spray is 1.40% by mass phenol, C6H5OH, in...Ch. 6 - Copper(I) iodide (CuI) is often added to table...Ch. 6 - A cough syrup contains 5.0% ethyl alcohol, C2H5OH,...Ch. 6 - D5W is a solution used as an intravenous fluid. It...Ch. 6 - Find the molarity of a 40.0% by mass aqueous...
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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