Universe
11th Edition
ISBN: 9781319039448
Author: Robert Geller, Roger Freedman, William J. Kaufmann
Publisher: W. H. Freeman
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Chapter 6, Problem 27Q
To determine
The advantages of using diffraction grating instead of prism in a spectrograph.
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The first-order diffraction maximum is observed at 12.4° for a crystal having
a spacing between planes of atoms of 0.285 nm.
(a) What wavelength x-ray is used to observe this first-order pattern?
nm
(b) How many orders can be observed for this crystal at this
wavelength?
A leli
A crystal sample of bacteriorhodopsin, a light-sensitive protein found in halobacteria that responds to light energy, has crystal planes separated by 0.20 nm If a beam of 10keV x rays illuminates a sample, what angles will give diffraction maxima of the first, second and third order?
Give advantages and disadvantages when using a X-ray Powder Diffraction/Diffractometer (XRD). Give at least 2 each.
Chapter 6 Solutions
Universe
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Ch. 6 - Prob. 11CCCh. 6 - Prob. 1QCh. 6 - Prob. 2QCh. 6 - Prob. 3QCh. 6 - Prob. 4QCh. 6 - Prob. 5QCh. 6 - Prob. 6QCh. 6 - Prob. 7QCh. 6 - Prob. 8QCh. 6 - Prob. 9QCh. 6 - Prob. 10QCh. 6 - Prob. 11QCh. 6 - Prob. 12QCh. 6 - Prob. 13QCh. 6 - Prob. 14QCh. 6 - Prob. 15QCh. 6 - Prob. 16QCh. 6 - Prob. 17QCh. 6 - Prob. 18QCh. 6 - Prob. 19QCh. 6 - Prob. 20QCh. 6 - Prob. 21QCh. 6 - Prob. 22QCh. 6 - Prob. 23QCh. 6 - Prob. 24QCh. 6 - Prob. 25QCh. 6 - Prob. 26QCh. 6 - Prob. 27QCh. 6 - Prob. 28QCh. 6 - Prob. 29QCh. 6 - Prob. 30QCh. 6 - Prob. 31QCh. 6 - Prob. 32QCh. 6 - Prob. 33QCh. 6 - Prob. 34QCh. 6 - Prob. 35QCh. 6 - Prob. 36QCh. 6 - Prob. 37QCh. 6 - Prob. 38QCh. 6 - Prob. 39QCh. 6 - Prob. 40QCh. 6 - Prob. 41QCh. 6 - Prob. 42QCh. 6 - Prob. 43QCh. 6 - Prob. 44QCh. 6 - Prob. 45Q
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- On a certain crystal, a first-order X-ray diffraction maximum is observed at an angle of 27.1° relative to its surface, using an X-ray source of unknown wavelength. Additionally, when illuminated with a different, this time of known wavelength 0.137 nm, a second-order maximum is detected at 37.3°. Determine (a) the spacing between the reflecting planes, and (b) the unknown wavelength.arrow_forwardAn X-ray scattering experiment is performed on a crystal whose atoms form planes separated by 0.440 nm. Using an X-ray source of wavelength 0.548 nm, what is the angle (with respect to the planes in question) at which the experimenter needs to illuminate the crystal in order to observe a first-order maximum?arrow_forwardCrystal lattices can be examined with x rays but not UV. Why?arrow_forward
- The structure of the NaCl crystal forms reflecting planes 0.541 nm apart. What is the smallest angle, measured from these planes, at which X-ray diffraction can be observed, if X-rays of wavelength 0.085 nm are used?arrow_forwardCrystal lattices can be examined with X-rays but not UV. Why?arrow_forwardAs a single crystal is rotated in an x-ray spectrometer (Fig. 3.22a), many parallel planes of atoms besides AA and BB produce strong diffracted beams. Two such planes are shown in Figure P3.38. (a) Determine geometrically the interplanar spacings d1 and d2 in terms of d0. (b) Find the angles (with respect to the surface plane AA) of the n = 1, 2, and 3 intensity maxima from planes with spacing d1. Let = 0.626 and d0 = 4.00 . Note that a given crystal structure (for example, cubic) has interplanar spacings with characteristic ratios, which produce characteristic diffraction patterns. In this way, measurement of the angular position of diffracted x-rays may be used to infer the crystal structure. Figure P3.38 Atomic planes in a cubic lattice.arrow_forward
- A crystal sample of bacteriorhodopsin, a light-sensitive protein found in halobacteria that responds to light energy, has crystal planes separated by 0.20 nm. If a beam of 12keV x rays illuminates a sample, what angles will give diffraction maxima of the first, second and third order? Express your answers in degrees separated by commas in ascending order.arrow_forwardA laser with 589 nm wavelength and a beam diameter of 2 mm is fed through a beam-expander,then aimed from the G.O. Jones building to the Canary Wharf tower at a distance of 2.75 km.What expansion factor is required for the beam-expander in order that the diffraction-limited spotat Canary Wharf tower has a diameter of 30 cm (defined as the diameter of the first dark ring) ?arrow_forwardThe first-order diffraction maximum is observed at 12.6° for a crystal having a spacing between planes of atoms of 0.250 nm. (a) What wavelength x-ray is used to observe this first-order pattern? (b) How many orders can be observed for this crystal at this wavelength?arrow_forward
- A laser with 589 nm wavelength and a beam diameter of 2 mm is fed through a beam-expander, then aimed from the building A to the Building B at a distance of 2.75 km. What expansion factor is required for the beam-expander in order that the diffraction-limited spot at Canary Wharf tower has a diameter of 30 cm (defined as the diameter of the first dark ring) ?arrow_forwardX-rays of wavelength 0.130 nm are reflected from a certain crystal, and the first-order maximum occurs at an angle of 14.2°. What value does this give for the interplanar spacing of the crystal? ____nmarrow_forwardAn X-ray beam of a wavelength 0.15 nm is incident on an NaCl crystal, at 25° to reflecting planes of the crystal. If the first order reflections occurred in the spectrum, find the spacing of the reflecting planes of the crystal. (а) 0.18 pm (b) 0.35 nm (c) 0.18 nm (d) 0.35 pmarrow_forward
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