(a)
Interpretation: The arrow pushing method is to be interpreted for the given transformation.
Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.
Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.
(b)
Interpretation: The arrow pushing method is to be interpreted for the given transformation.
Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.
Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.
(c)
Interpretation: The arrow pushing method is to be interpreted for the given transformation.
Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.
Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.
(d)
Interpretation: The arrow pushing method is to be interpreted for the given transformation.
Concept introduction: The chemical transformation can occur with the hydride shift; methylene shifts or methyl shifts etc.
Each transformation can be shown by the arrow pushing method in which the curved arrows show the movement of electrons or protons. The chemical transformation leads to the formation of intermediates.
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Chapter 6 Solutions
ORGANIC CHEMISTRY LL PRINT UPGRADE
- Indicate the product(s) B and C that are formed in the reaction: HN' OCH HC1 B + mayoritario C minoritario OCH3arrow_forwardIndicate the product(s) that are formed in the reaction: NH-NH, OCH3 -H₂O OCH3arrow_forward21.38 Arrange the molecules in each set in order of increasing acidity (from least acidic to most acidic). OH OH SH NH2 8 NH3 OH (b) OH OH OH (c) & & & CH3 NO2 21.39 Explain the trends in the acidity of phenol and the monofluoro derivatives of phenol. OH OH OH OH PK 10.0 PK 8.81 PK 9.28 PK 9.81arrow_forward
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- 3. Name this compound properly, including stereochemistry. H₂C H3C CH3 OH 4. Show the step(s) necessary to transform the compound on the left into the acid on the right. Bri CH2 5. Write in the product of this LiAlH4 Br H₂C OHarrow_forwardWhat are the major products of the following reaction? Please provide a detailed explanation and a drawing to show how the reaction proceeds.arrow_forwardWhat are the major products of the following enolate alkylation reaction? Please include a detailed explanation as well as a drawing as to how the reaction proceeds.arrow_forward
- A block of zinc has an initial temperature of 94.2 degrees celcius and is immererd in 105 g of water at 21.90 degrees celcius. At thermal equilibrium, the final temperature is 25.20 degrees celcius. What is the mass of the zinc block? Cs(Zn) = 0.390 J/gxdegrees celcius Cs(H2O) = 4.18 J/gx degrees celcusarrow_forwardPotential Energy (kJ) 1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction. AH = -950 kJ AH = 575 kJ (i) Cl₂ (g) + Pt (s) 2C1 (g) + Pt (s) Ea = 1550 kJ (ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s) (iii) Cl (g) + CICO (g) → Cl₂CO (g) Ea = 2240 kJ Ea = 2350 kJ AH = -825 kJ 2600 2400 2200 2000 1800 1600 1400 1200 1000 a. Draw the potential energy diagram for the reaction. Label the data points for clarity. The potential energy of the reactants is 600 kJ 800 600 400 200 0 -200- -400 -600- -800- Reaction Progressarrow_forwardCan u help me figure out the reaction mechanisms for these, idk where to even startarrow_forward
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