Concept explainers
Which of the following choices represents the molar volume of an ideal gas at 25 °C and 1.5 atm?
a.
b.
c.
d.
e.
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General Chemistry: Principles and Modern Applications (11th Edition)
- Consider the following unbalanced chemical equation: ^Sfr) + O2(g) —? Cu2O(s) + SO2(g) What volume of oxygen gas, measured at 27.5 °C and 0.998 atm. is required to react with 25 g of copper!I) sulfide? What volume of sulfur dioxide gas is produced under the same conditions?arrow_forward109 An ore sample with a mass of 670 kg contains 27.7% magnesium carbonate, MgCO3. If all of the magnesium carbonate in this ore sample is decomposed to form carbon dioxide, describe how to determine what volume of CO2 is evolved during the process. What would have to be measured to predict the needed volume in advance?arrow_forward5-37 A sample of a gas at 77°C and 1.33 atm occupies a volume of 50.3 L. (a) How many moles of the gas are present? (b) Does your answer depend on knowing what gas it is?arrow_forward
- Pressures of gases in mixtures are referred to as partial pressures and are additive. 1.00 L of He gas at 0.75 atm is mixed with 2.00 L of Ne gas at 1.5 atm at a temperature of 25.0 C to make a total volume of 3.00 L of a mixture. Assuming no temperature change and that He and Ne can be approximated as ideal gases, what are a the total resulting pressure, b the partial pressures of each component, and c the mole fractions of each gas in the mix?arrow_forwardA 1.000-g sample of an unknown gas at 0C gives the following data: P(atm) V (L) 0.2500 3.1908 0.5000 1.5928 0.7500 1.0601 1.0000 0.7930 Use these data to calculate the value of the molar mass at each of the given pressures from the ideal gas law (we will call this the apparent molar mass at this pressure). Plot the apparent molar masses against pressure and extrapolate to find the molar mass at zero pressure. Because the ideal gas law is most accurate at low pressures, this extrapolation will give an accurate value for the molar mass. What is the accurate molar mass?arrow_forwardWhat is the value of FT for a sample of gas whose volume is 2.97 L and pressure is 0.0553 atm? What could the volume of the gas be if the pressure were increased to 1.00 atm?arrow_forward
- 5-34 A sample of 30.0 mL of krypton gas, Kr, is at 756 mm Hg and 25.0°C. What is the new volume if the pressure is decreased to 325 mm Hg and the temperature is decreased to-12.5°C?arrow_forward5-118 Isooctane, which has a chemical formula C8H18 is the component of gasoline from which the term octane rating derives. (a) Write the balanced chemical equation for the combustion of isooctane. (b) The density of isooctane is 0.792 g/mL. How many kg of C02 are produced each year by the annual U.S. gasoline consumption of L? (c) What is the volume in liters of this CO2 at STP? (d) The chemical formula for isooctane can be represented by (CH3)3CCH2CH(CH3)2. Draw a Lewis structure of isooctane. (e) Another molecule with the same molecular formula is octane, which can be represented by: When comparing isooctane and octane, one structure is observed to have a boiling point of 99°C, while another is known to have a boiling point Of 125°C. Which substance, isooctane or octane, is expected to have the higher boiling point? (f) Determine whether isooctane or octane is expected to have the greater vapor pressure.arrow_forwardPlot the data given in Table 5.3 for oxygen at 0C to obtain an accurate molar mass for O2. To do this, calculate a value of the molar mass at each of the given pressures from the ideal gas law (we will call this the apparent molar mass at this pressure). On a graph show the apparent molar mass versus the pressure and extrapolate to find the molar mass at zero pressure. Because the ideal gas law is most accurate at low pressures, this extrapolation will give an accurate value for the molar mass. What is the accurate molar mass?arrow_forward
- Dichlorine oxide is used as bactericide to purify water. It is produced by the chlorination of sulfur dioxide gas. SO2(g)+2Cl2(g)SOCl2(l)+Cl2O(g)How many liters of Cl2O can be produced by mixing 5.85 L of SO2 and 9.00 L of Cl2? How many liters of the reactant in excess are present after reaction is complete? Assume 100% yield and that all the gases are measured at the same temperature and pressure.arrow_forwardPhosgene is a highly toxic gas made up of carbon, oxygen, and chlorine atoms. Its density at 1.05 atm and 25C is 4.24 g/L. (a) What is the molar mass of phosgene? (b) Phosgene is made up of 12.1% C, 16.2% O, and 71.7% Cl. What is the molecular formula of phosgene?arrow_forwardA cylinder of O2(g) used in breathing by emphysema patients has a volume of 3.00 L at a pressure of 10.0 atm. If the temperature of the cylinder is 28.0 C, what mass of oxygen is in the cylinder?arrow_forward
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