We have noted that atmospheric pressure depends on altitude. Atmospheric pressure as a function of altitude can be calculated with anequation known as the barometric formula: P = P 0 × 10 − M g h / 2.303 R T In this equation, P and P 0 can be in any pressure units, for example, Torr. P 2 is the pressure at sea level, generally taken to be 1.00 atm or isequivalent. The units in the exponential term must be SI units, however. Use the barometric formula to a. estimate the barometric pressure at the top of Mt.Whitney in California (altitude: 14,494 ft; assume a temperature of 10 °C); b. show that barometric pressure decreases by one-thirtieth value for every 900-ft increase in altitude.
We have noted that atmospheric pressure depends on altitude. Atmospheric pressure as a function of altitude can be calculated with anequation known as the barometric formula: P = P 0 × 10 − M g h / 2.303 R T In this equation, P and P 0 can be in any pressure units, for example, Torr. P 2 is the pressure at sea level, generally taken to be 1.00 atm or isequivalent. The units in the exponential term must be SI units, however. Use the barometric formula to a. estimate the barometric pressure at the top of Mt.Whitney in California (altitude: 14,494 ft; assume a temperature of 10 °C); b. show that barometric pressure decreases by one-thirtieth value for every 900-ft increase in altitude.
Solution Summary: The author explains that the barometric pressure at the top of Mt. Whitney in California should be calculated.
We have noted that atmospheric pressure depends on altitude. Atmospheric pressure as a function of altitude can be calculated with anequation known as the barometric formula:
P
=
P
0
×
10
−
M
g
h
/
2.303
R
T
In this equation, P and P0can be in any pressure units, for example, Torr.P2is the pressure at sea level, generally taken to be 1.00 atm or isequivalent. The units in the exponential term must be SI units, however. Use the barometric formula to a. estimate the barometric pressure at the top of Mt.Whitney in California (altitude: 14,494 ft; assume a temperature of 10 °C); b. show that barometric pressure decreases by one-thirtieth value for every 900-ft increase in altitude.
What spectral features allow you to differentiate the product from the starting material?
Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR.
2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too.
3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.
Question 6
What is the major product of the following Diels-Alder reaction?
?
Aldy by day of
A.
H
о
B.
C.
D.
E.
OB
OD
Oc
OE
OA
None
Chapter 6 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
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