Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 5.5, Problem 5.13CE
Interpretation Introduction
Interpretation:
The n value of first shell containing h orbitals has to be determined. Also, the number of h atomic orbitals in that shell has to be determined.
Concept Introduction:
Schrödinger and others found four related sets of numbers that define the shapes of orbitals and the allowed energies of a hydrogen atom; these are called quantum numbers. The four quantum numbers are designated n, l, ml, and ms.
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Chemistry: The Molecular Science
Ch. 5.1 - In the upper atmosphere there is solar radiation...Ch. 5.1 - A fellow chemistry student says that low-frequency...Ch. 5.1 - One type of solar radiation in the upper...Ch. 5.2 - Prob. 5.2PSPCh. 5.2 - Prob. 5.3ECh. 5.3 - Prob. 5.4ECh. 5.3 - Prob. 5.3PSPCh. 5.3 - The hydrogen atom contains only one electron, but...Ch. 5.3 - (a) Calculate the frequency and the wavelength of...Ch. 5.3 - Show that the value of the Rydberg constant per...
Ch. 5.4 - Calculate the de Broglie wavelength of a neutron...Ch. 5.5 - Prob. 5.7ECh. 5.5 - Prob. 5.8ECh. 5.5 - Prob. 5.6PSPCh. 5.5 - Prob. 5.9ECh. 5.5 - Prob. 5.10CECh. 5.5 - Prob. 5.11ECh. 5.5 - Prob. 5.12ECh. 5.5 - Prob. 5.13CECh. 5.7 - Use atomic orbital box diagrams to determine which...Ch. 5.7 - Prob. 5.7PSPCh. 5.7 - Prob. 5.15ECh. 5.7 - Prob. 5.8PSPCh. 5.8 - (a) What Period 3 anion with a 2 charge has the...Ch. 5.8 - Prob. 5.10PSPCh. 5.8 - Fluoride ion, F, has no unpaired electrons....Ch. 5.9 - Prob. 5.11PSPCh. 5.10 - Which of these isoelectronic ions, Ba2+, Cs+, or...Ch. 5.11 - Prob. 5.13PSPCh. 5.13 - Consider these ionic compounds: KCl, CaS, CaO,...Ch. 5 - Prob. 1QRTCh. 5 - Prob. 2QRTCh. 5 - Prob. 3QRTCh. 5 - Prob. 4QRTCh. 5 - Prob. 5QRTCh. 5 - Prob. 6QRTCh. 5 - Prob. 7QRTCh. 5 - Prob. 8QRTCh. 5 -
Write the electron configurations for the valence...Ch. 5 - Prob. 10QRTCh. 5 - Prob. 11QRTCh. 5 - Prob. 12QRTCh. 5 - Prob. 13QRTCh. 5 - The colors of the visible spectrum and the...Ch. 5 - Prob. 15QRTCh. 5 - Prob. 16QRTCh. 5 - Prob. 17QRTCh. 5 - Prob. 18QRTCh. 5 - Prob. 19QRTCh. 5 - Light of very long wavelength strikes a...Ch. 5 - Prob. 21QRTCh. 5 - Prob. 22QRTCh. 5 - Prob. 23QRTCh. 5 - A photoemissive material has a threshold energy,...Ch. 5 - Prob. 25QRTCh. 5 - Prob. 26QRTCh. 5 - Prob. 27QRTCh. 5 - Prob. 28QRTCh. 5 - Prob. 29QRTCh. 5 - Prob. 30QRTCh. 5 - Prob. 31QRTCh. 5 - Calculate the energy and wavelength of the photon...Ch. 5 - Calculate the energy and the wavelength of the...Ch. 5 - Spectroscopists have observed He+ in outer space....Ch. 5 - Prob. 35QRTCh. 5 - Prob. 36QRTCh. 5 - Prob. 37QRTCh. 5 - Prob. 38QRTCh. 5 - Prob. 39QRTCh. 5 - Prob. 40QRTCh. 5 - Prob. 41QRTCh. 5 - Give possible values for all four quantum numbers...Ch. 5 - Prob. 43QRTCh. 5 - Assign a correct set of four quantum numbers for...Ch. 5 - Prob. 45QRTCh. 5 - Prob. 46QRTCh. 5 - Assign a correct set of four quantum numbers for...Ch. 5 - Prob. 48QRTCh. 5 - Prob. 49QRTCh. 5 - Prob. 50QRTCh. 5 - Prob. 51QRTCh. 5 - Prob. 52QRTCh. 5 - Prob. 53QRTCh. 5 - Titanium metal and Cr2+ have the same number of...Ch. 5 - Consider a 2+ ion that has six 3d electrons; which...Ch. 5 - Prob. 56QRTCh. 5 - Prob. 57QRTCh. 5 - Prob. 58QRTCh. 5 - Prob. 59QRTCh. 5 - Prob. 60QRTCh. 5 - Prob. 61QRTCh. 5 - Prob. 62QRTCh. 5 - Prob. 63QRTCh. 5 - Prob. 64QRTCh. 5 - Prob. 65QRTCh. 5 - Prob. 66QRTCh. 5 - Prob. 67QRTCh. 5 - Prob. 68QRTCh. 5 - Prob. 69QRTCh. 5 - Prob. 70QRTCh. 5 - Prob. 71QRTCh. 5 - Prob. 72QRTCh. 5 - Prob. 73QRTCh. 5 - Prob. 74QRTCh. 5 - Prob. 75QRTCh. 5 - Prob. 76QRTCh. 5 - Prob. 77QRTCh. 5 - Prob. 78QRTCh. 5 - Use electron configurations to explain why (a)...Ch. 5 - Prob. 80QRTCh. 5 - Arrange these elements in order of increasing...Ch. 5 - Prob. 82QRTCh. 5 - Arrange these elements in order of increasing...Ch. 5 - Prob. 84QRTCh. 5 - Prob. 85QRTCh. 5 - Prob. 86QRTCh. 5 - Prob. 87QRTCh. 5 - Prob. 88QRTCh. 5 - Prob. 89QRTCh. 5 - Compare the elements B, Al, C, Si. (a) Which has...Ch. 5 - Prob. 91QRTCh. 5 - Prob. 92QRTCh. 5 - Prob. 93QRTCh. 5 - Prob. 94QRTCh. 5 - Determine the lattice energy for LiCl(s) given...Ch. 5 - Prob. 96QRTCh. 5 - Prob. 97QRTCh. 5 - Prob. 98QRTCh. 5 - Prob. 99QRTCh. 5 - Prob. 100QRTCh. 5 - Prob. 101QRTCh. 5 - Prob. 102QRTCh. 5 - Prob. 103QRTCh. 5 - Prob. 104QRTCh. 5 - Prob. 105QRTCh. 5 - Prob. 106QRTCh. 5 - Prob. 107QRTCh. 5 - Prob. 108QRTCh. 5 - Prob. 109QRTCh. 5 - Prob. 113QRTCh. 5 - Prob. 114QRTCh. 5 - Prob. 115QRTCh. 5 - Prob. 116QRTCh. 5 - Prob. 117QRTCh. 5 - Prob. 119QRTCh. 5 - Prob. 120QRTCh. 5 - Prob. 121QRTCh. 5 - Prob. 123QRTCh. 5 - Prob. 124QRTCh. 5 - Prob. 125QRTCh. 5 - Prob. 126QRTCh. 5 - Prob. 127QRTCh. 5 - Prob. 128QRTCh. 5 - Prob. 129QRTCh. 5 - Calculate the effective nuclear charge, Z, on...Ch. 5 - Prob. 131QRTCh. 5 - Prob. 133QRTCh. 5 - Prob. 134QRTCh. 5 - Prob. 135QRTCh. 5 - According to a relationship developed by Niels...Ch. 5 - Prob. 137QRTCh. 5 - Prob. 138QRTCh. 5 - Prob. 139QRTCh. 5 - Prob. 140QRTCh. 5 - Prob. 141QRTCh. 5 - Prob. 142QRTCh. 5 - Prob. 143QRTCh. 5 - Prob. 144QRTCh. 5 - Prob. 5.ACPCh. 5 - Prob. 5.CCP
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- Construct an energy level diagram showing all orbitals for the hydrogen atom up to n=5, labeling each orbital with its appropriate quantum numbers. How many different orbitals are in each shell?arrow_forwardSuppose that the spin quantum number did not exist, and therefore only one electron could occupy each orbital of a many-electron atom. Give the atomic numbers of the first three noble-gas atoms in this case.arrow_forward• identify an orbital (as 1s, 3p, etc.) from its quantum numbers, or vice versa.arrow_forward
- The helium ion He+ is a one-electron system whose wave functions and energy levels are obtained from those for H by changing the atomic number to Z=2 . Calculate the average distance of the electron from the nucleus in the 2s orbital and in the 2p orbital. Compare your results with those in Problem 11 and explain the difference.arrow_forwardPhotoelectron spectroscopy studies have determined the orbital energies for fluorine atoms to be 1s689eV2s34eV2p12eV Estimate the value of Zeff for F in each of these orbitals.arrow_forwardHow is the Bohr theory of the hydrogen atom inconsistent with the uncertainty principle? In fact, it was this inconsistency, along with the theorys limited application to non-hydrogen-like systems, that limited Bohrs theory.arrow_forward
- Some scientists study Rydberg atoms, atoms whose electron has a large value of the n quantum number. Some Rydberg hydrogen atoms may have consequences in interstellar chemistry. Predict the radius of a Rydberg hydrogen atom that has n=100.arrow_forwardWhat experimental evidence supports the quantum theory of light? Explain the wave-particle duality of all matter .. For what size particles must one consider both the wave and the particle properties?arrow_forwardUse the mathematical expression for the 2pz wave function of a one-electron atom (see Table 5.2) to show that the probability of finding an electron in that orbital anywhere in the x-y plane is 0. What are the nodal planes for a dxz orbital and for a dx2y2 orbital?arrow_forward
- In the Stern-Gerlach experiment, silver atoms were used. This was a good choice, as it turned out. Using the electron configuration of silver atoms, explain why silver was a good candidate for being able to observe the intrinsic angular momentum of the electron. Hint: Dont use the aufbau principle to determine the electron configuration of Ag, because its one of the exceptions. Look up the exact electron configuration in a table.arrow_forwardConsider a one-dimensional particle-in-a-box and a three-dimensional particle-in-a-box that have the same dimensions. a What is the ratio of the energies of a particle having the lowest possible quantum numbers in both boxes? b Does this ratio stay the same if the quantum numbers are not the lowest possible values?arrow_forwardIn 1885, Johann Balmer, a mathematician, derived the following relation for the wavelength of lines in the visible spectrum of hydrogen =364.5 n2( n2 4) where in nanometers and n is an integer that can be 3, 4, 5, . . . Show that this relation follows from the Bohr equation and the equation using the Rydberg constant. Note that in the Balmer series, the electron is returning to the n=2 level.arrow_forward
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