Introductory Chemistry: Foundation - Text (Looseleaf)
9th Edition
ISBN: 9781337399623
Author: ZUMDAHL
Publisher: Cengage
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Chapter 5, Problem 8ALQ
Why do we call
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
Google
Print Last Name, First Name Initial
Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
4th total
• 6H total
래
• 4H total
21 total
ZH
2H
Statistical
H < 3° C-H weakest
-
product
abstraction here
bund
leads to thermo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Product
6
Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
II
HA
H
CH3O-H
H
①
Chapter 5 Solutions
Introductory Chemistry: Foundation - Text (Looseleaf)
Ch. 5.2 - Exercise 5.1 Name the following compounds....Ch. 5.2 - Prob. 1CTCh. 5.2 - Exercise 5.2 Give the names of the following...Ch. 5.3 - Exercise 5.3 Name the following compounds....Ch. 5.3 - Exercise 5.4 Name the following compounds....Ch. 5.4 - Exercise 5.5 Name the following binary compounds....Ch. 5.5 - Exercise 5.6 Name each of the following compounds....Ch. 5.5 - Exercise 5.7 Name the following compounds....Ch. 5.7 - Prob. 1CTCh. 5.7 - Prob. 5.8SC
Ch. 5 - In some cases the Roman numeral in a name is the...Ch. 5 - Prob. 2ALQCh. 5 - The formulas MgO and CO look very similar. What is...Ch. 5 - Explain how to use the periodic table to determine...Ch. 5 - Prob. 5ALQCh. 5 - Prob. 6ALQCh. 5 - Name each of the following compounds. SO5 P2S5Ch. 5 - Why do we callBa(NO3)2 barium nitrate hut...Ch. 5 - What is the difference between sulfuric acid and...Ch. 5 - The “Chemistry in Focus” segment Sugar of Lead...Ch. 5 - Prob. 2QAPCh. 5 - Prob. 3QAPCh. 5 - Prob. 4QAPCh. 5 - Prob. 5QAPCh. 5 - Prob. 6QAPCh. 5 - Prob. 7QAPCh. 5 - We indicate the charge of a metallic element that...Ch. 5 - Prob. 9QAPCh. 5 - Prob. 10QAPCh. 5 - Prob. 11QAPCh. 5 - Prob. 12QAPCh. 5 - Prob. 13QAPCh. 5 - Prob. 14QAPCh. 5 - Prob. 15QAPCh. 5 - Prob. 16QAPCh. 5 - Write the name of each of the following binary...Ch. 5 - Write the name for each of the following binary...Ch. 5 - Name each of the following binary compounds, using...Ch. 5 - The formulasNa2O andN2O look very similar. What is...Ch. 5 - Name each of the following binary compounds, using...Ch. 5 - Name each of the following binary compounds, using...Ch. 5 - What is apolyatomicion? Give examples of five...Ch. 5 - Prob. 24QAPCh. 5 - Prob. 25QAPCh. 5 - Prob. 26QAPCh. 5 - Prob. 27QAPCh. 5 - Prob. 28QAPCh. 5 - Prob. 29QAPCh. 5 - Prob. 30QAPCh. 5 - Prob. 31QAPCh. 5 - Prob. 32QAPCh. 5 - Give the name of each of the following polyatomic...Ch. 5 - Prob. 34QAPCh. 5 - Prob. 35QAPCh. 5 - Prob. 36QAPCh. 5 - Give a simple definition of anacid.Ch. 5 - Prob. 38QAPCh. 5 - Prob. 39QAPCh. 5 - Prob. 40QAPCh. 5 - Prob. 41QAPCh. 5 - Prob. 42QAPCh. 5 - Prob. 43QAPCh. 5 - Prob. 44QAPCh. 5 - Prob. 45QAPCh. 5 - Prob. 46QAPCh. 5 - Prob. 47QAPCh. 5 - Prob. 48QAPCh. 5 - Prob. 49QAPCh. 5 - Prob. 50QAPCh. 5 - Prob. 51APCh. 5 - Prob. 52APCh. 5 - Prob. 53APCh. 5 - Prob. 54APCh. 5 - Prob. 55APCh. 5 - Prob. 56APCh. 5 - Name the following compounds. Ca(C2H3O2)2 PCl3...Ch. 5 - Prob. 58APCh. 5 - Prob. 59APCh. 5 - Prob. 60APCh. 5 - Most metallic elements formoxides, and often the...Ch. 5 - Consider a hypothetical simple ionDetermine the...Ch. 5 - Prob. 63APCh. 5 - A metal ion with a 2+ charge has 23 electrons and...Ch. 5 - Prob. 65APCh. 5 - Prob. 66APCh. 5 - The noble metals gold, silver, and platinum are...Ch. 5 - Prob. 68APCh. 5 - The elements of Group 7 (fluorine, chlorine,...Ch. 5 - Prob. 70APCh. 5 - Prob. 71APCh. 5 - An ion with one less electron than it has protons...Ch. 5 - An atom that has lost three electrons will have a...Ch. 5 - An ion with two more electrons than it has protons...Ch. 5 - For each of the negative ions listed in column 1,...Ch. 5 - For each of the following processes that show the...Ch. 5 - For each of the following atomic numbers, use the...Ch. 5 - For the following pairs of ions, use the principle...Ch. 5 - Prob. 79APCh. 5 - Prob. 80APCh. 5 - Prob. 81APCh. 5 - Prob. 82APCh. 5 - Prob. 83APCh. 5 - Name each of the following compounds....Ch. 5 - Prob. 85APCh. 5 - Prob. 86APCh. 5 - Write the foḿu1a for each of the following...Ch. 5 - Give the name of each of the following polyatomic...Ch. 5 - Prob. 89APCh. 5 - Prob. 90APCh. 5 - Prob. 91APCh. 5 - Prob. 92APCh. 5 - Prob. 93APCh. 5 - Complete the following table to predict whether...Ch. 5 - Prob. 95CPCh. 5 - Prob. 96CPCh. 5 - Prob. 97CPCh. 5 - Prob. 98CPCh. 5 - Prob. 1CRCh. 5 - Prob. 2CRCh. 5 - Prob. 3CRCh. 5 - Without consulting your textbook or notes, state...Ch. 5 - Prob. 5CRCh. 5 - What is meant by anuclear atom? Describe the...Ch. 5 - Prob. 7CRCh. 5 - Prob. 8CRCh. 5 - Prob. 9CRCh. 5 - Are most elements found in nature in the elemental...Ch. 5 - What are bus? How are ions formed from atoms? Do...Ch. 5 - Prob. 12CRCh. 5 - Prob. 13CRCh. 5 - Prob. 14CRCh. 5 - Prob. 15CRCh. 5 - Prob. 16CRCh. 5 - Prob. 17CRCh. 5 - Prob. 18CRCh. 5 - Prob. 19CRCh. 5 - Prob. 20CRCh. 5 - Prob. 21CRCh. 5 - How many electrons, protons, and neutrons are...Ch. 5 - What simple ion does each of the following...Ch. 5 - Prob. 24CRCh. 5 - Prob. 25CRCh. 5 - Prob. 26CRCh. 5 - Prob. 27CRCh. 5 - Prob. 28CRCh. 5 - Prob. 29CRCh. 5 - Prob. 30CRCh. 5 - Prob. 31CR
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