Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 5, Problem 77E
Interpretation Introduction
Interpretation:Two distinct changes that can help accomplish conditions of reduced volume in second container have to be stated and manner these adjustments can be achieved should be explained.
Concept introduction: Kinetic molecular theory abbreviated as KMT is foundational model that describes properties of gases. Postulates of KMT are listed as follows:
- Molecules of gas are very tiny entities situated far away each other.
- Rapid random movement allows gas particles to move freely in all directions.
- Effective pressure of gas is obtained from resultant of collisions each particle performs with each other and also with walls of container.
- Gas particles do not undergo any significant interaction when they collide.
- Since no loss of kinetic energy is observed and hence collisions are regarded to be perfectly elastic.
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.
The reaction of solid dimethylhydrazine, (CH3)2N2H2, and liquefied dinitrogen tetroxide, N2O4, has been investigated for use as rocket fuel. The reaction produces the gases carbon dioxide (CO2), nitrogen (N2), and water vapor (H2O), which are ejected in the exhaust gases. In a controlled experiment, solid dimethylhydrazine was reacted with excess dinitrogen tetroxide, and the gases were collected in a closed balloon until a pressure of 2.50 atm and a temperature of 400.0 K were reached.(a) What are the partial pressures of CO2, N2, and H2O?(b) When the CO2 is removed by chemical reaction, what are the partial pressures of the remaining gases?
One liter of chlorine gas at 1 atm and 298 K reacts completely with 1.00 L of nitrogen gas and 2.00 L of oxygen gas at the same temperature and pressure. A single gaseous product is formed, which fills a 2.00 L flask at 1.00 atm and 298 K. Use this information to determine the following characteristics of the product:(a) its empirical formula;(b) its molecular formula;(c) the most favorable Lewis formula based on formal charge arguments (the central atom is N);(d) the shape of the molecule.
Chapter 5 Solutions
Chemical Principles
Ch. 5 - Consider the following apparatus: a test tube...Ch. 5 - Prob. 2DQCh. 5 - Prob. 3DQCh. 5 - Prob. 4DQCh. 5 - Prob. 5DQCh. 5 - Prob. 6DQCh. 5 - Prob. 7DQCh. 5 - Prob. 8DQCh. 5 - Prob. 9DQCh. 5 - Prob. 10DQ
Ch. 5 - Prob. 11DQCh. 5 - Prob. 12DQCh. 5 - Prob. 13DQCh. 5 - Prob. 14DQCh. 5 - Prob. 15DQCh. 5 - Prob. 16DQCh. 5 - Prob. 17DQCh. 5 - For each of the quantities (af) listed below,...Ch. 5 - Prob. 19DQCh. 5 - Prob. 20DQCh. 5 - A sealed-tube manometer as shown below can be...Ch. 5 - A diagram for an open-tube manometer is shown...Ch. 5 - Prob. 23ECh. 5 - Prob. 24ECh. 5 - A gauge on a compressed gas cylinder reads 2200...Ch. 5 - Prob. 26ECh. 5 - Prob. 27ECh. 5 - Prob. 28ECh. 5 - Prob. 29ECh. 5 - Prob. 30ECh. 5 - A mixture of 1.00 g H2 and 1.00 g He is placed in...Ch. 5 - Prob. 32ECh. 5 - Prob. 33ECh. 5 - Prob. 34ECh. 5 - A piece of solid carbon dioxide, with a mass of...Ch. 5 - Prob. 36ECh. 5 - Suppose two 200.0-L tanks are to be filled...Ch. 5 - Prob. 38ECh. 5 - Prob. 39ECh. 5 - Prob. 40ECh. 5 - Prob. 41ECh. 5 - Prob. 42ECh. 5 - Prob. 43ECh. 5 - Prob. 44ECh. 5 - Prob. 45ECh. 5 - A sample of nitrogen gas was collected over water...Ch. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - A 1.00-L gas sample at 100.°C and 600. torr...Ch. 5 - Prob. 51ECh. 5 - Given that a sample of air is made up of nitrogen,...Ch. 5 - Prob. 53ECh. 5 - Prob. 54ECh. 5 - A compound contains only nitrogen and hydrogen and...Ch. 5 - A compound has the empirical formula CHCl. A...Ch. 5 - One of the chemical controversies of the...Ch. 5 - Discrepancies in the experimental values of the...Ch. 5 - A sample of methane (CH4) gas contains a small...Ch. 5 - Prob. 60ECh. 5 - Prob. 61ECh. 5 - Urea (H2NCONH2) is used extensively as a...Ch. 5 - Methanol (CH3OH) can be produced by the...Ch. 5 - Consider the reaction between 50.0 mL of liquid...Ch. 5 - Some very effective rocket fuels are composed of...Ch. 5 - Air bags are activated when a severe impact causes...Ch. 5 - Prob. 67ECh. 5 - Prob. 68ECh. 5 - Prob. 69ECh. 5 - Xenon and fluorine will react to form binary...Ch. 5 - The nitrogen content of organic compounds can be...Ch. 5 - Prob. 72ECh. 5 - Prob. 73ECh. 5 - Consider the following balanced equation in which...Ch. 5 - Prob. 75ECh. 5 - Prob. 76ECh. 5 - Prob. 77ECh. 5 - Prob. 78ECh. 5 - Prob. 79ECh. 5 - Prob. 80ECh. 5 - Calculate the average kinetic energies of the...Ch. 5 - Prob. 82ECh. 5 - Prob. 83ECh. 5 - Prob. 84ECh. 5 - Prob. 85ECh. 5 - Prob. 86ECh. 5 - Prob. 87ECh. 5 - One way of separating oxygen isotopes is by...Ch. 5 - A compound contains only C, H, and N. It is 58.51%...Ch. 5 - Prob. 90ECh. 5 - Prob. 91ECh. 5 - Prob. 92ECh. 5 - Why do real gases not always behave ideally?...Ch. 5 - Prob. 94ECh. 5 - Prob. 95ECh. 5 - Without looking at tables of values, which of the...Ch. 5 - Prob. 97ECh. 5 - Prob. 98ECh. 5 - Prob. 99ECh. 5 - Prob. 100ECh. 5 - Prob. 101ECh. 5 - Prob. 102ECh. 5 - Consider separate 1.0-L samples of O2(g) and...Ch. 5 - Consider separate 1.00-L samples of Ar(g), both...Ch. 5 - Calculate the intermolecular collision frequency...Ch. 5 - Prob. 106ECh. 5 - Prob. 107ECh. 5 - Prob. 108ECh. 5 - Prob. 109ECh. 5 - Prob. 110ECh. 5 - Prob. 111ECh. 5 - Prob. 112AECh. 5 - Prob. 113AECh. 5 - Prob. 114AECh. 5 - Prob. 115AECh. 5 - Prob. 116AECh. 5 - Prob. 117AECh. 5 - Prob. 118AECh. 5 - A 2.747-g sample of manganese metal is reacted...Ch. 5 - Prob. 120AECh. 5 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2...Ch. 5 - Prob. 122AECh. 5 - Prob. 123AECh. 5 - Prob. 124AECh. 5 - Prob. 125AECh. 5 - Prob. 126AECh. 5 - Prob. 127AECh. 5 - Prob. 128AECh. 5 - Prob. 129AECh. 5 - Prob. 130AECh. 5 - Prob. 131AECh. 5 - Prob. 132AECh. 5 - Prob. 133AECh. 5 - Prob. 134AECh. 5 - Prob. 135AECh. 5 - Prob. 136AECh. 5 - Prob. 137AECh. 5 - Prob. 138AECh. 5 - Prob. 139AECh. 5 - Prob. 140AECh. 5 - Prob. 141AECh. 5 - Prob. 142AECh. 5 - Prob. 143AECh. 5 - Prob. 144AECh. 5 - Prob. 145AECh. 5 - Prob. 146CPCh. 5 - A 16.0-g sample of methane (CH4) reacts with 64.0...Ch. 5 - You have two samples of helium gas at the same...Ch. 5 - Prob. 149CPCh. 5 - Prob. 150CPCh. 5 - Prob. 151CPCh. 5 - Prob. 152CPCh. 5 - The density of a pure gaseous compound was...Ch. 5 - Prob. 154CPCh. 5 - The most probable velocity ump is the velocity...Ch. 5 - Derive Dalton’s law of partial pressures from the...Ch. 5 - One of the assumptions of the kinetic molecular...Ch. 5 - Prob. 158CPCh. 5 - A steel cylinder contains 5.00 moles of graphite...Ch. 5 - Prob. 160CPCh. 5 - Prob. 161CPCh. 5 - Prob. 162CPCh. 5 - Calculate the number of stages needed to change...Ch. 5 - Prob. 164CPCh. 5 - You have a helium balloon at 1.00 atm and 25°C....Ch. 5 - Prob. 166CPCh. 5 - Prob. 167MP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- How does the square root mean square velocity of gas molecules vary with temperature? Illustrate this relationship by plotting the square root mean square velocity of N2 molecules as a function of temperature from T=100 K to T=300 K.arrow_forwardDraw product B, indicating what type of reaction occurs. F3C CF3 NH2 Me O .N. + B OMearrow_forwardBenzimidazole E. State its formula. sState the differences in the formula with other benzimidazoles.arrow_forward
- Draw product A, indicating what type of reaction occurs. F3C CN CF3 K2CO3, DMSO, H₂O2 Aarrow_forward19) Which metal is most commonly used in galvanization to protect steel structures from oxidation? Lead a. b. Tin C. Nickel d. Zinc 20) The following molecule is an example of a: R₁ R2- -N-R3 a. Secondary amine b. Secondary amide c. Tertiary amine d. Tertiary amidearrow_forwardpls helparrow_forward
- pls helparrow_forward35) Complete the following equation by drawing the line the structure of the products that are formed. Please note that in some cases more than one product is possible. You must draw all possible products to recive full marks! a. ethanol + 2-propanol + H2SO4 → b. OH conc. H2SO4 CH2 H3C CH + K2Cr2O7 C. d. H3C A pressure CH3 + H2 CH Pt catalystarrow_forward21) The rate of reaction depends upon: a. the concentration and nature of reactants b. the temperature of the reaction C. whether or not a catalyst was used d. all of the above 22) A Maxwell-Boltzmann curve shows the distribution of molecular energies in a reaction system. When the temperature in this system is increased, the peak is a. higher and further to the right. b. higher and further to the left. c. lower and further to the right. d. lower and further to the left. 23) Which of the following correctly describes the reaction represented by the reaction below? CaCO3 (s) + energy → CaO (s) + CO2 (g) a. It is exothermic and the potential energy is greater in the reactants than the products. b. c. It is exothermic and the potential energy is greater in the products than the reactants. It is endothermic and the potential energy is greater in the products than the reactants. d. It is endothermic and the potential energy is equal for the products and reactants.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningWorld of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co

Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning

World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning

Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning

General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning

Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning