Chemical Principles
Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
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Chapter 5, Problem 154CP
Interpretation Introduction

Interpretation:Ratio of temperatures for two samples of He and UF6 that produce same collision frequency with vessel walls is to be determined.

Concept introduction:Anything that has mass and accommodates some space is called matter. Three common states of matter are solids, liquids and gases. Gas is state of matter that neither has specific shape and volume. It can take up volume of container in which it is kept. Negligible intermolecular forces arise between molecules of gases. Gas molecules undergo collisions with each other and also with container walls.

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4) A 8.15 g sample containing hydrogen peroxide (H2O2) decomposes to form water and oxygen. Thetemperature and pressures conditions in the lab were 21.2oC and 761.4 torr, respectively. The oxygengas is collected over a sample of water at 21.2oC; the vapor pressure of water at that temperature is18.9 torr. When the water level inside and outside of the tube is equal the volume of of gas is recordedas 176.23 mL.a) Write and balance the equation for the decomposition reaction b) What is the partial pressure of the oxygen gas? c) Assuming no deviation from ideality, how many moles of oxygen gas were produced? d) What was the mass of hydrogen peroxide that reacted? e) What is the percent by mass of the hydrogen peroxide from the original sample?
8. For the reaction 2H₂O(1) + 2e¯ → H₂(g) + 2OH(aq), calculate the volume of "dry" hydrogen gas created at a pressure of 745 mm Hg and 25.0 °C when 0.6696 g H₂O are used. The vapor pressure of water at this temperature is 23.8 mmHg. A) 0.479 L B) 0.464 L C) 0.450 L D) 4.18 L E) 4.05 L
12. A sample of solid potassium chlorate was heated in a test tube and decomposed into potassium chloride and oxygen gas.  The oxygen produced was collected by displacement of water at 22ºC at a total pressure of 754 torr.  The volume of the gas collected was 0.650 L, and the vapor pressure of water at 22ºC is 21 torr. Calculate the partial pressure of O2 in the gas collected and the mass of potassium chlorate in the sample that was decomposed. (2.13 g)

Chapter 5 Solutions

Chemical Principles

Ch. 5 - Prob. 11DQCh. 5 - Prob. 12DQCh. 5 - Prob. 13DQCh. 5 - Prob. 14DQCh. 5 - Prob. 15DQCh. 5 - Prob. 16DQCh. 5 - Prob. 17DQCh. 5 - For each of the quantities (af) listed below,...Ch. 5 - Prob. 19DQCh. 5 - Prob. 20DQCh. 5 - A sealed-tube manometer as shown below can be...Ch. 5 - A diagram for an open-tube manometer is shown...Ch. 5 - Prob. 23ECh. 5 - Prob. 24ECh. 5 - A gauge on a compressed gas cylinder reads 2200...Ch. 5 - Prob. 26ECh. 5 - Prob. 27ECh. 5 - Prob. 28ECh. 5 - Prob. 29ECh. 5 - Prob. 30ECh. 5 - A mixture of 1.00 g H2 and 1.00 g He is placed in...Ch. 5 - Prob. 32ECh. 5 - Prob. 33ECh. 5 - Prob. 34ECh. 5 - A piece of solid carbon dioxide, with a mass of...Ch. 5 - Prob. 36ECh. 5 - Suppose two 200.0-L tanks are to be filled...Ch. 5 - Prob. 38ECh. 5 - Prob. 39ECh. 5 - Prob. 40ECh. 5 - Prob. 41ECh. 5 - Prob. 42ECh. 5 - Prob. 43ECh. 5 - Prob. 44ECh. 5 - Prob. 45ECh. 5 - A sample of nitrogen gas was collected over water...Ch. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - A 1.00-L gas sample at 100.°C and 600. torr...Ch. 5 - Prob. 51ECh. 5 - Given that a sample of air is made up of nitrogen,...Ch. 5 - Prob. 53ECh. 5 - Prob. 54ECh. 5 - A compound contains only nitrogen and hydrogen and...Ch. 5 - A compound has the empirical formula CHCl. A...Ch. 5 - One of the chemical controversies of the...Ch. 5 - Discrepancies in the experimental values of the...Ch. 5 - A sample of methane (CH4) gas contains a small...Ch. 5 - Prob. 60ECh. 5 - Prob. 61ECh. 5 - Urea (H2NCONH2) is used extensively as a...Ch. 5 - Methanol (CH3OH) can be produced by the...Ch. 5 - Consider the reaction between 50.0 mL of liquid...Ch. 5 - Some very effective rocket fuels are composed of...Ch. 5 - Air bags are activated when a severe impact causes...Ch. 5 - Prob. 67ECh. 5 - Prob. 68ECh. 5 - Prob. 69ECh. 5 - Xenon and fluorine will react to form binary...Ch. 5 - The nitrogen content of organic compounds can be...Ch. 5 - Prob. 72ECh. 5 - Prob. 73ECh. 5 - Consider the following balanced equation in which...Ch. 5 - Prob. 75ECh. 5 - Prob. 76ECh. 5 - Prob. 77ECh. 5 - Prob. 78ECh. 5 - Prob. 79ECh. 5 - Prob. 80ECh. 5 - Calculate the average kinetic energies of the...Ch. 5 - Prob. 82ECh. 5 - Prob. 83ECh. 5 - Prob. 84ECh. 5 - Prob. 85ECh. 5 - Prob. 86ECh. 5 - Prob. 87ECh. 5 - One way of separating oxygen isotopes is by...Ch. 5 - A compound contains only C, H, and N. It is 58.51%...Ch. 5 - Prob. 90ECh. 5 - Prob. 91ECh. 5 - Prob. 92ECh. 5 - Why do real gases not always behave ideally?...Ch. 5 - Prob. 94ECh. 5 - Prob. 95ECh. 5 - Without looking at tables of values, which of the...Ch. 5 - Prob. 97ECh. 5 - Prob. 98ECh. 5 - Prob. 99ECh. 5 - Prob. 100ECh. 5 - Prob. 101ECh. 5 - Prob. 102ECh. 5 - Consider separate 1.0-L samples of O2(g) and...Ch. 5 - Consider separate 1.00-L samples of Ar(g), both...Ch. 5 - Calculate the intermolecular collision frequency...Ch. 5 - Prob. 106ECh. 5 - Prob. 107ECh. 5 - Prob. 108ECh. 5 - Prob. 109ECh. 5 - Prob. 110ECh. 5 - Prob. 111ECh. 5 - Prob. 112AECh. 5 - Prob. 113AECh. 5 - Prob. 114AECh. 5 - Prob. 115AECh. 5 - Prob. 116AECh. 5 - Prob. 117AECh. 5 - Prob. 118AECh. 5 - A 2.747-g sample of manganese metal is reacted...Ch. 5 - Prob. 120AECh. 5 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2...Ch. 5 - Prob. 122AECh. 5 - Prob. 123AECh. 5 - Prob. 124AECh. 5 - Prob. 125AECh. 5 - Prob. 126AECh. 5 - Prob. 127AECh. 5 - Prob. 128AECh. 5 - Prob. 129AECh. 5 - Prob. 130AECh. 5 - Prob. 131AECh. 5 - Prob. 132AECh. 5 - Prob. 133AECh. 5 - Prob. 134AECh. 5 - Prob. 135AECh. 5 - Prob. 136AECh. 5 - Prob. 137AECh. 5 - Prob. 138AECh. 5 - Prob. 139AECh. 5 - Prob. 140AECh. 5 - Prob. 141AECh. 5 - Prob. 142AECh. 5 - Prob. 143AECh. 5 - Prob. 144AECh. 5 - Prob. 145AECh. 5 - Prob. 146CPCh. 5 - A 16.0-g sample of methane (CH4) reacts with 64.0...Ch. 5 - You have two samples of helium gas at the same...Ch. 5 - Prob. 149CPCh. 5 - Prob. 150CPCh. 5 - Prob. 151CPCh. 5 - Prob. 152CPCh. 5 - The density of a pure gaseous compound was...Ch. 5 - Prob. 154CPCh. 5 - The most probable velocity ump is the velocity...Ch. 5 - Derive Dalton’s law of partial pressures from the...Ch. 5 - One of the assumptions of the kinetic molecular...Ch. 5 - Prob. 158CPCh. 5 - A steel cylinder contains 5.00 moles of graphite...Ch. 5 - Prob. 160CPCh. 5 - Prob. 161CPCh. 5 - Prob. 162CPCh. 5 - Calculate the number of stages needed to change...Ch. 5 - Prob. 164CPCh. 5 - You have a helium balloon at 1.00 atm and 25°C....Ch. 5 - Prob. 166CPCh. 5 - Prob. 167MP
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