Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
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Chapter 5, Problem 53E
Interpretation Introduction
Interpretation:Pressure and density of helium gas that is added to two different containers, with one rigid and one flexible container should be predicted.
Concept introduction:The formula to calculate density is as follows:
The mathematical relation between volume and temperature as per the Charles law are as follows:
Where,
Thus it can be concluded that increases in temperature increase volume and vice versa.
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An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.
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Chapter 5 Solutions
Chemical Principles
Ch. 5 - Consider the following apparatus: a test tube...Ch. 5 - Prob. 2DQCh. 5 - Prob. 3DQCh. 5 - Prob. 4DQCh. 5 - Prob. 5DQCh. 5 - Prob. 6DQCh. 5 - Prob. 7DQCh. 5 - Prob. 8DQCh. 5 - Prob. 9DQCh. 5 - Prob. 10DQ
Ch. 5 - Prob. 11DQCh. 5 - Prob. 12DQCh. 5 - Prob. 13DQCh. 5 - Prob. 14DQCh. 5 - Prob. 15DQCh. 5 - Prob. 16DQCh. 5 - Prob. 17DQCh. 5 - For each of the quantities (af) listed below,...Ch. 5 - Prob. 19DQCh. 5 - Prob. 20DQCh. 5 - A sealed-tube manometer as shown below can be...Ch. 5 - A diagram for an open-tube manometer is shown...Ch. 5 - Prob. 23ECh. 5 - Prob. 24ECh. 5 - A gauge on a compressed gas cylinder reads 2200...Ch. 5 - Prob. 26ECh. 5 - Prob. 27ECh. 5 - Prob. 28ECh. 5 - Prob. 29ECh. 5 - Prob. 30ECh. 5 - A mixture of 1.00 g H2 and 1.00 g He is placed in...Ch. 5 - Prob. 32ECh. 5 - Prob. 33ECh. 5 - Prob. 34ECh. 5 - A piece of solid carbon dioxide, with a mass of...Ch. 5 - Prob. 36ECh. 5 - Suppose two 200.0-L tanks are to be filled...Ch. 5 - Prob. 38ECh. 5 - Prob. 39ECh. 5 - Prob. 40ECh. 5 - Prob. 41ECh. 5 - Prob. 42ECh. 5 - Prob. 43ECh. 5 - Prob. 44ECh. 5 - Prob. 45ECh. 5 - A sample of nitrogen gas was collected over water...Ch. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - A 1.00-L gas sample at 100.°C and 600. torr...Ch. 5 - Prob. 51ECh. 5 - Given that a sample of air is made up of nitrogen,...Ch. 5 - Prob. 53ECh. 5 - Prob. 54ECh. 5 - A compound contains only nitrogen and hydrogen and...Ch. 5 - A compound has the empirical formula CHCl. A...Ch. 5 - One of the chemical controversies of the...Ch. 5 - Discrepancies in the experimental values of the...Ch. 5 - A sample of methane (CH4) gas contains a small...Ch. 5 - Prob. 60ECh. 5 - Prob. 61ECh. 5 - Urea (H2NCONH2) is used extensively as a...Ch. 5 - Methanol (CH3OH) can be produced by the...Ch. 5 - Consider the reaction between 50.0 mL of liquid...Ch. 5 - Some very effective rocket fuels are composed of...Ch. 5 - Air bags are activated when a severe impact causes...Ch. 5 - Prob. 67ECh. 5 - Prob. 68ECh. 5 - Prob. 69ECh. 5 - Xenon and fluorine will react to form binary...Ch. 5 - The nitrogen content of organic compounds can be...Ch. 5 - Prob. 72ECh. 5 - Prob. 73ECh. 5 - Consider the following balanced equation in which...Ch. 5 - Prob. 75ECh. 5 - Prob. 76ECh. 5 - Prob. 77ECh. 5 - Prob. 78ECh. 5 - Prob. 79ECh. 5 - Prob. 80ECh. 5 - Calculate the average kinetic energies of the...Ch. 5 - Prob. 82ECh. 5 - Prob. 83ECh. 5 - Prob. 84ECh. 5 - Prob. 85ECh. 5 - Prob. 86ECh. 5 - Prob. 87ECh. 5 - One way of separating oxygen isotopes is by...Ch. 5 - A compound contains only C, H, and N. It is 58.51%...Ch. 5 - Prob. 90ECh. 5 - Prob. 91ECh. 5 - Prob. 92ECh. 5 - Why do real gases not always behave ideally?...Ch. 5 - Prob. 94ECh. 5 - Prob. 95ECh. 5 - Without looking at tables of values, which of the...Ch. 5 - Prob. 97ECh. 5 - Prob. 98ECh. 5 - Prob. 99ECh. 5 - Prob. 100ECh. 5 - Prob. 101ECh. 5 - Prob. 102ECh. 5 - Consider separate 1.0-L samples of O2(g) and...Ch. 5 - Consider separate 1.00-L samples of Ar(g), both...Ch. 5 - Calculate the intermolecular collision frequency...Ch. 5 - Prob. 106ECh. 5 - Prob. 107ECh. 5 - Prob. 108ECh. 5 - Prob. 109ECh. 5 - Prob. 110ECh. 5 - Prob. 111ECh. 5 - Prob. 112AECh. 5 - Prob. 113AECh. 5 - Prob. 114AECh. 5 - Prob. 115AECh. 5 - Prob. 116AECh. 5 - Prob. 117AECh. 5 - Prob. 118AECh. 5 - A 2.747-g sample of manganese metal is reacted...Ch. 5 - Prob. 120AECh. 5 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2...Ch. 5 - Prob. 122AECh. 5 - Prob. 123AECh. 5 - Prob. 124AECh. 5 - Prob. 125AECh. 5 - Prob. 126AECh. 5 - Prob. 127AECh. 5 - Prob. 128AECh. 5 - Prob. 129AECh. 5 - Prob. 130AECh. 5 - Prob. 131AECh. 5 - Prob. 132AECh. 5 - Prob. 133AECh. 5 - Prob. 134AECh. 5 - Prob. 135AECh. 5 - Prob. 136AECh. 5 - Prob. 137AECh. 5 - Prob. 138AECh. 5 - Prob. 139AECh. 5 - Prob. 140AECh. 5 - Prob. 141AECh. 5 - Prob. 142AECh. 5 - Prob. 143AECh. 5 - Prob. 144AECh. 5 - Prob. 145AECh. 5 - Prob. 146CPCh. 5 - A 16.0-g sample of methane (CH4) reacts with 64.0...Ch. 5 - You have two samples of helium gas at the same...Ch. 5 - Prob. 149CPCh. 5 - Prob. 150CPCh. 5 - Prob. 151CPCh. 5 - Prob. 152CPCh. 5 - The density of a pure gaseous compound was...Ch. 5 - Prob. 154CPCh. 5 - The most probable velocity ump is the velocity...Ch. 5 - Derive Dalton’s law of partial pressures from the...Ch. 5 - One of the assumptions of the kinetic molecular...Ch. 5 - Prob. 158CPCh. 5 - A steel cylinder contains 5.00 moles of graphite...Ch. 5 - Prob. 160CPCh. 5 - Prob. 161CPCh. 5 - Prob. 162CPCh. 5 - Calculate the number of stages needed to change...Ch. 5 - Prob. 164CPCh. 5 - You have a helium balloon at 1.00 atm and 25°C....Ch. 5 - Prob. 166CPCh. 5 - Prob. 167MP
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