(a)
Interpretation:
The direction of the equilibrium shift when the concentration of Ozone is decreased has to be given.
Concept introduction:
Le-Chatelier Principle:
If a chemical system at equilibrium is disturbed the system will react in the direction that counteracts the disturbance the stress.
Example:
If the concentration of the reactant is increased the equilibrium of the reaction shifted to the right side.
If the concentration of the reactant is decreased the equilibrium of the reaction shifted to the left side.
(b)
Interpretation:
The direction of the equilibrium shift when the concentration of Oxygen is decreased has to be given.
Concept introduction:
Refer to part (a).
(c)
Interpretation:
The direction of the equilibrium shift when the concentration of Ozone is increased has to be given.
Concept introduction:
Refer to part (a).
Want to see the full answer?
Check out a sample textbook solutionChapter 5 Solutions
Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry
- Consider the equation G = G + RT ln(Q). What is the value of G for a reaction at equilibrium? What does Q equal at equilibrium? At equilibrium, the previous equation reduces to G = RT ln(K). When G 0, what does it indicate about K? When G 0, what does it indicate about K? When t G = 0, what does it indicate about K? G predicts spontaneity for a reaction, whereas G predicts the equilibrium position. Explain what this statement means. Under what conditions can you use G to determine the spontaneity of a reaction?arrow_forward. Consider the reaction 2CO(g)+O2(g)2CO2(g)Suppose the system is already at equilibrium, and then an additional mole of CO2(g) is injected into the system at constant temperature. Does the amount of O2(g) in the system increase or decrease? Does the value of K for the reaction change?arrow_forwardThe formation of ammonia from its elements is an important industrial process. 3 H2(g) + N2(g) 2 NH3(g) 1. Does the reaction shift to the right or to the left, or does it remain unchanged, when extra H2 is added? (a) shift left (b) shift right (c)unchangedarrow_forward
- Water gas, a mixture of H2 and CO, is an important industrial fuel produced by the reaction of steam with red hot coke, essentially pure carbon. (a) Write the expression for the equilibrium constant for the reversible reaction C(s)+H2O(g)CO(g)+H2(g)H=131.30kJ (b) What will happen to the concentration of each reactant and product at equilibrium if more C is added? (c) What will happen to the concentration of each reactant and product at equilibrium if H2O is removed? (d) What will happen to the concentration of each reactant and product at equilibrium if CO is added? (e) What will happen to the concentration of each reactant and product at equilibrium if the temperature of the system is increased?arrow_forwardThe only stress (change) that also changes the value of K is a change in temperature. For an exothermic reaction, how does the equilibrium position change as temperature increases, and what happens to the value of K? Answer the same questions for an endothermic reaction. If the value of K increases with a decrease in temperature, is the reaction exothermic or endothermic? Explain.arrow_forwardThe following equilibrium is established in a closed container: C(s)+O2(g)CO2(g)H=393kJmol1 How does the equilibrium shift in response to each of the following stresses? (a) The quantity of solid carbon is increased. (b) A small quantity of water is added, and CO2 dissolves in it. (c) The system is cooled. (d) The volume of the container is increased.arrow_forward
- . Consider an equilibrium mixture consisting of H2O(g), CO(g). H2(g), and CO2(g) reacting in a closed vessel according to the equation H2O(g)+CO(g)H2(g)+CO2(g)a. You add more H2O to the flask. How does the new equilibrium concentration of each chemical compare to its origin al equilibrium concentration after equilibrium is re-established? Justify your answer. b. You add more H2to the flask. How does the concentration of each chemical compare to its original concentration after equilibrium is re-established? Justify your answer.arrow_forwardConsider an equilibrium mixture of four chemicals (A. B. C. and D. all gases) reacting in a closed flask according to the following equation: A+BC+Da. You add more A to the flask. How does the concentration of each chemical compare to its original concentration after equilibrium is re-established? Justify your answer. h. You have the original set-up at equilibrium, and add more D to the flask. How does the concentration of each chemical compare to its original concentration after equilibrium is re-established? Justify your answer.arrow_forwardConsider the system 4 NH3(g) + 3 O2(g) ⇌ 2 N2(g) + 6 H20(ℓ) ΔrH° = −1530.4 kJ/mol How will the amount of ammonia at equilibrium be affected by removing O2(g) without changing the total gas volume? adding N2(g) without changing the total gas volume? adding water without changing the total gas volume? expanding the container? increasing the temperature? Which of these changes (i to v) increases the value of K? Which decreases it?arrow_forward
- Consider the following hypothetical dissociation: AB3(s) A3+(aq)+3 B(aq)H0What effect will each of the following have on the position of equilibrium? (a) addition of A(NO3)3 (b) increase in temperature (c) adding Na+, forming NaBarrow_forwardHydrogen for use in ammonia production is produced by the reaction CH4(g)+H2O(g)750oCNicatalystCO(g)+3H2(g) What will happen to a reaction mixture at equilibrium if a. H2O(g) is removed? b. the temperature is increased (the reaction is endothermic)? c. an inert gas is added to a rigid reaction container? d. CO(g) is removed? e. the volume of the container is tripled?arrow_forwardExplain why an equilibrium between Br2(l) and Br2(g) would not be established if the container were not a closed vessel shown in Figure 13.5.arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning