Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Textbook Question
Chapter 5, Problem 58E
The
Pure lithium is composed of two isotopes.
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1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
None
Part II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization
of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm").
Determine the following:
(a) molecular Formula and Degree of unsaturation of compound Brian
(b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts
(ii) integration, ciii) multiplicity and (iv) interferences made for each signal
(c) Draw the structure of compound Brian.
)
ΕΙ
43
41
27
71
114 (M+)
Hmmm
20
30
40
50 60
70
80
90 100 110 120
1H NMR spectrum
300 MHz in CDCl3
2.0
alle
1.0
Chapter 5 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 5 - Prob. 1ECh. 5 - List the major points in Daltons atomic theory.Ch. 5 - Show that the Daltons atomic theory explains the...Ch. 5 - How does Daltons atomic theory account for the Law...Ch. 5 - The chemical name for limestone, a compound of...Ch. 5 - The brilliance with which magnesium burns makes it...Ch. 5 - Sulfur and fluorine form at least two compounds...Ch. 5 - Prob. 8ECh. 5 - Advances in technology and science often progress...Ch. 5 - When J. J. Thomson measured the deflection of a...
Ch. 5 - Prob. 11ECh. 5 - What is meant by stating that the charge of an...Ch. 5 - How can we account for the fact that, in the...Ch. 5 - How can we account for the fact that most of the...Ch. 5 - What do we call the central part of an atom?Ch. 5 - What major conclusions were drawn from the...Ch. 5 - Describe the activity of electrons according to...Ch. 5 - The Rutherford experiment was performed and its...Ch. 5 - Compare the three major parts of an atom in charge...Ch. 5 - Prob. 20ECh. 5 - Can two different elements have the same atomic...Ch. 5 - Compare the number of protons and electrons in an...Ch. 5 - Explain why isotopes of different elements can...Ch. 5 - How many protons, neutrons and electrons are there...Ch. 5 - Prob. 25ECh. 5 - What advantage does the atomic mass unit have over...Ch. 5 - What is an atomic mass unit?Ch. 5 - The mass of an average atom of a certain element...Ch. 5 - The average mass of boron atoms is 10.81u. How...Ch. 5 - The atomic masses of the natural isotopes of neon...Ch. 5 - A certain element consists of two stable isotopes....Ch. 5 - The mass of 60.4 of the atoms of an element is...Ch. 5 - Isotopic data for boron allow the calculation of...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Questions 31 through 36: Percentage abundances and...Ch. 5 - Prob. 40ECh. 5 - How many elements are in Period 5 of the periodic...Ch. 5 - Write the symbol of the element in each given...Ch. 5 - Prob. 43ECh. 5 - List the symbols of the elements of each of the...Ch. 5 - Using only a periodic table for reference, list...Ch. 5 - Prob. 46ECh. 5 - Write the atomic masses of helium and aluminum.Ch. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - Prob. 50ECh. 5 - Prob. 51ECh. 5 - Determine whether each statement that follows is...Ch. 5 - Prob. 53ECh. 5 - Sodium oxide and sodium peroxide are two compounds...Ch. 5 - Prob. 55ECh. 5 - The CRC Handbook, a large reference book of...Ch. 5 - The element lanthanum has two stable isotopes,...Ch. 5 - The atomic mass of lithium on a periodic table is...Ch. 5 - Prob. 59ECh. 5 - Prob. 60ECh. 5 - Prob. 61ECh. 5 - Prob. 62ECh. 5 - Prob. 5.1TCCh. 5 - Prob. 5.2TCCh. 5 - Prob. 5.3TCCh. 5 - Prob. 5.4TCCh. 5 - Prob. 5.5TCCh. 5 - Write a brief description of the relationships...Ch. 5 - Prob. 2CLECh. 5 - Prob. 3CLECh. 5 - Prob. 4CLECh. 5 - Prob. 5CLECh. 5 - Prob. 6CLECh. 5 - Prob. 7CLECh. 5 - What is the number of each type of subatomic...Ch. 5 - Naturally occurring lithium is composed of two...Ch. 5 - Prob. 3PECh. 5 - Prob. 4PECh. 5 - Prob. 5PE
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forwardPart V. Choose which isomer would give the 1H-NMR spectrum below. Justify your reasoning by assigning important signals to the Corresponding protons of the correct molecule. A D on of of of H H 88 2 90 7.8 7.6 7.4 80 5 6 [ppm] 7.2 6.8 6.6 6.4 ō [ppm]arrow_forwardShow work with explanation. don't give Ai generated solutionarrow_forward
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- a. For the following indicated bonds, rank them in order of decreasing AH° for homolytic cleavage. Based on your answer, which bond would be most likely to break homolytically? (a) (c) H3C CH3 .CH3 CH3 CH3 (b) Page 1 of 5 Chem 0310 Organic Chemistry 1 Recitations b. Draw all the possible radical products for 2-methylbutane, and determine which bond is most likely to be broken.arrow_forwardA 5-m³ rigid tank contains 5 kg of water at 100°C. Determine (a) the pressure, (b) the total enthalpy, and (c) the mass of each phase of water.arrow_forwardQ8. Draw the mechanism for this halogenation reaction. Show all steps including initiation, propagation, and recombination. Cl₂, hv CI Br Br2, hv, heatarrow_forward
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