Concept explainers
Interpretation: All possible constitutional and stereoisomers for a compound of molecular formula
Concept introduction: A compound exhibits number of stereoisomers when it contains more than one stereogenic centers. The maximum number of stereoisomers a compound with
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- Draw all possible stereoisomers of the following compound (there are four of them). You need to consider both the chiral carbon and the double bond CH;CH=CHCH(CI)CH3arrow_forwardAAtropine, extracted from the plant Atropa belladonna, has been used in the treatment of bradycardia (low heart rate) and cardiac arrest. Draw the enantiomer of atropine (the original molecule is drawn below, use that structure to draw the enantiomer): CH3 H OH B Draw a structure using wedges and dashes for the following compound: H CH3 OH Draw Your Solution HO- -H H CH3 -OHarrow_forwardChrysanthemic acid, from the chrysanthemum flower, is a naturally occurring insecticide, with the constitution indicated. Draw the structures of the cis and trans stereoisomers of chrysanthemic acid.arrow_forward
- 5a 5barrow_forwardShow the structure of all alcohols with the molecular formula C5H11OH. Identify the ones that are chiral. Do not repeat same structures twice.arrow_forwardEthambutol is an anti-tuberculosis medicinal agent with two stereogenic centers, as shown in the given skeletal structure. It has 15, 2S configuration at its stereogenic centers. Redraw ethambutol, showing the correct configuration at each of the stereogenic centers. OH H fil N H 2 OH - Click and drag to start drawing a structure. C C С X Ś CX èarrow_forward
- Identify the asymmetric carbon in the following molecules and mark them with an x. There may be one or more asymmetric carbon or none at all in the given molecules. Appropriately name each molecule as chiral or achiral.arrow_forwardIndicate whether the pair of structures shown represent stereoisomers, constitutional isomers, different conformations of the same compound, or the same conformation of a compound viewed from a different perspective. Note that cis, trans isomers are an example of stereoisomers. CH3 CI- CH3 CH3- H3C- CH3- 오. CH3 ♦arrow_forwardMark each chiral center in the following molecules with an asterisk. How many stereoisomers are possible for each molecule?arrow_forward
- PGF 2a is a prostaglandin, a group of compounds that are responsible for inflammation (Section 19.6). (a) How many tetrahedral stereogenic centers does PGF 2a contain? (b) How many double bonds can exist as cis and trans isomers? (c) Considering both double bonds and tetrahedral stereogenic centers, what is the maximum number of stereoisomers that can exist for PGF20? OH HO -CH₂CH=CH(CH₂)3COOH CH=CHCH(OH)(CH₂)4CH3 PGF₂αarrow_forwardIs the methyl group at the junction of rings C and D axial or equatorial to ring C?arrow_forwardWhat is the molecular formula (in the order CH) of the compound?arrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning