Concept explainers
(a)
Interpretation:
The given molecule is same or different enantiomer of the shown original molecule is to be identified.
Concept introduction:
Isomers are molecules having same connectivity. Enantiomers are nonsuperimposable mirror images. If the molecules can be interconverted by one or more single bond rotation, then they are said to be the same enantiomer or identical molecules. If the molecules are not able to interconvert, then they are enantiomers of each other.
Answer to Problem 5.37P
The given molecule is not same enantiomer as the original one.
Explanation of Solution
The given original enantiomer is:
The molecule which is to be compared is:
The given molecule is the non superimposable mirror image of THE original molecule.
These molecules cannot be interconverted by single bond rotation. Hence, the given molecule is not same enantiomer as the original one.
The molecule is not a same enantiomer as the original molecule is determined on the basis of capability of interconversion by single bond rotation.
(b)
Interpretation:
The given molecule is same or different enantiomer of the shown original molecule is to be identified.
Concept introduction:
Isomers are the molecules having same connectivity. Enantiomers are nonsuperimposable mirror images. If the molecules can be interconverted by one or more single bond rotation, then they are said to be same enantiomer or identical molecules. If the molecules are not able to interconvert, then they are enantiomers of each other.
Answer to Problem 5.37P
The given molecule is a same enantiomer as the original one.
Explanation of Solution
The given original enantiomer is:
The molecule which is to be compared is:
The molecule can be converted to original molecule.
Hence, the given molecule is a same enantiomer as the original one.
The molecule is a same enantiomer as the original molecule is determined on the basis of capability of interconversion by single bond rotation.
(c)
Interpretation:
The given molecule is same or different enantiomer of the shown original molecule is to be identified.
Concept introduction:
Isomers are the molecules having same connectivity. Enantiomers are nonsuperimposable mirror images. If the molecules can be interconverted by one or more single bond rotation, then they are said to be the same enantiomer or identical molecules. If the molecules are not able to interconvert, then they are enantiomers of each other.
Answer to Problem 5.37P
The given molecule is not a same enantiomer as the original one.
Explanation of Solution
The given original enantiomer is:
The molecule which is to be compared is:
The molecule cannot be converted to the original molecule by single bond rotation.
Hence, the given molecule is not same enantiomer as the original one.
The molecule is not a same enantiomer as original molecule is determined on the basis of capability of interconversion by single bond rotation.
(d)
Interpretation:
The given molecule is same or different enantiomer of the shown original molecule is to be identified.
Concept introduction:
Isomers are molecules having same connectivity. Enantiomers are nonsuperimposable mirror images. If the molecules can be interconverted by one or more single bond rotation, then they are said to be the same enantiomer or identical molecules. If the molecules are not able to interconvert, then they are enantiomers of each other.
Answer to Problem 5.37P
The given molecule is same enantiomer as the original one.
Explanation of Solution
The given original enantiomer is:
The molecule which is to be compared is:
The given Newman projection can be converted to zigzag structure as shown below:
The molecule can be converted to the original molecule.
Hence, the given molecule is same enantiomer as the original one.
The molecule is a same enantiomer as original molecule is determined by converting Newman projection to zigzag structure.
(e)
Interpretation:
The given molecule is same or different enantiomer of the shown original molecule is to be identified.
Concept introduction:
Isomers are molecules having same connectivity. Enantiomers are nonsuperimposable mirror images. If the molecules can be interconverted by one or more single bond rotation, then they are said to be the same enantiomer or identical molecules. If the molecules are not able to interconvert, then they are enantiomers of each other.
Answer to Problem 5.37P
The given molecule is not a same enantiomer as the original one.
Explanation of Solution
The given original enantiomer is:
The molecule which is to be compared is:
The given Newman projection can be converted to zigzag structure as shown below:
The given molecule is a nonsuperimposable mirror image of the original molecule.
These molecules cannot be interconverted by single bond rotation. Hence, the given molecule is not same enantiomer as the original one.
The molecule is a not the same enantiomer as the original molecule is determined by converting Newman projection to zigzag structure.
(f)
Interpretation:
The given molecule is same or different enantiomer of the shown original molecule it is to be identified.
Concept introduction:
Isomers are molecules having same connectivity. Enantiomers are nonsuperimposable mirror images. If the molecules can be interconverted by one or more single bond rotation, then they are said to be same enantiomer or identical molecules. If the molecules are not able to interconvert, then they are enantiomers of each other. In Fischer projection, the horizontal bonds point towards the observer and are denoted as wedge bond in the zigzag structure.
Answer to Problem 5.37P
The given molecule is a same enantiomer as the original one.
Explanation of Solution
The given original enantiomer is:
The molecule which is to be compared is:
The given Fischer projection can be converted to zigzag structure as shown below:
Hence, the given molecule is a same enantiomer as the original one.
The molecule is not a same enantiomer as the original molecule is determined by converting Fischer projection to zigzag structure.
(e)
Interpretation:
The given molecule is same or different enantiomer of the shown original molecule is to be identified.
Concept introduction:
Isomers are molecules having same connectivity. Enantiomers are nonsuperimposable mirror images. If the molecules can be interconverted by one or more single bond rotation, then they are said to be the same enantiomer or identical molecules. If the molecules are not able to interconvert, then they are enantiomers of each other. In Fischer projection, the horizontal bonds point toward the observer and are denoted as wedge bond in the zigzag structure.
Answer to Problem 5.37P
The given molecule is not a same enantiomer as the original one.
Explanation of Solution
The given original enantiomer is:
The molecule which is to be compared is:
The given Fischer projection can be converted to zigzag structure as shown below:
The given molecule is a nonsuperimposable mirror image of the original molecule.
These molecules cannot be interconverted by single bond rotation. Hence, the given molecule is not same enantiomer as the original one.
The molecule is not a same enantiomer as the original molecule is determined by converting Fischer projection to zigzag structure.
(g)
Interpretation:
The given molecule is same or different enantiomer of the shown original molecule it is to be identified.
Concept introduction:
Isomers are the molecules having same connectivity. Enantiomers are nonsuperimposable mirror images. If the molecules can be interconverted by one or more single bond rotation, then they are said to be the same enantiomer or identical molecules. If the molecules are not able to interconvert, then they are enantiomers of each other.
Answer to Problem 5.37P
The given molecule is not a same enantiomer as the original one.
Explanation of Solution
The given original enantiomer is:
The molecule which is to be compared is:
This molecule can be converted to original molecule by single bond rotation.
Hence, the given molecule is same enantiomer as the original one.
The molecule is a same enantiomer as the original molecule is determined on the basis of capability of interconversion by single bond rotation.
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Chapter 5 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
- Calculate the pH and the pOH of each of the following solutions at 25 °C for which the substances ionize completely: (a) 0.000259 M HClO4arrow_forwardWhat is the pH of a 1.0 L buffer made with 0.300 mol of HF (Ka = 6.8 × 10⁻⁴) and 0.200 mol of NaF to which 0.160 mol of NaOH were added?arrow_forwardDetermine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction. NaN₃arrow_forward
- A. Draw the structure of each of the following alcohols. Then draw and name the product you would expect to produce by the oxidation of each. a. 4-Methyl-2-heptanol b. 3,4-Dimethyl-1-pentanol c. 4-Ethyl-2-heptanol d. 5,7-Dichloro-3-heptanolarrow_forwardWhat is the pH of a 1.0 L buffer made with 0.300 mol of HF (Ka = 6.8 × 10⁻⁴) and 0.200 mol of NaF to which 0.160 mol of NaOH were added?arrow_forwardCan I please get help with this.arrow_forward
- Determine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction. N₂H₅ClO₄arrow_forwardPlease help me with identifying these.arrow_forwardCan I please get help with this?arrow_forward
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning