The type of isomers in limonene has to be identified. Concept Introduction: Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents. Chirality: It refers to a Carbon atom in a molecule that contains four different substituents. Enantiomers: They are chiral molecules whose mirror images are not superimposable.

Question

[10] 10] Q1. Do the following conversions as directed. Write the complete reaction equation. (a) Benzaldehyde to Benzoic Acid. (b) Propanal to 1-propanal (c) Cyclohexanone to Cyclohexanol (d) Acetaldehyde to Ethyl alcohol (e) Acetone to Iso-propyl alcohol

Answer 1

Question

Chapter 5, Problem 5.35P

(a)

Interpretation Introduction

Interpretation:

The type of isomers in limonene has to be identified.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

(b)

Interpretation Introduction

Interpretation:

Possibility of having E, Z isomers in limonene has to be identified.

Concept Introduction:

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

(c)

Interpretation Introduction

Interpretation:

Reason for why isomers of limonene smell differently has to be explained.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

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[10] 10] Q1. Do the following conversions as directed. Write the complete reaction equation. (a) Benzaldehyde to Benzoic Acid. (b) Propanal to 1-propanal (c) Cyclohexanone to Cyclohexanol (d) Acetaldehyde to Ethyl alcohol (e) Acetone to Iso-propyl alcohol

(a) Draw a skeletal structure of the anabolic steroid 4-androstene-3,17-dione, also called "andro," from the following description. Andro contains the tetracyclic steroid skeieton with carbonyl groups at C3 and C17, a double bond between C4 and C5, and methyl groups bonded to C10 and C13. (b) Add wedges and dashes for all stereogenic centers with the following information: the configuration at C10 is R, the configuration at C13 is S, and all substituents at ring fusions are trans to each other.

PGF 2a is a prostaglandin, a group of compounds that are responsible for inflammation (Section 19.6). (a) How many tetrahedral stereogenic centers does PGF 2a contain? (b) How many double bonds can exist as cis and trans isomers? (c) Considering both double bonds and tetrahedral stereogenic centers, what is the maximum number of stereoisomers that can exist for PGF20? OH HO -CH₂CH=CH(CH₂)3COOH CH=CHCH(OH)(CH₂)4CH3 PGF₂α

Answer 2

Question

Chapter 5, Problem 5.35P

(a)

Interpretation Introduction

Interpretation:

The type of isomers in limonene has to be identified.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

(b)

Interpretation Introduction

Interpretation:

Possibility of having E, Z isomers in limonene has to be identified.

Concept Introduction:

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

(c)

Interpretation Introduction

Interpretation:

Reason for why isomers of limonene smell differently has to be explained.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

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Answer 3

Question

Chapter 5, Problem 5.35P

(a)

Interpretation Introduction

Interpretation:

The type of isomers in limonene has to be identified.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

(b)

Interpretation Introduction

Interpretation:

Possibility of having E, Z isomers in limonene has to be identified.

Concept Introduction:

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

(c)

Interpretation Introduction

Interpretation:

Reason for why isomers of limonene smell differently has to be explained.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

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Answer 4

Question

Chapter 5, Problem 5.35P

(a)

Interpretation Introduction

Interpretation:

The type of isomers in limonene has to be identified.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

(b)

Interpretation Introduction

Interpretation:

Possibility of having E, Z isomers in limonene has to be identified.

Concept Introduction:

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

(c)

Interpretation Introduction

Interpretation:

Reason for why isomers of limonene smell differently has to be explained.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

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Answer 5

Chapter 5, Problem 5.35P

(a)

Interpretation Introduction

Interpretation:

The type of isomers in limonene has to be identified.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

(b)

Interpretation Introduction

Interpretation:

Possibility of having E, Z isomers in limonene has to be identified.

Concept Introduction:

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

(c)

Interpretation Introduction

Interpretation:

Reason for why isomers of limonene smell differently has to be explained.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

Answer 6

Chapter 5, Problem 5.35P

(a)

Interpretation Introduction

Interpretation:

The type of isomers in limonene has to be identified.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

Answer 7

Chapter 5, Problem 5.35P

(a)

Interpretation Introduction

Interpretation:

The type of isomers in limonene has to be identified.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Possibility of having E, Z isomers in limonene has to be identified.

Concept Introduction:

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Possibility of having E, Z isomers in limonene has to be identified.

Concept Introduction:

Geometric isomers: Two compounds are considered as geometric isomers of each other if both contain same number of atoms but different in their arrangement.

E configuration: The geometric isomers are given E configuration if high priority groups are placed on opposite sides of the double bond.

Z configuration: The geometric isomers are given Z configuration if high priority groups are placed on same sides of the double bond.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Reason for why isomers of limonene smell differently has to be explained.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Reason for why isomers of limonene smell differently has to be explained.

Concept Introduction:

Chiral carbon: A carbon is said to be chiral carbon if it is bonded to four different substituents.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

Answer 12

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Ch. 5.1 - Calculate the index of hydrogen deficiency for...Ch. 5.1 - Prob. 5.2P Ch. 5.2 - Write the IUPAC name of each alkene. (a) (b)Ch. 5.2 - Prob. 5.4P Ch. 5.2 - Prob. 5.5P Ch. 5.2 - Prob. 5.6P Ch. 5.2 - Prob. 5.7P Ch. 5.2 - Prob. 5.8P Ch. 5 - Predict all approximate bond angles about each...Ch. 5 - Prob. 5.10P

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