Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
Question
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Chapter 5, Problem 5.15P

(a)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are CH3, H, Br, CH2CH3

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are OCH3,CH(CH3)2,B(CH2CH3), H

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

(b)

Interpretation Introduction

Interpretation:

Increasing order of priority of the given groups has to be given. Given groups are CH3,CH2OH,CH2NH2, CH2Br

Concept Introduction:

The group attached to asymmetric center should be ranked based on the atomic number of atom which directly connected to asymmetric center. The higher the atomic number of atom, higher the priority. If there is tie, then consider the next atoms attached to the connected atom and so on.

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(b) NABH, CH3 COCH,CH3 CH3CH2OH (c)
Identify the following reactions as either SN1, SN2, E1, or E2: (a) Br CHCH3 CH=CH2 кон (b) Br OCH3 .CHCH3 .CHCH3 CH3OH Heat
Estimate the heat released when ethene(CH2=CH2) reacts with HBr to giveCH3CH2Br. Bond enthalpies areC-H : 412 kJ/mol; C-C : 348 kJ/mol;C=C : 612 kJ/mol; C-Br : 276 kJ/mol;Br-Br : 193 kJ/mol; H-Br : 366 kJ/mol. Choose the correct answer:1. 1036 kJ/mol2. 58 kJ/mol3. 424 kJ/mol4. 200 kJ/mol5. 470 kJ/mol
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