
Concept explainers
(a)
Interpretation:The isomeric relationship between cyclopropylcyclopentane and cyclobutylcyclobutane should beidentified.
Concept introduction:Chiral carbon is any stereocenter attached to four different alkyl substituents. If any two of the substituent happen to be similar the center is regarded as achiral.
The enantiomers are identical chemical compounds that have a mirror-image relationship to each other while diastereomers do not hold similar mirror image relationships.
The molecular models of
The two compounds constitute a pair of constitutional isomers. These kinds of isomers are formed by cleavage and replacement of bonds, unlike the conformational isomers that result due to rotation around the bond.
(a)

Explanation of Solution
Structures of cyclopropylcyclopentane and cyclobutylcyclobutane are illustrated as follows:
The molecular formula for both cyclopropylcyclopentane and cyclobutylcyclobutane is
(b)
Interpretation: The isomeric relationship among
Concept introduction: Chiral carbon is any stereocenter attached to four different alkyl substituents. If any two of the substituent happen to be similar the center is regarded as achiral.
The enantiomers are identical chemical compounds that have a mirror-image relationship to each other while diastereomers do not hold similar mirror image relationships.
The molecular models of
The two compounds constitute a pair of constitutional isomers. These kinds of isomers are formed by cleavage and replacement of bonds, unlike the conformational isomers that result due to rotation around the bond.
(b)

Explanation of Solution
Structures of
are illustrated as follows:
Since cis and trans form represent diastereoisomers therefore
Want to see more full solutions like this?
Chapter 5 Solutions
ORGANIC CHEMISTRY (LL)-PACKAGE
- Synthesize 2-Hydroxy-2-phenylacetonitrile from phenylmethanol using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forwardSynthesize N-Methylcyclohexylamine from cyclohexanol using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forwardSynthesize N-Methylcyclohexylamine from cyclohexanol using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forward
- If possible, please provide the formula of the compound 3,3-dimethylbut-2-enal.arrow_forwardSynthesize 1,4-dibromobenzene from acetanilide (N-phenylacetamide) using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forwardIndicate the products obtained by mixing (3-oxo-3-phenylpropyl)triphenylphosphonium bromide with sodium hydride.arrow_forward
- We mix N-ethyl-2-hexanamine with excess methyl iodide and followed by heating with aqueous Ag2O. Indicate the major products obtained.arrow_forwardIndicate the products obtained by mixing acetophenone with iodine and NaOH.arrow_forwardIndicate the products obtained by mixing 2-Propanone and ethyllithium and performing a subsequent acid hydrolysis.arrow_forward
- Indicate the products obtained if (E)-2-butenal and 3-oxo-butanenitrile are mixed with sodium ethoxide in ethanol.arrow_forwardQuestion 3 (4 points), Draw a full arrow-pushing mechanism for the following reaction Please draw all structures clearly. Note that this intramolecular cyclization is analogous to the mechanism for halohydrin formation. COH Br + HBr Brarrow_forwardIndicate the products obtained if 2,2-dimethylpropanal and acetaldehyde are mixed with sodium ethoxide in ethanol.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY





