Student Solutions Manual for Ebbing/Gammon's General Chemistry, 11th
11th Edition
ISBN: 9781305673472
Author: Darrell Ebbing, Steven D. Gammon
Publisher: Cengage Learning
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Textbook Question
Chapter 5, Problem 5.156QP
A mixture contained zinc sulfide, ZnS, and lead sulfide, PbS. A sample of the mixture weighing 6.12 g was reacted with an excess of hydrochloric acid. The reactions are
If the sample reacted completely and produced 1.049 L of hydrogen sulfide, H2S, at 23°C and 762 mmHg, what were the percentages of ZnS and PbS in the mixture?
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LTS
Solid:
AT=Te-Ti
Trial 1
Trial 2
Trial 3
Average
ΔΗ
Mass water, g
24.096
23.976
23.975
Moles of solid, mol
0.01763
001767
0101781
Temp. change, °C
2.9°C
11700
2.0°C
Heat of reaction, J
-292.37J -170.473
-193.26J
AH, kJ/mole
16.58K 9.647 kJ 10.85 kr
16.58K59.64701
KJ
mol
12.35k
Minimum AS,
J/mol K
41.582
mol-k
Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn &
Show your calculations for:
AH in J and then in kJ/mole for Trial 1:
qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J
qsin =
qrxn =
292.35 292.37J
AH in J = 292.375 0.2923kJ
0.01763m01
=1.65×107
AH in kJ/mol =
=
16.58K
0.01763mol
mol
qrx
Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con
Kelvin.)
AS=AHIT
(1.65×10(9.64×103) + (1.0
Jimai
For the compound: C8H17NO2
Use the following information to come up with a plausible structure:
8
This compound has "carboxylic acid amide" and ether functional groups.
The peaks at 1.2ppm are two signals that are overlapping one another.
One of the two signals is a doublet that represents 6 hydrogens; the
other signal is a quartet that represents 3 hydrogens.
Vnk the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest bolling
point, choose 2 next to the substance with the next highest boiling point, and so on.
substance
C
D
chemical symbol,
chemical formula
or Lewis structure.
CH,-N-CH,
CH,
H
H 10: H
C-C-H
H H H
Cale
H 10:
H-C-C-N-CH,
Bri
CH,
boiling point
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Chapter 5 Solutions
Student Solutions Manual for Ebbing/Gammon's General Chemistry, 11th
Ch. 5.1 - A gas in a container had a measured pressure of 57...Ch. 5.1 - Prob. 5.1CCCh. 5.2 - A volume of carbon dioxide gas, CO2, equal to 20.0...Ch. 5.2 - If you expect a chemical reaction to produce 4.38...Ch. 5.2 - A balloon contains 5.41 dm3 of helium, He, at 24C...Ch. 5.2 - Prob. 5.2CCCh. 5.3 - Prob. 5.5ECh. 5.3 - Prob. 5.6ECh. 5.3 - Calculate the density of helium, He, in grams per...Ch. 5.3 - A sample of a gaseous substance at 25C and 0.862...
Ch. 5.3 - Prob. 5.3CCCh. 5.4 - How many liters of chlorine gas, Cl2, can be...Ch. 5.5 - A 10.0-L flask contains 1.031 g O2 and 0.572 g CO2...Ch. 5.5 - A flask equipped with a valve contains 3.0 mol of...Ch. 5.5 - Prob. 5.11ECh. 5.6 - Prob. 5.5CCCh. 5.7 - What is the rms speed (in m/s) of a carbon...Ch. 5.7 - At what temperature do hydrogen molecules, H2,...Ch. 5.7 - Prob. 5.14ECh. 5.7 - If it takes 4.67 times as long for a particular...Ch. 5.7 - Prob. 5.6CCCh. 5.8 - Prob. 5.16ECh. 5.8 - Prob. 5.7CCCh. 5 - Prob. 5.1QPCh. 5 - Prob. 5.2QPCh. 5 - Prob. 5.3QPCh. 5 - Prob. 5.4QPCh. 5 - The volume occupied by a gas depends linearly on...Ch. 5 - Prob. 5.6QPCh. 5 - Prob. 5.7QPCh. 5 - Prob. 5.8QPCh. 5 - Prob. 5.9QPCh. 5 - Prob. 5.10QPCh. 5 - Prob. 5.11QPCh. 5 - Prob. 5.12QPCh. 5 - Prob. 5.13QPCh. 5 - Prob. 5.14QPCh. 5 - Prob. 5.15QPCh. 5 - Prob. 5.16QPCh. 5 - Prob. 5.17QPCh. 5 - Prob. 5.18QPCh. 5 - Prob. 5.19QPCh. 5 - Prob. 5.20QPCh. 5 - Under what conditions does the behavior of a real...Ch. 5 - Prob. 5.22QPCh. 5 - Prob. 5.23QPCh. 5 - Prob. 5.24QPCh. 5 - Prob. 5.25QPCh. 5 - A 1-liter container is filled with 2.0 mol Ar, 2.0...Ch. 5 - Prob. 5.27QPCh. 5 - Prob. 5.28QPCh. 5 - Prob. 5.29QPCh. 5 - Prob. 5.30QPCh. 5 - Prob. 5.31QPCh. 5 - A 3.00-L flask containing 2.0 mol of O2 and 1.0...Ch. 5 - Prob. 5.33QPCh. 5 - Two identical He-filled balloons, each with a...Ch. 5 - You have a balloon that contains O2. What could...Ch. 5 - Prob. 5.36QPCh. 5 - Prob. 5.37QPCh. 5 - The barometric pressure measured outside an...Ch. 5 - Prob. 5.39QPCh. 5 - You fill a balloon with helium gas to a volume of...Ch. 5 - Prob. 5.41QPCh. 5 - Prob. 5.42QPCh. 5 - A McLeod gauge measures low gas pressures by...Ch. 5 - If 456 dm3 of krypton at 101 kPa and 21C is...Ch. 5 - A sample of nitrogen gas at 17C and 760 mmHg has a...Ch. 5 - Prob. 5.46QPCh. 5 - Helium gas, He, at 22C and 1.00 atm occupied a...Ch. 5 - Prob. 5.48QPCh. 5 - A vessel containing 39.5 cm3 of helium gas at 25C...Ch. 5 - A sample of 62.3 cm3 of argon gas at 18C was...Ch. 5 - A bacterial culture isolated from sewage produced...Ch. 5 - Pantothenic acid is a B vitamin. Using the Dumas...Ch. 5 - In the presence of a platinum catalyst, ammonia,...Ch. 5 - Methanol, CH3OH, can be produced in industrial...Ch. 5 - Prob. 5.55QPCh. 5 - Prob. 5.56QPCh. 5 - A cylinder of oxygen gas contains 91.3 g O2. If...Ch. 5 - In an experiment, you fill a heavy-walled 6.00-L...Ch. 5 - Prob. 5.59QPCh. 5 - According to your calculations, a reaction should...Ch. 5 - Prob. 5.61QPCh. 5 - A 2.50-L flask was used to collect a 5.65-g sample...Ch. 5 - What is the density of ammonia gas, NH3, at 31C...Ch. 5 - Calculate the density of hydrogen sulfide gas,...Ch. 5 - Butane, C4H10, is an easily liquefied gaseous...Ch. 5 - Chloroform, CHCl3, is a volatile (easily...Ch. 5 - A chemist vaporized a liquid compound and...Ch. 5 - You vaporize a liquid substance at 100C and 755...Ch. 5 - A 2.56-g sample of a colorless liquid was...Ch. 5 - A 2.30-g sample of white solid was vaporized in a...Ch. 5 - Ammonium chloride, NH4Cl, is a while solid. When...Ch. 5 - Prob. 5.72QPCh. 5 - Calcium carbide reacts with water to produce...Ch. 5 - Magnesium metal reacts with hydrochloric acid to...Ch. 5 - Lithium hydroxide, LiOH, is used in spacecraft to...Ch. 5 - Magnesium burns in air to produce magnesium oxide,...Ch. 5 - Urea, NH2CONH2, is a nitrogen fertilizer that is...Ch. 5 - Nitric acid is produced from nitrogen monoxide,...Ch. 5 - Ammonium sulfate is used as a nitrogen and sulfur...Ch. 5 - Sodium hydrogen carbonate is also known as baking...Ch. 5 - Calculate the total pressure (in atm) of a mixture...Ch. 5 - Calculate the total pressure (in atm) of a mixture...Ch. 5 - A 900.0-mL flask contains 1.16 mg O2 and 0.42 mg...Ch. 5 - The atmosphere in a sealed diving bell contained...Ch. 5 - Prob. 5.85QPCh. 5 - Prob. 5.86QPCh. 5 - Formic acid, HCHO2, is a convenient source of...Ch. 5 - An aqueous solution of ammonium nitrite, NH4NO2,...Ch. 5 - Prob. 5.89QPCh. 5 - Calculate the rms speed of Br2 molecules at 23C...Ch. 5 - Uranium hexafluoride, UF6, is a white solid that...Ch. 5 - For a spacecraft or a molecule to leave the moon,...Ch. 5 - Prob. 5.93QPCh. 5 - At what temperature does the rms speed of O2...Ch. 5 - Prob. 5.95QPCh. 5 - Prob. 5.96QPCh. 5 - Prob. 5.97QPCh. 5 - Prob. 5.98QPCh. 5 - If 4.83 mL of an unknown gas effuses through a...Ch. 5 - A given volume of nitrogen, N2, required 68.3 s to...Ch. 5 - Calculate the pressure of ethanol vapor,...Ch. 5 - Calculate the pressure of water vapor at 120.0C if...Ch. 5 - Calculate the molar volume of ethane at 1.00 atm...Ch. 5 - Calculate the molar volume of oxygen at 1.00 atm...Ch. 5 - A glass tumbler containing 243 cm3 of air at 1.00 ...Ch. 5 - The density of air at 20C and 1.00 atm is 1.205...Ch. 5 - A flask contains 201 mL of argon at 21C and 738...Ch. 5 - Prob. 5.108QPCh. 5 - A balloon containing 5.0 dm3 of gas at 14C and...Ch. 5 - Prob. 5.110QPCh. 5 - A radioactive metal atom decays (goes to another...Ch. 5 - The combustion method used to analyze for carbon...Ch. 5 - Prob. 5.113QPCh. 5 - A hydrocarbon gas has a density of 1.22 g/L at 20C...Ch. 5 - A person exhales about 5.8 102 L of carbon...Ch. 5 - Pyruvic acid, HC3H3O3, is involved in cell...Ch. 5 - Liquid oxygen was first prepared by heating...Ch. 5 - Raoul Pictet, the Swiss physicist who first...Ch. 5 - Prob. 5.119QPCh. 5 - A 21.4-mL volume of hydrochloric acid reacts...Ch. 5 - A 41.41-mL sample of a 0.1250 M acid reacts with...Ch. 5 - A 48.90-mL sample of a 0.2040 M acid reacts with...Ch. 5 - If the rms speed of NH3 molecules is found to be...Ch. 5 - If the rms speed of He atoms in the exosphere...Ch. 5 - Prob. 5.125QPCh. 5 - Prob. 5.126QPCh. 5 - A 1.000-g sample of an unknown gas at 0C gives the...Ch. 5 - Plot the data given in Table 5.3 for oxygen at 0C...Ch. 5 - Carbon monoxide, CO, and oxygen, O2, react...Ch. 5 - Suppose the apparatus shown in the figure...Ch. 5 - Prob. 5.131QPCh. 5 - Prob. 5.132QPCh. 5 - Prob. 5.133QPCh. 5 - Prob. 5.134QPCh. 5 - A 19.9-mL volume of a hydrochloric acid solution...Ch. 5 - The graph here represents the distribution of...Ch. 5 - Prob. 5.137QPCh. 5 - Prob. 5.138QPCh. 5 - Prob. 5.139QPCh. 5 - Sulfur-containing compounds give skunks their...Ch. 5 - Sulfur hexafluoride, SF6, is an extremely dense...Ch. 5 - Prob. 5.142QPCh. 5 - Prob. 5.143QPCh. 5 - Shown below are three containers of an ideal gas...Ch. 5 - A 275-mL sample of CO gas is collected over water...Ch. 5 - Ethanol, the alcohol used in automobile fuels, is...Ch. 5 - Silicon nitride, Si3N4, is a material that is used...Ch. 5 - Prob. 5.148QPCh. 5 - If you have a 150-L cylinder filled with chlorine...Ch. 5 - Prob. 5.150QPCh. 5 - A sample of natural gas is 85.2% methane, CH4, and...Ch. 5 - A sample of a breathing mixture for divers...Ch. 5 - A sample of sodium peroxide, Na2O2, was reacted...Ch. 5 - Prob. 5.154QPCh. 5 - A mixture contained calcium carbonate, CaCO3, and...Ch. 5 - A mixture contained zinc sulfide, ZnS, and lead...Ch. 5 - A mixture of N2 and Ne contains equal moles of...Ch. 5 - A mixture of Ne and Ar gases at 350 K contains...Ch. 5 - An ideal gas with a density of 3.00 g/L has a...Ch. 5 - Prob. 5.160QPCh. 5 - Prob. 5.161QP
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