Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
10th Edition
ISBN: 9781305957510
Author: ZUMDAHL, Steven S.; Zumdahl, Susan A.; DeCoste, Donald J.
Publisher: Cengage Learning
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Chapter 5, Problem 137AE
The nitrogen content of organic compounds can be determined by the Dumas method. The compound in question is first reacted by passage over hot CuO(s):
The product gas is then passed through a concentrated solution of KOH to remove the CO2. After passage through the KOH solution, the gas contains N2 and is saturated with water vapor. In a given experiment a 0.253-g sample of a compound produced 31.8 mL N2 saturated with water vapor at 25°C and 726 torr. What is the mass percent of nitrogen in the compound? (The vapor pressure of water at 25°C is 23.8 torr.)
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The reaction
N2O4−⇀↽−2NO2
is allowed to reach equilibrium in a chloroform solution at 25 ∘C . The equilibrium concentrations are 0.327 mol/L N2O4 and 1.91 mol/L NO2 .
Calculate the equilibrium constant, Kc , for this reaction.
Kc= 11.16
An additional 1.00 mol NO2 is added to 1.00 L of the solution and the system is allowed to reach equilibrium again at the same temperature. Select the direction of the equilibrium shift after the NO2 is added.
towards the product
towards the reactant
no change
Determine how the addition of extra NO2 in the previous step will affect the rate constant, Kc .
Kc will increase
Kc will not change
Kc will decrease
Calculate the equilibrium concentrations of N2O4 and NO2 after the extra 1.00 mol NO2 is added to 1.00 L of solution.
[N2O4]=
mol/L
[NO2]=
mol/L
Consider the equilibrium system described by the chemical reaction below. A
1.00 L reaction vessel was filled with 2.00 mol SO2 and 2.00 mol NO2 and
allowed to react at a high temperature. At equilibrium, there were 1.30 mol of NO
in the vessel. Determine the concentrations of all reactants and products at
equilibrium and then calculate the value of Kc for this reaction.
SO2(9) + NO2(g)
SO3(g) + NO(g)
1
NEXT
Based on the given values, fill in the ICE table to determine concentrations of all reactants and
products.
SO2(g)
NO2(g)
SO3(g)
NO(g)
+
Initial (M)
2.00
2.00
Change (M)
-1.30
-1.30
1.30
1.30
Equilibrium (M)
0.70
0.70
1.30
1.30
RESET
+x
-X
1.00
2.00
1.30
-1.00
-1.30
2.30
2.70
0.70
1.35
2.00 - x
2.00 +x
What is the CORRECT equilibrium constant expression for the reaction of N2O (g) and O2(g) to produce NO(g)?
Chapter 5 Solutions
Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
Ch. 5 - Prob. 1RQCh. 5 - Prob. 2RQCh. 5 - Prob. 3RQCh. 5 - Prob. 4RQCh. 5 - Prob. 5RQCh. 5 - Prob. 6RQCh. 5 - Prob. 7RQCh. 5 - Prob. 8RQCh. 5 - Prob. 9RQCh. 5 - Why do real gases not always behave ideally? Under...
Ch. 5 - Prob. 3ALQCh. 5 - Prob. 4ALQCh. 5 - Prob. 6ALQCh. 5 - Prob. 8ALQCh. 5 - Prob. 11ALQCh. 5 - Prob. 12ALQCh. 5 - Prob. 13ALQCh. 5 - Prob. 14ALQCh. 5 - Prob. 17ALQCh. 5 - Prob. 18ALQCh. 5 - Draw molecular-level views that show the...Ch. 5 - Prob. 22QCh. 5 - Prob. 23QCh. 5 - Prob. 24QCh. 5 - Prob. 25QCh. 5 - As weather balloons rise from the earths surface,...Ch. 5 - Prob. 27QCh. 5 - Consider two different containers, each filled...Ch. 5 - Prob. 29QCh. 5 - Prob. 32QCh. 5 - Prob. 33QCh. 5 - Prob. 34QCh. 5 - Prob. 35QCh. 5 - Prob. 36QCh. 5 - Prob. 37QCh. 5 - Without looking at a table of values, which of the...Ch. 5 - Prob. 39QCh. 5 - Prob. 40QCh. 5 - Prob. 41ECh. 5 - Prob. 42ECh. 5 - A sealed-tube manometer (as shown below) can be...Ch. 5 - Prob. 44ECh. 5 - A diagram for an open-tube manometer is shown...Ch. 5 - Prob. 46ECh. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - An 11.2-L sample of gas is determined to contain...Ch. 5 - Prob. 50ECh. 5 - Prob. 51ECh. 5 - Prob. 52ECh. 5 - Prob. 53ECh. 5 - Prob. 54ECh. 5 - The Steel reaction vessel of a bomb calorimeter,...Ch. 5 - A 5.0-L flask contains 0.60 g O2 at a temperature...Ch. 5 - Prob. 57ECh. 5 - A person accidentally swallows a drop of liquid...Ch. 5 - Prob. 59ECh. 5 - N2O is a gas commonly used to help sedate patients...Ch. 5 - A gas sample containing 1.50 moles at 25C exerts a...Ch. 5 - Prob. 62ECh. 5 - Prob. 63ECh. 5 - What will be the effect on the volume of an ideal...Ch. 5 - Prob. 65ECh. 5 - Prob. 66ECh. 5 - An ideal gas is contained in a cylinder with a...Ch. 5 - Prob. 68ECh. 5 - A sealed balloon is filled with 1.00 L helium at...Ch. 5 - Prob. 70ECh. 5 - Consider the following reaction:...Ch. 5 - A student adds 4.00 g of dry ice (solid CO2) to an...Ch. 5 - Air bags are activated when a severe impact causes...Ch. 5 - Concentrated hydrogen peroxide solutions are...Ch. 5 - In 1897 the Swedish explorer Andre tried to reach...Ch. 5 - Sulfur trioxide, SO3, is produced in enormous...Ch. 5 - A 15.0-L rigid container was charged with 0.500...Ch. 5 - An important process for the production of...Ch. 5 - Consider the reaction between 50.0 mL liquid...Ch. 5 - Urea (H2NCONH2) is used extensively as a nitrogen...Ch. 5 - Prob. 81ECh. 5 - Prob. 82ECh. 5 - Prob. 83ECh. 5 - A compound has the empirical formula CHCl. A...Ch. 5 - Prob. 85ECh. 5 - Silicon tetrachloride (SiCl4) and trichlorosilane...Ch. 5 - Prob. 87ECh. 5 - Prob. 88ECh. 5 - For scuba dives below 150 ft, helium is often used...Ch. 5 - Prob. 90ECh. 5 - Consider the flasks in the following diagram. What...Ch. 5 - Consider the flask apparatus in Exercise 85, which...Ch. 5 - Prob. 93ECh. 5 - At 0C a 1.0-L flask contains 5.0 102 mole of N2,...Ch. 5 - A mixture of cyclopropane and oxygen is sometimes...Ch. 5 - Prob. 96ECh. 5 - Prob. 97ECh. 5 - A tank contains a mixture of 52.5 g oxygen gas and...Ch. 5 - Prob. 99ECh. 5 - Helium is collected over water at 25C and 1.00 atm...Ch. 5 - At elevated temperatures, sodium chlorate...Ch. 5 - Xenon and fluorine will react to form binary...Ch. 5 - Methanol (CH3OH) can be produced by the following...Ch. 5 - In the Mthode Champenoise, grape juice is...Ch. 5 - Hydrogen azide, HN3, decomposes on heating by the...Ch. 5 - Prob. 106ECh. 5 - Prob. 107ECh. 5 - The oxides of Group 2A metals (symbolized by M...Ch. 5 - Prob. 109ECh. 5 - Prob. 110ECh. 5 - Prob. 111ECh. 5 - Prob. 112ECh. 5 - Prob. 113ECh. 5 - Prob. 114ECh. 5 - Prob. 115ECh. 5 - Prob. 116ECh. 5 - Prob. 117ECh. 5 - Prob. 118ECh. 5 - Prob. 119ECh. 5 - Prob. 120ECh. 5 - Prob. 121ECh. 5 - Prob. 122ECh. 5 - Prob. 123ECh. 5 - Prob. 124ECh. 5 - Use the data in Table 84 to calculate the partial...Ch. 5 - Prob. 126ECh. 5 - Prob. 127ECh. 5 - Prob. 128ECh. 5 - Prob. 129ECh. 5 - Prob. 130ECh. 5 - Prob. 131AECh. 5 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2,...Ch. 5 - Prob. 133AECh. 5 - Prob. 134AECh. 5 - Prob. 135AECh. 5 - Cyclopropane, a gas that when mixed with oxygen is...Ch. 5 - The nitrogen content of organic compounds can be...Ch. 5 - Hyperbaric oxygen therapy is used to treat...Ch. 5 - A 15.0L tank is filled with H2 to a pressure of...Ch. 5 - A spherical glass container of unknown volume...Ch. 5 - Prob. 141AECh. 5 - A 20.0L stainless steel container at 25C was...Ch. 5 - Metallic molybdenum can be produced from the...Ch. 5 - Prob. 144AECh. 5 - Prob. 145AECh. 5 - One of the chemical controversies of the...Ch. 5 - An organic compound contains C, H, N, and O....Ch. 5 - Prob. 148AECh. 5 - Prob. 149CWPCh. 5 - Prob. 150CWPCh. 5 - A certain flexible weather balloon contains helium...Ch. 5 - A large flask with a volume of 936 mL is evacuated...Ch. 5 - A 20.0L nickel container was charged with 0.859...Ch. 5 - Consider the unbalanced chemical equation below:...Ch. 5 - Prob. 155CWPCh. 5 - Which of the following statements is(are) true? a....Ch. 5 - A chemist weighed out 5.14 g of a mixture...Ch. 5 - A mixture of chromium and zinc weighing 0.362 g...Ch. 5 - Prob. 159CPCh. 5 - You have an equimolar mixture of the gases SO2 and...Ch. 5 - Methane (CH4) gas flows into a combustion chamber...Ch. 5 - Prob. 162CPCh. 5 - Prob. 163CPCh. 5 - Prob. 164CPCh. 5 - You have a helium balloon at 1.00 atm and 25C. You...Ch. 5 - We state that the ideal gas law tends to hold best...Ch. 5 - You are given an unknown gaseous binary compound...Ch. 5 - Prob. 168CPCh. 5 - Prob. 170IPCh. 5 - In the presence of nitric acid, UO2+ undergoes a...Ch. 5 - Silane, SiH4, is the silicon analogue of methane,...Ch. 5 - Prob. 173IPCh. 5 - Prob. 174IPCh. 5 - Prob. 175MP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY