
Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
10th Edition
ISBN: 9781305957510
Author: ZUMDAHL, Steven S.; Zumdahl, Susan A.; DeCoste, Donald J.
Publisher: Cengage Learning
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Question
Chapter 5, Problem 114E
Interpretation Introduction
Interpretation: For the given picture, three distinct changes to double the volume of a container should be explained.
Concept introduction:
- A gaseous law with interpreting the relationship between the pressure and volume of a gas at constant temperature. This law is known as Boyle’s law.
Mathematically,
or
Where,
P = pressure in atmospheres
V= volumes in liters
K= a constant for a particular gas at given temperature
- A gaseous law with interpreting the relationship between the temperature and volume of a gas at constant pressure. That is the behavior of gas towards the heat. This law is known as Charles’s law.
Mathematically this law can be written as,
Where,
T is temperature and b is proportionality constant
- A gaseous law with interpreting the relationship between the number of moles and the volume of a gas at constant temperature and pressure. This law is known as
Avogadro’s law
Mathematically this law can be written as,
Where,
n is the number of moles of gas and a is proportionality constant
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⚫ worksheets.beyondlabz.com
5 (a). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 6
5 (b). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 7
6. Are there any differences between the spectra you obtained
in Beyond Labz and the predicted spectra? If so, what were
the differences?
<
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Chapter 5 Solutions
Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
Ch. 5 - Prob. 1RQCh. 5 - Prob. 2RQCh. 5 - Prob. 3RQCh. 5 - Prob. 4RQCh. 5 - Prob. 5RQCh. 5 - Prob. 6RQCh. 5 - Prob. 7RQCh. 5 - Prob. 8RQCh. 5 - Prob. 9RQCh. 5 - Why do real gases not always behave ideally? Under...
Ch. 5 - Prob. 3ALQCh. 5 - Prob. 4ALQCh. 5 - Prob. 6ALQCh. 5 - Prob. 8ALQCh. 5 - Prob. 11ALQCh. 5 - Prob. 12ALQCh. 5 - Prob. 13ALQCh. 5 - Prob. 14ALQCh. 5 - Prob. 17ALQCh. 5 - Prob. 18ALQCh. 5 - Draw molecular-level views that show the...Ch. 5 - Prob. 22QCh. 5 - Prob. 23QCh. 5 - Prob. 24QCh. 5 - Prob. 25QCh. 5 - As weather balloons rise from the earths surface,...Ch. 5 - Prob. 27QCh. 5 - Consider two different containers, each filled...Ch. 5 - Prob. 29QCh. 5 - Prob. 32QCh. 5 - Prob. 33QCh. 5 - Prob. 34QCh. 5 - Prob. 35QCh. 5 - Prob. 36QCh. 5 - Prob. 37QCh. 5 - Without looking at a table of values, which of the...Ch. 5 - Prob. 39QCh. 5 - Prob. 40QCh. 5 - Prob. 41ECh. 5 - Prob. 42ECh. 5 - A sealed-tube manometer (as shown below) can be...Ch. 5 - Prob. 44ECh. 5 - A diagram for an open-tube manometer is shown...Ch. 5 - Prob. 46ECh. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - An 11.2-L sample of gas is determined to contain...Ch. 5 - Prob. 50ECh. 5 - Prob. 51ECh. 5 - Prob. 52ECh. 5 - Prob. 53ECh. 5 - Prob. 54ECh. 5 - The Steel reaction vessel of a bomb calorimeter,...Ch. 5 - A 5.0-L flask contains 0.60 g O2 at a temperature...Ch. 5 - Prob. 57ECh. 5 - A person accidentally swallows a drop of liquid...Ch. 5 - Prob. 59ECh. 5 - N2O is a gas commonly used to help sedate patients...Ch. 5 - A gas sample containing 1.50 moles at 25C exerts a...Ch. 5 - Prob. 62ECh. 5 - Prob. 63ECh. 5 - What will be the effect on the volume of an ideal...Ch. 5 - Prob. 65ECh. 5 - Prob. 66ECh. 5 - An ideal gas is contained in a cylinder with a...Ch. 5 - Prob. 68ECh. 5 - A sealed balloon is filled with 1.00 L helium at...Ch. 5 - Prob. 70ECh. 5 - Consider the following reaction:...Ch. 5 - A student adds 4.00 g of dry ice (solid CO2) to an...Ch. 5 - Air bags are activated when a severe impact causes...Ch. 5 - Concentrated hydrogen peroxide solutions are...Ch. 5 - In 1897 the Swedish explorer Andre tried to reach...Ch. 5 - Sulfur trioxide, SO3, is produced in enormous...Ch. 5 - A 15.0-L rigid container was charged with 0.500...Ch. 5 - An important process for the production of...Ch. 5 - Consider the reaction between 50.0 mL liquid...Ch. 5 - Urea (H2NCONH2) is used extensively as a nitrogen...Ch. 5 - Prob. 81ECh. 5 - Prob. 82ECh. 5 - Prob. 83ECh. 5 - A compound has the empirical formula CHCl. A...Ch. 5 - Prob. 85ECh. 5 - Silicon tetrachloride (SiCl4) and trichlorosilane...Ch. 5 - Prob. 87ECh. 5 - Prob. 88ECh. 5 - For scuba dives below 150 ft, helium is often used...Ch. 5 - Prob. 90ECh. 5 - Consider the flasks in the following diagram. What...Ch. 5 - Consider the flask apparatus in Exercise 85, which...Ch. 5 - Prob. 93ECh. 5 - At 0C a 1.0-L flask contains 5.0 102 mole of N2,...Ch. 5 - A mixture of cyclopropane and oxygen is sometimes...Ch. 5 - Prob. 96ECh. 5 - Prob. 97ECh. 5 - A tank contains a mixture of 52.5 g oxygen gas and...Ch. 5 - Prob. 99ECh. 5 - Helium is collected over water at 25C and 1.00 atm...Ch. 5 - At elevated temperatures, sodium chlorate...Ch. 5 - Xenon and fluorine will react to form binary...Ch. 5 - Methanol (CH3OH) can be produced by the following...Ch. 5 - In the Mthode Champenoise, grape juice is...Ch. 5 - Hydrogen azide, HN3, decomposes on heating by the...Ch. 5 - Prob. 106ECh. 5 - Prob. 107ECh. 5 - The oxides of Group 2A metals (symbolized by M...Ch. 5 - Prob. 109ECh. 5 - Prob. 110ECh. 5 - Prob. 111ECh. 5 - Prob. 112ECh. 5 - Prob. 113ECh. 5 - Prob. 114ECh. 5 - Prob. 115ECh. 5 - Prob. 116ECh. 5 - Prob. 117ECh. 5 - Prob. 118ECh. 5 - Prob. 119ECh. 5 - Prob. 120ECh. 5 - Prob. 121ECh. 5 - Prob. 122ECh. 5 - Prob. 123ECh. 5 - Prob. 124ECh. 5 - Use the data in Table 84 to calculate the partial...Ch. 5 - Prob. 126ECh. 5 - Prob. 127ECh. 5 - Prob. 128ECh. 5 - Prob. 129ECh. 5 - Prob. 130ECh. 5 - Prob. 131AECh. 5 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2,...Ch. 5 - Prob. 133AECh. 5 - Prob. 134AECh. 5 - Prob. 135AECh. 5 - Cyclopropane, a gas that when mixed with oxygen is...Ch. 5 - The nitrogen content of organic compounds can be...Ch. 5 - Hyperbaric oxygen therapy is used to treat...Ch. 5 - A 15.0L tank is filled with H2 to a pressure of...Ch. 5 - A spherical glass container of unknown volume...Ch. 5 - Prob. 141AECh. 5 - A 20.0L stainless steel container at 25C was...Ch. 5 - Metallic molybdenum can be produced from the...Ch. 5 - Prob. 144AECh. 5 - Prob. 145AECh. 5 - One of the chemical controversies of the...Ch. 5 - An organic compound contains C, H, N, and O....Ch. 5 - Prob. 148AECh. 5 - Prob. 149CWPCh. 5 - Prob. 150CWPCh. 5 - A certain flexible weather balloon contains helium...Ch. 5 - A large flask with a volume of 936 mL is evacuated...Ch. 5 - A 20.0L nickel container was charged with 0.859...Ch. 5 - Consider the unbalanced chemical equation below:...Ch. 5 - Prob. 155CWPCh. 5 - Which of the following statements is(are) true? a....Ch. 5 - A chemist weighed out 5.14 g of a mixture...Ch. 5 - A mixture of chromium and zinc weighing 0.362 g...Ch. 5 - Prob. 159CPCh. 5 - You have an equimolar mixture of the gases SO2 and...Ch. 5 - Methane (CH4) gas flows into a combustion chamber...Ch. 5 - Prob. 162CPCh. 5 - Prob. 163CPCh. 5 - Prob. 164CPCh. 5 - You have a helium balloon at 1.00 atm and 25C. You...Ch. 5 - We state that the ideal gas law tends to hold best...Ch. 5 - You are given an unknown gaseous binary compound...Ch. 5 - Prob. 168CPCh. 5 - Prob. 170IPCh. 5 - In the presence of nitric acid, UO2+ undergoes a...Ch. 5 - Silane, SiH4, is the silicon analogue of methane,...Ch. 5 - Prob. 173IPCh. 5 - Prob. 174IPCh. 5 - Prob. 175MP
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