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MOLECULAR NATURE OF MATTER 7/E LL W/AC
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- The amount of oxygen, O2, dissolved in a water sample at 25 C can be determined by titration. The first step is to add solutions of MnSO4 and NaOH to the water to convert the dissolved oxygen to MnO2. A solution of H2SO4 and KI is then added to convert the MnO2 to Mn2+, and the iodide ion is converted to I2. The I2 is then titrated with standardized Na2S2O3. (a) Balance the equation for the reaction of Mn2+ ions with O2 in basic solution. (b) Balance the equation for the reaction of MnO2 with I in acid solution. (c) Balance the equation for the reaction of S2O32 with I2. (d) Calculate the amount of O2 in 25.0 mL of water if the titration requires 2.45 mL of 0.0112 M Na2S2O3 solution.arrow_forwardWhen 85.0 mL of 0.250 M Ba(OH)2 solution is added to 85.00 mL of 0.250 M Al (NO3)3 solution, a white gelatinous precipitate of Al(OH)3; is formed. Assuming 100% yield, (a) what mass (in grams) of Al(OH)3 is formed? (b) what is the molarity of each of the ions Ba2+, OH-, Al3+, NO3- in the resulting solution?arrow_forwardUsing circles to represent cations and squares to represent anions, show pictorially the reactions that occur between aqueous solutions of (a) Fe3+ and OH-. (b) Na+ and PO43-.arrow_forward
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- The blood alcohol (C2H5OH) level can be determined by titrating a sample of blood plasma with an acidic potassium di-chromate solution, resulting in the production of Cr3+ (aq) and carbon dioxide. The reaction can be monitored because the dichromate ion (Cr2O72) is orange in solution, and the Cr3+ ion is green. The balanced equations is 16H+(aq) + 2Cr2O72(aq) + C2H5OH(aq) 4Cr4+(aq) + 2CO2(g) + 11H2O(l) This reaction is an oxidationreduction reaction. What species is reduced, and what species is oxidized? How many electrons are transferred in the balanced equation above?arrow_forwardA mountain lake that is 4.0 km × 6.0 km with an average depth of 75 m has an H+(aq) concentration of 1.3 × 10−6 M. Calculate the mass of calcium carbonate that would have to be added to the lake to change the H+(aq) concentration to 6.3 × 10−8 M. Assume that all the carbonate is converted to carbon dioxide, which bubbles out of the solution.arrow_forwardThe molarity of iodine in solution can be determined by titration with arsenious acid, H3AsO4. The unbalanced equation for the reaction is H3AsO3(aq)+I2(aq)+H2O2 I(aq)+H3AsO4(aq)+2 H+(aq)A 243-mL solution of aqueous iodine is prepared by dissolving iodine crystals in water. A fifty-mL portion of the solution requires 15.42 mL of 0.134 M H3AsO3 for complete reaction. What is the molarity of the solution? How many grams of iodine were added to the solution?arrow_forward
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