MOLECULAR NATURE OF MATTER 7/E LL W/AC
7th Edition
ISBN: 9781119664796
Author: JESPERSEN
Publisher: WILEY
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Chapter 5, Problem 2PE
Interpretation Introduction
Interpretation:
The substances which are oxidized, reduced, and the reducing and oxidizing agents in the reaction of aluminum and chlorine to form aluminum chloride are to be identified.
Concept Introduction:
Oxidation is defined as the loss of electrons during a
Reduction is defined as the gain of electrons during a chemical reaction.
An oxidizing agent is the agent or substance that donates electron(s) to other substances. During a
A reducing agent is the agent or substance that accepts electron(s) from other substances. During a redox reaction, it gets oxidized and reduces the other substance.
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Understanding how substituents activate
Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
HN
NH2
Check
X
(Choose one)
(Choose one)
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects on benzene
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Inductive Effects
Resonance Effects
Overall Electron-Density
Molecule
CF3
O donating
O donating
O withdrawing
O withdrawing
O no inductive effects
O no resonance effects
electron-rich
electron-deficient
O similar to benzene
CH3
O donating
O withdrawing
O no inductive effects
O donating
O withdrawing
Ono resonance effects
O electron-rich
O electron-deficient
O similar to benzene
Explanation
Check
Х
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* Hint: Think back to Chem 1 solubility rules.
Follow Up Questions for Part B
12. What impact do the following disturbances to a system at equilibrium have on k, the rate constant
for the forward reaction? Explain. (4 pts)
a) Changing the concentration of a reactant or product. (2 pts)
b) Changing the temperature of an exothermic reaction. (2 pts)
of
Chapter 5 Solutions
MOLECULAR NATURE OF MATTER 7/E LL W/AC
Ch. 5 - When sodium reacts with molecular oxygen, O2, the...Ch. 5 - Prob. 2PECh. 5 - The chlorite ion, ClO2, is a potent disinfectant,...Ch. 5 - Assign oxidation numbers to each atom in...Ch. 5 - Prob. 5PECh. 5 - Chlorine dioxide, ClO2, is used to kill bacteria...Ch. 5 - The following equation is nor balanced. Explain...Ch. 5 - Practice Exercise 5.8
The element technetium...Ch. 5 - Practice Exercise 5.9
Consider the following...Ch. 5 - Balance the following equation for a basic...
Ch. 5 - Write the balanced half-react ions for the...Ch. 5 - Prob. 12PECh. 5 - Suppose an aqueous mixture is prepared containing...Ch. 5 - Prob. 14PECh. 5 - Prob. 15PECh. 5 - Write a balanced equation for the combustion of...Ch. 5 - Prob. 17PECh. 5 - Prob. 18PECh. 5 - Prob. 1RQCh. 5 - Prob. 2RQCh. 5 - Prob. 3RQCh. 5 - Are the following redox reactions? Explain....Ch. 5 - If the oxidation number of nitrogen in a certain...Ch. 5 - When balancing redox reactions, which side of a...Ch. 5 - Prob. 7RQCh. 5 - What are the net charges on the left and right...Ch. 5 - In Question 5.8, which half-reaction represents...Ch. 5 - The following equation is not balanced....Ch. 5 - 5.11 What is a nonoxidizing acid? Give two...Ch. 5 - What is the strongest oxidizing agent in an...Ch. 5 - Prob. 13RQCh. 5 - Prob. 14RQCh. 5 - What is a single replacement reaction?Ch. 5 - If a metal is able to react with a solution of...Ch. 5 - Prob. 17RQCh. 5 - Prob. 18RQCh. 5 - Where in the activity series do we find the best...Ch. 5 - When manganese reacts with silver ions, is...Ch. 5 - Prob. 21RQCh. 5 - Prob. 22RQCh. 5 - Prob. 23RQCh. 5 - If one of the impurities in diesel fuel has the...Ch. 5 - Prob. 25RQCh. 5 - Prob. 26RQCh. 5 - Prob. 27RQCh. 5 - Potassium permanganate is often used for redox...Ch. 5 - Assign oxidation numbers to the atoms in the...Ch. 5 - 5.30 Assign oxidation numbers to the atoms in the...Ch. 5 - Assign oxidation numbers to each atom in the...Ch. 5 - Assign oxidation numbers to the elements...Ch. 5 - 5.33 Assign oxidation numbers to the elements in...Ch. 5 - 5.34 Assign oxidation numbers to the elements in...Ch. 5 - Titanium burns in pure nitrogen to form TiN. What...Ch. 5 - 5.36 Zirconia, which is , is used to make ceramic...Ch. 5 - 5.37 Ozone, , is an allotrope of oxygen and is one...Ch. 5 - 5.38 The other major air pollutant is . What are...Ch. 5 - For the following reactions, identify the...Ch. 5 - 5.40 For the following reactions, identify the...Ch. 5 - When chlorine is added to drinking water to kill...Ch. 5 - One pollutant in smog is nitrogen dioxide. NO2....Ch. 5 - Balance the following equations for reactions...Ch. 5 - 5.44 Balance the following equations for reactions...Ch. 5 - Prob. 45RQCh. 5 - 5.46 Balance the following equations for reactions...Ch. 5 - 5.47 Balance the equations for the following...Ch. 5 - Balance the equations for the following reactions...Ch. 5 - Prob. 49RQCh. 5 - 5.50 Hydroiodic acid reduces chlorine to...Ch. 5 - Prob. 51RQCh. 5 - Corn is grown for human consumption, feeding...Ch. 5 - Prob. 53RQCh. 5 - Laundry bleach such as Clorox is a dilute solution...Ch. 5 - Prob. 55RQCh. 5 - Chlorine is a good bleaching agent because it is...Ch. 5 - Write balanced molecular, ionic, and net ionic...Ch. 5 - 5.58 Write balanced molecular, ionic, and net...Ch. 5 - Prob. 59RQCh. 5 - Prob. 60RQCh. 5 - Prob. 61RQCh. 5 - Prob. 62RQCh. 5 - Prob. 63RQCh. 5 - Hot, concentrated sulfuric acid is a fairly strong...Ch. 5 - Use Table 5.3 to predict the outcome of the...Ch. 5 - 5.66 Use Table 5.3 to predict the outcome of the...Ch. 5 - The following reactions occur spontaneously....Ch. 5 - The following reactions occur spontaneously....Ch. 5 - Prob. 69RQCh. 5 - When chromium metal is dipped into a solution of...Ch. 5 - Write a balanced equation for the reaction...Ch. 5 - Write a balanced equation for the reaction...Ch. 5 - Write the balanced chemical equation for the...Ch. 5 - Write the balanced chemical equation for the...Ch. 5 - 5.75 Write balanced chemical equations for the...Ch. 5 - Write balanced chemical equations for the complete...Ch. 5 - 5.77 Write balanced equations for the combustion...Ch. 5 - 5.78 Write balanced equations for the combustion...Ch. 5 - 5.79 The metabolism of carbohydrates such as...Ch. 5 - Methanol, CH3OH, has been suggested as an...Ch. 5 - Write the balanced equation for the combustion of...Ch. 5 - 5.82 Thiophene, , is an impurity in crude oil and...Ch. 5 - Write chemical equations for the reaction of...Ch. 5 - Prob. 84RQCh. 5 - Prob. 85RQCh. 5 - Prob. 86RQCh. 5 - In an acidic solution, permanganate ion reacts...Ch. 5 - 5.88 In an acidic solution, bisulfite ion reacts...Ch. 5 - Prob. 89RQCh. 5 - Potable water (drinking water) should not have...Ch. 5 - 5.91 Sulfites are used worldwide in the wine...Ch. 5 - Methylbromide, CH3Br, is used in agriculture to...Ch. 5 - A sample of a copper ore with a mass of 0.4225 g...Ch. 5 - 5.94 A 1.362 g sample of an iron ore that...Ch. 5 - 5.95 Hydrogen peroxide, , solution can be...Ch. 5 - 5.96 Sodium nitrite, , is used as a preservative...Ch. 5 - Prob. 97RQCh. 5 - Prob. 98RQCh. 5 - Both calcium chloride and sodium chloride are used...Ch. 5 - 5.100 One way to analyze a sample for nitrite ion...Ch. 5 - Use oxidation numbers to show that the...Ch. 5 - Prob. 102RQCh. 5 - Prob. 103RQCh. 5 - Prob. 104RQCh. 5 - Balance the following equations using the...Ch. 5 - Prob. 106RQCh. 5 - What is the average oxidation number of carbon in...Ch. 5 - Prob. 108RQCh. 5 - In Problem 5-108, were all of the experiments...Ch. 5 - Prob. 110RQCh. 5 - 5.111 In each of the following pairs, choose the...Ch. 5 - Use Table 5.3 to predict whether the following...Ch. 5 - Sucrose, C12H22O11, is ordinary table sugar. Write...Ch. 5 - Balance the following equations by the...Ch. 5 - 5.115 Lead(IV) oxide reacts with hydrochloric acid...Ch. 5 - Prob. 116RQCh. 5 - A copper bar with a mass of 12.340 g is dipped...Ch. 5 - Prob. 118RQCh. 5 - 5.119 As described in the Chemistry Outside the...Ch. 5 - Titanium(IV) can be reduced to titanium(III) by...Ch. 5 - A researcher planned to use chlorine gas in an...Ch. 5 - 5.122 A sample of a tin ore weighing 0.3000 g was...Ch. 5 - Biodiesel is formed from the reaction of oils with...Ch. 5 - *5.124 In June 2002, the Department of Health and...Ch. 5 - An organic compound contains carbon, hydrogen, and...Ch. 5 - *5.126 A mixture is made by combining with ....Ch. 5 - A solution containing 0.1244 g of K2C2O4 was...Ch. 5 - It was found that a 20.0 mL portion of a solution...Ch. 5 - A 15.00 mL sample of a solution containing oxalic...Ch. 5 - A solution with a volume of 500.0 mL contained a...Ch. 5 - Prob. 131RQCh. 5 - We described the ion-electron method for balancing...Ch. 5 - Assuming that a chemical reaction with DNA could...Ch. 5 - Would you expect atomic oxygen and chlorine to be...Ch. 5 - Prob. 135RQCh. 5 - Prob. 136RQ
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