LAB EXPERIMENTS FOR CHEM >C<
7th Edition
ISBN: 9781323912027
Author: Brown
Publisher: PEARSON C
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 5, Problem 122IE
Consider the following acid-neutralization reactions involving the strong base NaOH(aq):
HNO3(aq) + NaOH(aq) → NaNO3(aq) + H20(l)
HCl(aq) + NaOH(aq)→NaCl(aq) + H20(l)
NH4+(aq) NaOH(aq)→NH3(aq) + Na (aq) + H20(l)
- By using data in Appendix C , calculate ΔH° for each of the reactions.
- As we saw in Section 4.3 , nitric acid and hydrochloric acid are strong acids. Write net ionic equations for the neutralization of these acids.
- Compare the values ofΔH° for the first two reactions. What can you conclude?
- In the third equation NH4+(42q) is acting as an acid. Based on the value of ΔH°for this reaction, do you think it is a strong or a weak acid? Explain.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Check the box under each structure in the table that is an enantiomer of the molecule shown below. If none of them are, check the none of the above box under
the table.
Molecule 1
Molecule 2
IZ
IN
Molecule 4
Molecule 5
ZI
none of the above
☐
Molecule 3
Х
IN
www
Molecule 6
NH
G
Highlight each chiral center in the following molecule. If there are none, then check the box under the drawing area.
There are no chiral centers.
Cl
Cl
Highlight
A student proposes the following two-step synthesis of an ether from an alcohol A:
1. strong base
A
2. R
Is the student's proposed synthesis likely to work?
If you said the proposed synthesis would work, enter the chemical
formula or common abbreviation for an appropriate strong base to use
in Step 1:
If you said the synthesis would work, draw the structure of an alcohol
A, and the structure of the additional reagent R needed in Step 2, in
the drawing area below.
If there's more than one reasonable choice for a good reaction yield,
you can draw any of them.
☐
Click and drag to start drawing a structure.
Yes
No
ロ→ロ
0|0
G
Х
D
: ☐
ப
Chapter 5 Solutions
LAB EXPERIMENTS FOR CHEM >C<
Ch. 5.2 - A mixture of gases A2 and B2 are introduced to a...Ch. 5.2 - Practice Exercise 2 Calculate the change in the...Ch. 5.3 - A solid sample of Zn(OH)2 is added to 0.350 L of...Ch. 5.3 -
Practice Exercise 2
Calculate the work, in J, if...Ch. 5.3 - Practice Exercise 1 A chemical reaction that gives...Ch. 5.3 - Prob. 5.3.2PECh. 5.4 - Prob. 5.4.1PECh. 5.4 - Prob. 5.4.2PECh. 5.5 - The coinage metals (Group 1B) copper, silver, and...Ch. 5.5 - Prob. 5.5.2PE
Ch. 5.5 - Practice Exercise 1 When 0.243 g of Mg metal is...Ch. 5.5 - Practical exercise 2 When 50.0 mL of 0.100MAgNO3...Ch. 5.5 - Prob. 5.7.1PECh. 5.5 - Practice Exercise 2 A 0.5865-g sample of lactic...Ch. 5.6 - Prob. 5.8.1PECh. 5.6 - Prob. 5.8.2PECh. 5.6 - Calculate H for the reaction C(s)+...Ch. 5.6 - Prob. 5.9.2PECh. 5.7 - Prob. 5.10.1PECh. 5.7 - Prob. 5.10.2PECh. 5.7 - Prob. 5.11.1PECh. 5.7 - Prob. 5.11.2PECh. 5.7 -
Practice Exercise 1
Given 2SO2(g) + 02(g) —>...Ch. 5.7 - Prob. 5.12.2PECh. 5.8 - Use the average bond enthalpies in Table 5.41to...Ch. 5.8 -
Use the average bond enthalpies in Table 5.4 to...Ch. 5.9 - Prob. 5.14.1PECh. 5.9 - Prob. 5.14.2PECh. 5 - One of the important ideas of thermodynamics is...Ch. 5 - Two positively charged spheres, each with a charge...Ch. 5 - SI The accompanying photo shows a pipevine...Ch. 5 - Consider the accompanying energy diagram. Does...Ch. 5 - The contents of the closed box in each of the...Ch. 5 - Imagine that you are climbing a mountain. Is the...Ch. 5 - The diagram shows four states of a system, each...Ch. 5 - You may have noticed that when you compress the...Ch. 5 - Imagine a container placed in a tub of water, as...Ch. 5 - In the accompanying cylinder diagram, a chemical...Ch. 5 - Prob. 10ECh. 5 - Consider the two diagrams that follow. Based on...Ch. 5 - Consider the conversion of compound A into...Ch. 5 - What is the electrostatic potential energy (in...Ch. 5 - What is the electrostatic potential energy (in...Ch. 5 - The electrostatic force (not energy) of attraction...Ch. 5 - Use the equations given in Problem 5.15 to...Ch. 5 - A sodium ion, Na+, with a charge of 1.6 x 10-19 C...Ch. 5 - A magnesium ion, Mg2+, with a charge of 3.2 x...Ch. 5 - Identify the force present and explain whether...Ch. 5 - Identify the force present and explain whether...Ch. 5 - Which of the following cannot leave or enter a...Ch. 5 - Prob. 22ECh. 5 - According to the first law of thermodynamics, what...Ch. 5 - Write an equation that expresses the first law of...Ch. 5 - Calculate AB and determine whether the process is...Ch. 5 - For the following processes, calculate the change...Ch. 5 - A gas is confined to a cylinder fitted with a...Ch. 5 - Consider a system consisting of two oppositely...Ch. 5 - What is meant by the term state function? Give an...Ch. 5 - Indicate which of the following is independent of...Ch. 5 - During a normal breath, our lungs expand about...Ch. 5 - How much work (in J) is involved in a chemical...Ch. 5 - Why is the change in enthalpy usually easier to...Ch. 5 - Under what condition will the enthalpy change of a...Ch. 5 - Assume that the following reaction occurs at...Ch. 5 - Suppose that the gas-phase reaction 2NO(g) + 02(g)...Ch. 5 - A gas is confined to a cylinder under constant...Ch. 5 - A gas is confined to a cylinder under constant...Ch. 5 - The complete combustion of ethanol, C2H5OH(l), to...Ch. 5 - The decomposition of Ca(OH)2(s) into CaO(s) and...Ch. 5 - Ozone, 03(9), is a form of elemental oxygen that...Ch. 5 -
5.42 Without referring to tables, predict which...Ch. 5 - Consider the following reaction: 2 Mg(s) + 02(g)2...Ch. 5 -
544 Consider the following reaction:
2...Ch. 5 - When solutions containing silver ions and chloride...Ch. 5 - At one time, a common means of forming small...Ch. 5 -
5.47 Consider the combustion of liquid methanol,...Ch. 5 -
5.48 Consider the decomposition of liquid...Ch. 5 - 5.49
a What are the units of molar heat...Ch. 5 - Two solid objects, A and B, are placed in boiling...Ch. 5 - What is the specific heat of liquid water? What is...Ch. 5 -
5.52
a. Which substance in Table 5.2 requires...Ch. 5 - The specific heat of octane, C8H18(l), is 2.22...Ch. 5 -
6.54 Consider the data about gold metal in...Ch. 5 - When a 6-50-g sample of solid sodium hydroxide...Ch. 5 -
5.56
a. When a 4 25-g sample of solid ammonium...Ch. 5 - A 2.200-g sample of quinone (C5H402) is burned in...Ch. 5 -
8.68 A 1.800-g sample of phenol (C6H5OH) was...Ch. 5 - Under constant-volume conditions, the heat of...Ch. 5 -
5.60 Under constant-volume conditions, the heat...Ch. 5 -
5.61 Can you use an approach similar to Hess's...Ch. 5 -
5.62 Consider the following hypothetical...Ch. 5 - Calculate the enthalpy change for the reaction...Ch. 5 - From the enthalpies of reaction calculate H for...Ch. 5 - From the enthalpies of reaction Calculate H for...Ch. 5 - Given the data use Hess's law to calculate H for...Ch. 5 -
5.67
What is meant by the term standard...Ch. 5 - S
5.68
What is the value of the standard enthalpy...Ch. 5 - For each of the following compounds, write a...Ch. 5 - Write balanced equations that describe the...Ch. 5 - The following is known as the thermite reaction:...Ch. 5 -
5.72 Many portable gas heaters and grills use...Ch. 5 - Using values from Appendix C , calculate the...Ch. 5 -
5.74 Using values from Appendix C, calculate the...Ch. 5 - Complete combustion of 1 mol of acetone (C2H6O)...Ch. 5 - Calcium carbide (CaC2) reacts with water to form...Ch. 5 -
5.77 Gasoline is composed primarily of...Ch. 5 - Prob. 78ECh. 5 - Ethanol (C2H5OH) is blended with gasoline as an...Ch. 5 -
5.80 Methanol (CH3OH) is used as a fuel in race...Ch. 5 -
5.81 Without doing any calculations, predict the...Ch. 5 -
5.82 Without doing any calculations, predict...Ch. 5 - Use bond enthalpies in Table 5.4 Q to estimate for...Ch. 5 - Use bond enthalpies in Table 5.40 to estimate for...Ch. 5 - Use enthalpies of formation given in Appendix C to...Ch. 5 -
5.86
The nitrogen atoms in an N2 molecule are...Ch. 5 -
5.87 Consider the reaction 2H(g) + O2(g) ...Ch. 5 -
5.88 Consider the reaction H2(g) + I2(s) ...Ch. 5 -
5.89
What is meant by the term fuel value?
Which...Ch. 5 -
5.90
Which releases the most energy when...Ch. 5 -
5.91
A serving of a particular ready-to-serve...Ch. 5 -
5.92 A pound of plain M&M® candies contains 96 g...Ch. 5 -
5.93 The heat of combustion of fructose,...Ch. 5 -
5.94 The heat of combustion of ethanol,...Ch. 5 -
5.95 The standard enthalpies of formation of...Ch. 5 -
5.98 It is interesting to compare the ‘fuel...Ch. 5 - At the end of 2012, global population was about...Ch. 5 -
5.98 The automobile fuel called E85 consists of...Ch. 5 - The air bags that provide protection in...Ch. 5 -
5.100 An aluminum can of a soft drink is placed...Ch. 5 -
5.101 Consider a system consisting of the...Ch. 5 - A sample of gas is contained in a...Ch. 5 - Limestone stalactites and stalagmites are formed...Ch. 5 - Consider the systems shown in Figure 5.10. In one...Ch. 5 -
5.105 A house is designed to have passive solar...Ch. 5 -
5.108 A coffee-cup calorimeter of the type shown...Ch. 5 -
5.107
When a 0.235-9 sample of benzoic acid is...Ch. 5 -
5.108 Meals-ready-to-eat (MREs) are military...Ch. 5 - 5.109 Burning methane in oxygen can produce three...Ch. 5 - Prob. 110AECh. 5 -
5.111 From the following data for three...Ch. 5 - The hydrocarbons acetylene (C2H2) and benzene...Ch. 5 - Ammonia (NH3) boils at -33 °C; at this temperature...Ch. 5 -
5.114 Three common hydrocarbons that contain four...Ch. 5 -
5.115 A 201-lb man decides to add to his exercise...Ch. 5 -
5.116 TheSun supplies about 1.0 kilowatt of...Ch. 5 -
5.117 Itis estimated that the net amount of...Ch. 5 -
5.118 At 20 °C (approximately room temperature)...Ch. 5 - Suppose an Olympic diver who weighs 52.0 kg...Ch. 5 -
5.120 Consider the combustion of a single...Ch. 5 -
5.121 Consider the following unbalanced...Ch. 5 - Consider the following acid-neutralization...Ch. 5 -
5.123 Consider two solutions, the first being...Ch. 5 - The precipitation reaction between AgNO3(aq) and...Ch. 5 -
5.125 A sample of a hydrocarbon is combusted...Ch. 5 -
5.126 The methane molecule, CH4, has the geometry...Ch. 5 -
5.127 One of the best-selling light, or...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- टे Predict the major products of this organic reaction. Be sure to use wedge and dash bonds when necessary, for example to distinguish between different major products. ☐ ☐ : ☐ + NaOH HO 2 Click and drag to start drawing a structure.arrow_forwardShown below are five NMR spectra for five different C6H10O2 compounds. For each spectrum, draw the structure of the compound, and assign the spectrum by labeling H's in your structure (or in a second drawing of the structure) with the chemical shifts of the corresponding signals (which can be estimated to nearest 0.1 ppm). IR information is also provided. As a reminder, a peak near 1700 cm-1 is consistent with the presence of a carbonyl (C=O), and a peak near 3300 cm-1 is consistent with the presence of an O–H. Extra information: For C6H10O2 , there must be either 2 double bonds, or 1 triple bond, or two rings to account for the unsaturation. There is no two rings for this problem. A strong band was observed in the IR at 1717 cm-1arrow_forwardPredict the major products of the organic reaction below. : ☐ + Х ك OH 1. NaH 2. CH₂Br Click and drag to start drawing a structure.arrow_forward
- NG NC 15Show all the steps you would use to synthesize the following products shown below using benzene and any organic reagent 4 carbons or less as your starting material in addition to any inorganic reagents that you have learned. NO 2 NC SO3H NO2 OHarrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forwardShow work...don't give Ai generated solutionarrow_forward
- 1 Please provide an efficient synthesis of the product below from the starting material. Use the starting material as the ONLY source of carbon atoms. Show the synthesis of each compound that would be used in the overall synthesis of the product. [This synthesis uses alkyne and alcohol chemistry.]arrow_forward10- 4000 20 20 30- %Reflectance 60 50- 09 60- 40- Date: Thu Feb 06 17:30:02 2025 (GMT-05:0(UnknownP Scans: 8 Resolution: 2.000 70 70 88 80 3500 3000 2500 90 100 00 Wavenumbers (cm-1) 2000 1500 2983.10 2359.13 1602.52 1584.22 1451.19 1391.87 1367.07 1314.37 1174.34 1070.13 1027.33 1714.16 1269.47 1000 1106.08 1001.14 937.02 873.60 850.20 780.22 686.91 674.38 643.09 617.98 02/06/25 16:38:20arrow_forwardd. Draw arrow-pushing mechanism for an enzymatic retro-aldol reaction of the following hexose. Use B: and/or HA as needed. OH OH سية HO OH OHarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY