For a given condition, the pressure should be determined and compared by using ideal gas law , and Van der Waals equation at V= 1.00L and V=10.00L Concept introduction: By combining the three gaseous laws namely Boyle’s law, Charles’s law and Avogadro’s law a combined gaseous equation is obtained. This combined gaseous equation is called Ideal gas law . According to ideal gas law, P V = n R T Where, P = pressure in atmospheres V= volumes in liters n = number of moles R =universal gas constant ( 0.08206 L ⋅ a t m / K ⋅ m o l ) T = temperature in kelvins A modified ideal gas equation on account of molecular size and molecular interaction forces is termed as Van der Waals equation. That is, [ P + a ( n V ) 2 ] ( V - n b ) = n R T ‘a’ and ‘b’ is called Van der Waals coefficient and are characteristic of the individual gas Where, P = pressure in atmospheres V= volumes in liters n = number of moles R =universal gas constant ( 0.08206 L ⋅ a t m / K ⋅ m o l ) T = temperature in kelvins

Question

Predict the major products of the following organic reaction: NC Δ ? Some important Notes: • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. • Be sure to draw bonds carefully to show important geometric relationships between substituents. Note: if your answer contains a complicated ring structure, you must use one of the molecular fragment stamps (available in the menu at right) to enter the ring structure. You can add any substituents using the pencil tool in the usual way. Click and drag to start drawing a structure. Х а

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Question

Chapter 5, Problem 116E

Interpretation Introduction

Interpretation: For a given condition, the pressure should be determined and compared by using ideal gas law, and Van der Waals equation at V= 1.00L and V=10.00L

Concept introduction:

By combining the three gaseous laws namely Boyle’s law, Charles’s law and Avogadro’s law a combined gaseous equation is obtained. This combined gaseous equation is called Ideal gas law.

According to ideal gas law,

PV=nRT

Where,

P = pressure in atmospheres

V= volumes in liters

n = number of moles

R =universal gas constant ( 0.08206L⋅atm/K⋅mol )

T = temperature in kelvins

A modified ideal gas equation on account of molecular size and molecular interaction forces is termed as Van der Waals equation.

That is, [P+a(nV)2](V-nb) = nRT

‘a’ and ‘b’ is called Van der Waals coefficient and are characteristic of the individual gas

Where,

P = pressure in atmospheres

V= volumes in liters

n = number of moles

R =universal gas constant ( 0.08206L⋅atm/K⋅mol )

T = temperature in kelvins

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