Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 4.9, Problem 29P

(a)

Interpretation Introduction

Interpretation:

The specific rotation of (R)-(-)-monosodium has to be calculated.

Concept introduction:

The pair of Enantiomers has different configurations.

Pair of enantiomers has different optical activity, which means if one will show levorotatory then the other will show dextrorotatory.

The direction and magnitude of rotation of plane-polarized light by an optically compound is measured by using polarimeter.

This rotation of polarized light is specific for a compound at specified temperature and wavelength, so it is called as Specific rotation of that compound.

The specific rotation of enantiomers has equal magnitudes and opposite signs.

Racemic mixture (equal amounts of enantiomers) of a compound has zero specific rotation.

(b)

Interpretation Introduction

Interpretation:

The specific rotation of racemic mixture of monosodium glutamate has to be calculated.

Concept introduction:

The pair of Enantiomers has different configurations.

Pair of enantiomers has different optical activity, which means if one will show levorotatory then the other will show dextrorotatory.

The direction and magnitude of rotation of plane-polarized light by an optically compound is measured by using polarimeter.

This rotation of polarized light is specific for a compound at specified temperature and wavelength, so it is called as Specific rotation of that compound.

The specific rotation of enantiomers has equal magnitudes and opposite signs.

Racemic mixture (equal amounts of enantiomers) of a compound has zero specific rotation.

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(S)-(+)-Monosodium glutamate (MSG) is a flavor enhancer used in many foods. Some people have an allergic reaction to MSG (including headache, chest pain, and an overall feeling of weakness). Fast food often contains substantial amounts of MSG, which is widely used in Chinese food as well. (S)-(+)-MSG has a specific rotation of +24.a. What is the specific rotation of (R)-(-)-monosodium glutamate? b. What is the specific rotation of a racemic mixture of MSG?
(S)-(+)-Monosodium glutamate (MSG) is a flavor enhancer used in many foods. Some people have an allergic reaction to MSG (including headache, chest pain, and an overall feeling of weakness). "Fast food" often contains substantial amounts of MSG, which is widely used in Chinese food as well. (S)-(+)-MSG has a specific rotation of +24.  a). What is the specific rotation of (R)-(−)-monosodium glutamate? b). What is the specific rotation of a racemic mixture of MSG?
The specific rotation of quinine, an anti-malarial drug, is -165°. How much quinine (in %) is present in a sample that has an observed specific rotation of 33°? CH3O HO H H quinine (antimalarial drug)

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Essential Organic Chemistry (3rd Edition)

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