Whether the single Raman band consistent with the trans orientation of the oxygen atoms in structure of IO 2 F 5 2 − ion or not needs to be explained. Concept introduction: A vibration is said to be Raman active if the symmetry matches for the functions xy, xz, yz, x 2 , y 2 or z 2 or their linear combinations. If any vibration matches with these functions, there must be change in polarizability. They are with other functions which are listed in the character tables.

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Answer 1

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Chapter 4.4, Problem 4.14E

Interpretation Introduction

Interpretation: Whether the single Raman band consistent with the trans orientation of the oxygen atoms in structure of IO2F52− ion or not needs to be explained.

Concept introduction: A vibration is said to be Raman active if the symmetry matches for the functions xy, xz, yz, x2,y2or z2 or their linear combinations. If any vibration matches with these functions, there must be change in polarizability. They are with other functions which are listed in the character tables.

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Answer 2

Question

Chapter 4.4, Problem 4.14E

Interpretation Introduction

Interpretation: Whether the single Raman band consistent with the trans orientation of the oxygen atoms in structure of IO2F52− ion or not needs to be explained.

Concept introduction: A vibration is said to be Raman active if the symmetry matches for the functions xy, xz, yz, x2,y2or z2 or their linear combinations. If any vibration matches with these functions, there must be change in polarizability. They are with other functions which are listed in the character tables.

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Check out a sample textbook solution

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Answer 3

Question

Chapter 4.4, Problem 4.14E

Interpretation Introduction

Interpretation: Whether the single Raman band consistent with the trans orientation of the oxygen atoms in structure of IO2F52− ion or not needs to be explained.

Concept introduction: A vibration is said to be Raman active if the symmetry matches for the functions xy, xz, yz, x2,y2or z2 or their linear combinations. If any vibration matches with these functions, there must be change in polarizability. They are with other functions which are listed in the character tables.

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Answer 4

Question

Chapter 4.4, Problem 4.14E

Interpretation Introduction

Interpretation: Whether the single Raman band consistent with the trans orientation of the oxygen atoms in structure of IO2F52− ion or not needs to be explained.

Concept introduction: A vibration is said to be Raman active if the symmetry matches for the functions xy, xz, yz, x2,y2or z2 or their linear combinations. If any vibration matches with these functions, there must be change in polarizability. They are with other functions which are listed in the character tables.

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Answer 5

Chapter 4.4, Problem 4.14E

Interpretation Introduction

Interpretation: Whether the single Raman band consistent with the trans orientation of the oxygen atoms in structure of IO2F52− ion or not needs to be explained.

Concept introduction: A vibration is said to be Raman active if the symmetry matches for the functions xy, xz, yz, x2,y2or z2 or their linear combinations. If any vibration matches with these functions, there must be change in polarizability. They are with other functions which are listed in the character tables.

Answer 6

Chapter 4.4, Problem 4.14E

Interpretation Introduction

Interpretation: Whether the single Raman band consistent with the trans orientation of the oxygen atoms in structure of IO2F52− ion or not needs to be explained.

Concept introduction: A vibration is said to be Raman active if the symmetry matches for the functions xy, xz, yz, x2,y2or z2 or their linear combinations. If any vibration matches with these functions, there must be change in polarizability. They are with other functions which are listed in the character tables.

Answer 7

Chapter 4.4, Problem 4.14E

Interpretation Introduction

Interpretation: Whether the single Raman band consistent with the trans orientation of the oxygen atoms in structure of IO2F52− ion or not needs to be explained.

Concept introduction: A vibration is said to be Raman active if the symmetry matches for the functions xy, xz, yz, x2,y2or z2 or their linear combinations. If any vibration matches with these functions, there must be change in polarizability. They are with other functions which are listed in the character tables.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 4.1 - Prob. 4.1E Ch. 4.1 - Find all the symmetry elements in the following...Ch. 4.2 - Use the procedure described previously to verify...Ch. 4.3 - Prob. 4.4E Ch. 4.3 - Verify the transformation matrices for the E and...Ch. 4.3 - Prepare a representation flowchart according to...Ch. 4.4 - Which point groups are possible for chiral...Ch. 4.4 - Write the corresponding 99 transformation matrices...Ch. 4.4 - Using the x, y, and z coordinates for each atom in...Ch. 4.4 - Reduce the following representations to their...

Solution Summary: The author explains whether a single Raman band is consistent with the trans orientation of the oxygen atoms in structure of mathrmIO_2

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