Given compound has to be named. Concept Introduction: Nomenclature of bicyclic compounds: The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are, Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent. Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path. Arrange the substituents alphabetically. In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Question

Give the structure(s) of the product(s) the reaction below, and be sure to indicate any relative stereochemistry (you can assume that each of the Diels-Alder reactions will proceed with endo selectivity). Draw out relevant enantiomer(s) if they are expected to form. If no reaction is expected to occur under the indicated conditions, then write "no reaction" or NR, and explain why you would expect nothing to occur. If more than one product is formed, please indicate which one will be the major product or if they will be formed in equal amounts. In all cases, equimolar amounts of both components/reagents are present unless indicated otherwise I'm struggling to see how this reaction will go! I am wondering if it will cycle on itself but I'm not sure how I drew out a decagon but I'm a bit lost

Answer 1

Question

Chapter 4.2, Problem 11PTS

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] (each number represent number of carbon atoms) and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(e)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

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Give the structure(s) of the product(s) the reaction below, and be sure to indicate any relative stereochemistry (you can assume that each of the Diels-Alder reactions will proceed with endo selectivity). Draw out relevant enantiomer(s) if they are expected to form. If no reaction is expected to occur under the indicated conditions, then write "no reaction" or NR, and explain why you would expect nothing to occur. If more than one product is formed, please indicate which one will be the major product or if they will be formed in equal amounts. In all cases, equimolar amounts of both components/reagents are present unless indicated otherwise I'm struggling to see how this reaction will go! I am wondering if it will cycle on itself but I'm not sure how I drew out a decagon but I'm a bit lost

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Answer 2

Question

Chapter 4.2, Problem 11PTS

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] (each number represent number of carbon atoms) and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(e)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

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Answer 3

Question

Chapter 4.2, Problem 11PTS

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] (each number represent number of carbon atoms) and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(e)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Expert Solution & Answer

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Answer 4

Question

Chapter 4.2, Problem 11PTS

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] (each number represent number of carbon atoms) and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(e)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Expert Solution & Answer

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Answer 5

Chapter 4.2, Problem 11PTS

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] (each number represent number of carbon atoms) and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

(e)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 6

Chapter 4.2, Problem 11PTS

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 7

Chapter 4.2, Problem 11PTS

(a)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] (each number represent number of carbon atoms) and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] (each number represent number of carbon atoms) and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Given compound has to be named.

Concept Introduction:

Nomenclature of bicyclic compounds:

The organic compound naming is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Identify and the parent: The term ‘Bicylo-’ is introduced in the name of the parent. Count the number of carbons excluding the bridge heads. In the compound below, each of the three paths has two carbons. These three numbers are ordered from largest to smallest, as [2.2.2] and placed in the middle of the parent.

Identify and name substituents: If substituent is present, the parent must be numbered properly in order to assign the locants to the substituent. To number the parent, start at one of the bridgeheads and begin numbering along the longest path, then go to the second longest path, and finally go along the shortest path.

Arrange the substituents alphabetically.

In the complex substituent in compounds, the substituent name is assigned by a name each of them based on numbers going away from the parent.

Answer 16

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Answer 17

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Answer 27

Ch. 4.2 - Prob. 1LTS Ch. 4.2 - Prob. 1PTS Ch. 4.2 - Prob. 2PTS Ch. 4.2 - Prob. 3ATS Ch. 4.2 - Prob. 2LTS Ch. 4.2 - Prob. 4PTS Ch. 4.2 - Prob. 5ATS Ch. 4.2 - Prob. 3LTS Ch. 4.2 - Prob. 6PTS Ch. 4.2 - Prob. 7ATS

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Chapter 4 Solutions