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(a)
Interpretation:
The systematic name for the following compound should be determined.
Concept Introduction:
Compounds consisting of carbon and hydrogen are known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula
Rules of naming
- First, choose the longest continuous chain of carbon atoms known as the parent chain and determines the base name of the alkane.
- The numbering of the parent chain should be done in a way that the substituents get the lowest number.
- The appropriate name should be given to every alkyl group and denote its position on the parent chain with the number.
- The alkyl groups are written in alphabetical order.
(b)
Interpretation:
The systematic name for the following compound should be determined.
Concept Introduction:
Compounds consisting of carbon and hydrogen are known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula
Rules of naming alkanes are:
- First, choose the longest continuous chain of carbon atoms known as the parent chain and determines the base name of the alkane.
- The numbering of the parent chain should be done in a way that the substituents get the lowest number.
- The appropriate name should be given to every alkyl group and denote its position on the parent chain with the number.
- The alkyl groups are written in alphabetical order.
(c)
Interpretation:
The systematic name for the following compound should be determined.
Concept Introduction:
Compounds consisting of carbon and hydrogen are known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula
Rules of naming alkanes are:
- First, choose the longest continuous chain of carbon atoms known as the parent chain and determines the base name of the alkane.
- The numbering of the parent chain should be done in a way that the substituents get the lowest number.
- The appropriate name should be given to every alkyl group and denote its position on the parent chain with the number.
- The alkyl groups are written in alphabetical order.
(d)
Interpretation:
The systematic name for the following compound should be determined.
Concept Introduction:
Compounds consisting of carbon and hydrogen are known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula
The compounds in which a series of atoms are connected to form a ring is known as cyclic compound whereas the compounds which are open chain compounds and their atoms don't form a ring is known as acyclic compounds. The general molecular formula of a cyclic alkane is
Rules of naming cycloalkanes are:
- First, determine the cycloalkane present in the structure which is considered as a parent chain (maximum number of carbon atoms). If the acyclic alkane chain has more carbon atoms, then the alkyl chain is considered a parent chain.
- For a cyclic system, the number of carbon atoms must be identified as present in different paths connected with two bridgeheads.
- The numbering of the parent chain should be done in a way that the substituents get the lowest number.
- The appropriate name should be given to every alkyl group or cycloalkyl group and denote its position on the parent chain with the number
- The alkyl groups or cycloalkyl groups are written in alphabetical order.
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Chapter 4 Solutions
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
- 3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…arrow_forwardA chemistry graduate student is studying the rate of this reaction: 2 HI (g) →H2(g) +12(g) She fills a reaction vessel with HI and measures its concentration as the reaction proceeds: time (minutes) [IH] 0 0.800M 1.0 0.301 M 2.0 0.185 M 3.0 0.134M 4.0 0.105 M Use this data to answer the following questions. Write the rate law for this reaction. rate = 0 Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.arrow_forwardNonearrow_forward
- in which spectral range of EMR, atomic and ionic lines of metal liesarrow_forwardQ2: Label the following molecules as chiral or achiral, and label each stereocenter as R or S. CI CH3 CH3 NH2 C CH3 CH3 Br CH3 X &p Bra 'CH 3 "CH3 X Br CH3 Me - N OMe O DuckDuckarrow_forward1. For the four structures provided, Please answer the following questions in the table below. a. Please draw π molecular orbital diagram (use the polygon-and-circle method if appropriate) and fill electrons in each molecular orbital b. Please indicate the number of π electrons c. Please indicate if each molecule provided is anti-aromatic, aromatic, or non- aromatic TT MO diagram Number of π e- Aromaticity Evaluation (X choose one) Non-aromatic Aromatic Anti-aromatic || ||| + IVarrow_forward
- 1.3 grams of pottasium iodide is placed in 100 mL of o.11 mol/L lead nitrate solution. At room temperature, lead iodide has a Ksp of 4.4x10^-9. How many moles of precipitate will form?arrow_forwardQ3: Circle the molecules that are optically active: ДДДДarrow_forward6. How many peaks would be observed for each of the circled protons in the compounds below? 8 pts CH3 CH3 ΤΙ A. H3C-C-C-CH3 I (₁₁ +1)= 7 H CI B. H3C-C-CI H (3+1)=4 H LIH)=2 C. (CH3CH2-C-OH H D. CH3arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
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