EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
4th Edition
ISBN: 9781119659525
Author: Klein
Publisher: WILEY CONS
Question
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Chapter 4, Problem 57PP

(a)

Interpretation Introduction

Interpretation:

The total energy cost associated with all torsional strain and steric strain of given conformations are needed to find out using table 4.6.

Concept introduction:

Conformations are arising due to the free rotation of CC bond. These rotations are measured by dihedral angle; it is the angle between two atoms attached to two different carbons of CC rotation in Newman projection.

The torsional strain between atoms of eclipsed conformations makes them more energized as compared to staggered conformations.

For eclipsed conformations, Torsional strain and steric interactions of atoms are the energizing factors.

For staggered conformations, anti-interactions and gauche interactions of atoms are the energizing factors.

Table 4.6

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG, Chapter 4, Problem 57PP , additional homework tip  1

To find: the total energy cost associated with all torsional strain and steric strain of given conformations.

(b)

Interpretation Introduction

Interpretation:

The total energy cost associated with all torsional strain and steric strain of given conformations are needed to find out using table 4.6.

Concept introduction:

Conformations are arising due to the free rotation of CC bond. These rotations are measured by dihedral angle; it is the angle between two atoms attached to two different carbons of CC rotation in Newman projection.

The torsional strain between atoms of eclipsed conformations makes them more energized as compared to staggered conformations.

For eclipsed conformations, Torsional strain and steric interactions of atoms are the energizing factors.

For staggered conformations, anti-interactions and gauche interactions of atoms are the energizing factors.

Table 4.6

EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG, Chapter 4, Problem 57PP , additional homework tip  2

To find: the total energy cost associated with all torsional strain and steric strain of given conformations.

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