Physics for Scientists and Engineers with Modern Physics
10th Edition
ISBN: 9781337553292
Author: Raymond A. Serway, John W. Jewett
Publisher: Cengage Learning
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Chapter 41, Problem 26P
To determine
The table for electronic configuration of atoms containing 11 through 19 electrons.
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3. Consider a monatomic linear with equilibrium separation a. Suppose the outer
electrons (of mass m) in a given atom move with a displacement different from that
of the corresponding ion core (of mass M). Let the displacement of the ion core s be:
Us = uei(Ksa-wt)
and the displacement of the center of mass of the outer electrons associated with ion s
be:
V = vei(Ksa-wt)
Each ion core is assumed to interact only with its own outer electrons with a force
proportional to the displacement of the electron distribution from the nucleus, and the
force constant is C₂. However, neighboring electron distributions interact with a force
constant C₁.
a) Show that
-w² Mus = C₂ (vs - Us)
-w²mvs = C₂ (us - Vs) + C₁ (Vs+1 + Vs-1-2vs)
b) Substitute for the displacements, and solve the resulting simultaneous equations.
Find an expression for w².
c) Take the limit as m → 0 (the mass of electrons is much smaller than that of the ion
core), and show that the dispersion relation for the acoustic mode is…
Describe how the structure of atoms would differ if the Pauli exclusion principle were not valid. What consequences would follow, both at the atomic level and in the world at large?
B/ answer with the word true or
false and correct the error,
1- The total energy of the electron
is usually greater than zero. If
2)the electron moves from one
orbit to another higher than it, the
velocity of the electron in the higher
orbit increases
3- The hydrogen bond is mostly ionic
4) The probability of the existence
of an electron at a level higher than
the Fermi level at absolute zero is
50%
5) Propagation current arises from
the effect of an electric field on a
metal.
Chapter 41 Solutions
Physics for Scientists and Engineers with Modern Physics
Ch. 41.3 - Prob. 41.1QQCh. 41.3 - Prob. 41.2QQCh. 41.4 - Prob. 41.3QQCh. 41.4 - Prob. 41.4QQCh. 41.8 - Prob. 41.5QQCh. 41 - Prob. 1PCh. 41 - Prob. 2PCh. 41 - Prob. 3PCh. 41 - Prob. 4PCh. 41 - Prob. 5P
Ch. 41 - Prob. 6PCh. 41 - Prob. 7PCh. 41 - Prob. 8PCh. 41 - Prob. 9PCh. 41 - Prob. 10PCh. 41 - Prob. 11PCh. 41 - Prob. 13PCh. 41 - Prob. 14PCh. 41 - Prob. 15PCh. 41 - Prob. 16PCh. 41 - Prob. 17PCh. 41 - Prob. 18PCh. 41 - Prob. 19PCh. 41 - Prob. 20PCh. 41 - Prob. 21PCh. 41 - Prob. 23PCh. 41 - Prob. 24PCh. 41 - Prob. 25PCh. 41 - Prob. 26PCh. 41 - Prob. 27PCh. 41 - Prob. 28PCh. 41 - Prob. 29PCh. 41 - Prob. 30PCh. 41 - Prob. 31PCh. 41 - Prob. 32PCh. 41 - Prob. 33PCh. 41 - Prob. 34PCh. 41 - Prob. 35PCh. 41 - Prob. 36PCh. 41 - Prob. 37APCh. 41 - Prob. 39APCh. 41 - Prob. 40APCh. 41 - Prob. 41APCh. 41 - Prob. 42APCh. 41 - Prob. 44APCh. 41 - Prob. 45APCh. 41 - Prob. 46APCh. 41 - Prob. 47APCh. 41 - Prob. 49APCh. 41 - Prob. 50APCh. 41 - Prob. 51CPCh. 41 - Prob. 52CP
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- What is Pauli's exclusion principle? Explain the importance of this principle for the understanding of atomic structure and molecular bonding.arrow_forward(a) How many electrons can be in the n = 4 shell? (b) What are its subshells, and how many elections can be in each?arrow_forwardThe valence election of chlorine is excited to a 3p state, (a) What is the magnitude of the election's orbital angular momentum? (b) What are possible values for the z-component of angular’ measurement?arrow_forward
- As an alternative to Equation 42.1, another useful model for the potential energy of a diatomic molecule is the Morse potential U(r)=B[ea(rr0)1]2 where B, a, and r0 are parameters used to adjust the shape of the potential and its depth. (a) What is the equilibrium separation of the nuclei? (b) What is the depth of the potential well, defined as the difference in energy between the potentials minimum value and its asymptote as r approaches infinity? (c) If is the reduced mass of the system of two nuclei and assuming the potential is nearly parabolic about the well minimum, what is the vibrational frequency of the diatomic molecule in its ground state? (d) What amount of energy needs to be supplied to the ground-state molecule to separate the two nuclei to infinity?arrow_forwardConsider hydrogen in the ground state, 100 . (a) Use the derivative to determine the radial position for which the probability density, P(r), is a maximum. (b) Use the integral concept to determine the average radial position. (This is called the expectation value of the electrons radial position.) Express your answers into terms of the Bohr radius, a0. Hint: The expectation value is the just average value, (c) Why are these values different?arrow_forwardWhy does the graph in Figure 9.12 increase gradually from the origin? Figure 9.12 (a) Density of state for a free electron gas; (b) probability that a state is occupied at T = 0 K; (c) density if occupied states at T = 0 k.arrow_forward
- c. n= 2, 1 = 0. 2. Calculate the maximum number of electrons that can occupy a shell with (a) n = 2, (b) n = 3, and (c) n as a variable. Note you are only looking at the orbitals with the specified n value, not those at lower energies.arrow_forwardProblem: Please Derive The Equation of States of Van Der Waals. The Equation iis: (p+2)(Vu –b) = RT WM-b) = RT V You are asked to proof the value of: 27 R Tc 1 RTc dan b 64 Pc 8 Pearrow_forward5. a) Sketch a polar diagram of the directional dependence of the probability density of a problem of a atom with only one electron for I = 2, ml = 0. b) At what angle 0 does the probability density have its minimum value? c) Where the angular probability density has a value of a quarter of its maximum value?arrow_forward
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