Physics for Scientists and Engineers with Modern Physics
10th Edition
ISBN: 9781337553292
Author: Raymond A. Serway, John W. Jewett
Publisher: Cengage Learning
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Chapter 41, Problem 15P
To determine
To plot the wave function and probability density function of the for the hydrogen atom.
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The time-independent
w (r) =
√
1
P =
wavefunction of the ground state of the hydrogen electron is a function of radial position r.
y
3/2
elas
In the equation, ao 0.0529 nm is the Bohr radius.
What is the probability P of finding the hydrogen electron within a spherical shell of inner radius 0.00600 nm and outer radius
0.0316 nm?
The average value (or expected value) of r^k, where r is the distance of an electron in the state with principal quantum number n and orbital quantum number leo proton in the hydrogen atom is given by the integral below, where Pnl(r) is a radial probability density of the state with quantum number n, lek is an arbitrary power. For an electron in the ground state of the hydrogen atom.
a) calculate <r>nl in terms of the Bohr radius aB
b) calculate <l/r>nl in terms of aB
c) calculate <U(r)>nl, where U(r) = -e^2/(4piE0r). Respond in eV units.
d) Considering also that the electron is in the ground state, estimate the expected value for two kinetic energy <K> and its mean quadratic velocity v.
e) Is it justifiable to disregard relativistic corrections for this system? Justify.
If, in
1
1
= Ry
-
you set ni = 1 and take n2 greater than 1,
you generate what is known as the Lyman
%3D
series.
Find the wavelength of the first mem-
ber of this series.
The value of ħ is
1.05457 × 10¬34 J.s; the Rydberg constant
for hydrogen is 1.09735 × 10’ m¬'; the Bohr
radius is 5.29177 × 10¬1" m; and the ground
state energy for hydrogen is 13.6057 eV.
Answer in units of nm.
Consider the next three members of this se-
ries. The wavelengths of successive members
of the Lyman series approach a common limit
as n2 → ∞.
What is this limit?
Answer in units of nm.
Chapter 41 Solutions
Physics for Scientists and Engineers with Modern Physics
Ch. 41.3 - Prob. 41.1QQCh. 41.3 - Prob. 41.2QQCh. 41.4 - Prob. 41.3QQCh. 41.4 - Prob. 41.4QQCh. 41.8 - Prob. 41.5QQCh. 41 - Prob. 1PCh. 41 - Prob. 2PCh. 41 - Prob. 3PCh. 41 - Prob. 4PCh. 41 - Prob. 5P
Ch. 41 - Prob. 6PCh. 41 - Prob. 7PCh. 41 - Prob. 8PCh. 41 - Prob. 9PCh. 41 - Prob. 10PCh. 41 - Prob. 11PCh. 41 - Prob. 13PCh. 41 - Prob. 14PCh. 41 - Prob. 15PCh. 41 - Prob. 16PCh. 41 - Prob. 17PCh. 41 - Prob. 18PCh. 41 - Prob. 19PCh. 41 - Prob. 20PCh. 41 - Prob. 21PCh. 41 - Prob. 23PCh. 41 - Prob. 24PCh. 41 - Prob. 25PCh. 41 - Prob. 26PCh. 41 - Prob. 27PCh. 41 - Prob. 28PCh. 41 - Prob. 29PCh. 41 - Prob. 30PCh. 41 - Prob. 31PCh. 41 - Prob. 32PCh. 41 - Prob. 33PCh. 41 - Prob. 34PCh. 41 - Prob. 35PCh. 41 - Prob. 36PCh. 41 - Prob. 37APCh. 41 - Prob. 39APCh. 41 - Prob. 40APCh. 41 - Prob. 41APCh. 41 - Prob. 42APCh. 41 - Prob. 44APCh. 41 - Prob. 45APCh. 41 - Prob. 46APCh. 41 - Prob. 47APCh. 41 - Prob. 49APCh. 41 - Prob. 50APCh. 41 - Prob. 51CPCh. 41 - Prob. 52CP
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- Consider hydrogen in the ground state, 100 . (a) Use the derivative to determine the radial position for which the probability density, P(r), is a maximum. (b) Use the integral concept to determine the average radial position. (This is called the expectation value of the electrons radial position.) Express your answers into terms of the Bohr radius, a0. Hint: The expectation value is the just average value, (c) Why are these values different?arrow_forwardLook up the values of the quantities in aB = h2 / 4π2 me kqe2 ,and verify that the Bohr radius aB is 0.529 x 10-10 m .arrow_forwardWhat is the average radius of the orbit of an electron in the n=2 energy level of an oxygen atom (Z=8)? Express your answer in pico-meters.arrow_forward
- a) An electron in a hydrogen atom has energy E= -3.40 eV, where the zero of energy is at the ionization threshold. In the Bohr model, what is the angular momentum of the electron? Express your result as a multiple of ħ. Ans. b) What is the deBroglie wavelength of the electron when it is in this state? Ans. c) When the electron is in this state, what is the ratio of the circumference of the orbit of the electron to the deBroglie wavelength of the electron? Ans. d) The electron makes a transition from the state with energy E= -3.40 eV to the ground state, that has energy -13.6 eV. What is the wavelength of the photon emitted during this transition? Ans.arrow_forwardHydrogen gas can be placed inside a strong magnetic field B=12T. The energy of 1s electron in hydrogen atom is 13.6 eV ( 1eV= 1.6*10 J ). a) What is a wavelength of radiation corresponding to a transition between 2p and 1s levels when magnetic field is zero? b) What is a magnetic moment of the atom with its electron initially in s state and in p state? c) What is the wavelength change for the transition from p- to s- if magnetic field is turned on?arrow_forwarda. The electron of a hydrogen atom is excited into a higher energy level from a lower energy level. A short time later the electron relaxes down to the no = 1 energy level, releasing a photon with a wavelength of 93.83 nm. Compute the quantum number of the energy level the electron relaxes from, nhi. Note: the Rydberg constant in units of wavenumbers is 109,625 cm-1 nhi =16 b. What would the wavenumber, wavelength and energy of the photon be if instead no = 1 and nhi = 4? V: 6.9121e14 x (cm-¹) λ: (nm) E: 45.8e-20 ✓ (1)arrow_forward
- Please only type answerarrow_forwardThe radial probability density of a hydrogen wavefunction in the 1s state is given by P(r) = |4rr2 (R13 (r))²| and the radial wavefunction R1s (r) = a0 , where ao is 3/2 the Bohr radius. Using the standard integral x"e - ka dx n! calculate the standard deviation in the radial position from the nucleus for the 1s state in the Hydrogen atom. Give your answer in units of the Bohr radius ao.arrow_forwardZirconium (Z = 40) has two electrons in an incomplete d subshell. (a) What are the values of n and ℓ for each electron? n = ℓ = (b) What are all possible values of m and ms? m = − to + ms = ± (c) What is the electron configuration in the ground state of zirconium? (Use the first space for entering the shorthand element of the filled inner shells, then use the remaining for the outer-shell electrons. Ex: for Manganese you would enter [Ar]3d54s2)arrow_forward
- Problem 7: The electric potential near a hydrogen atom can be modeled as the equation to the right where ao is the Bohr radius and q is the charge on the central proton. V (r) exp(- 2r/a,)(1 +a/r) Randomized Variables m = 2 n = 3 Part (a) Find an expression for the 0-component of the electric field, Eg. Numeric : A numeric value is expected and not an expression. Eg = Part (b) Find an expression for the o-component (azimuthal) of the electric field, Eo Expression : Select from the variables below to write your expression. Note that all variables may not be required. a, B, 0, a, b, c, d, g, h, j, k, m, P, S, t Part (c) What is the change in the magnitude of the electric field (in N/C) if a test point moves from the position (x = m²ao, y = 0, z = 0) to position (x = n-ao, y = 0, z = 0). Numeric : A numeric value is expected and not an expression. ΔΕ Ξarrow_forwardThe wave function for the Is state of an electron in the hydrogen atom is VIs(P) = e-p/ao where ao is the Bohr radius. The probability of finding the electron in a region W of R³ is equal to J, P(x, y, 2) dV where, in spherical coordinates, p(p) = |V1s(P)² Use integration in spherical coordinates to show that the probability of finding the electron at a distance greater than the Bohr radius is equal to 5/e = 0.677. (The Bohr radius is ao =5.3 x 10-1" m, but this value is not needed.)arrow_forwardForm factor of atomic hydrogen. For the hydrogen atom in its ground state, the number density is n(r) = (ra)¯ exp(-2r/a), where a, is the Bohr radius. Show that the form factor is fc = 16/(4 + G*a)*. %3Darrow_forward
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