Sodium bicarbonate (baking soda),
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Chapter 4 Solutions
Chemistry by OpenStax (2015-05-04)
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- The Handbook of Chemistry and Physics (http://openstaxcollege.org/l/16Handbook) gives solubilities of the following compounds in grams per 100 mL of water. Because these compounds are only slightly soluble, assume that the volume does not change on dissolution and calculate the solubility product for each. (a) BaSiF6, 0.026 g/100 mL (contains SiF62- ions) (b) Ce(IO3)4, 1.5102 g/100 mL (c) Gd2(SO4)3, 3.98 g/100 mL (d) (NH4)2PtBr6, 0.59 g/100 mL (contains PtBr62- ions)arrow_forwardAccording to the Resource Conservation and Recovery Act (RCRA), waste material is classified as toxic and must be handled as hazardous if the lead concentration exceeds 5 mg/L. By adding chloride ion, the lead ion will precipitate as PbCl2, which can be separated from the liquid portion. Once the lead has been removed, the rest of the waste can be sent to a conventional waste treatment facility. How many grams of sodium chloride must be added to 500 L of a waste solution to reduce the concentration of the Pb2+ ion from 10 to 5 mg/L?arrow_forwardYou are given four different aqueous solutions and told that they each contain NaOH, Na2CO3, NaHCO3, or a mixture of these solutes. You do some experiments and gather these data about the samples. Sample A: Phenolphthalein is colorless in the solution. Sample B: The sample was titrated with HCl until the pink color of phenolphthalein disappeared, then methyl orange was added. The solution became pink. Methyl orange changes color from pH 3.01 (red) to pH 4.4 (orange). Sample C: Equal volumes of the sample were titrated with standardized acid. Using phenolphthalein as an indicator required 15.26 mL of standardized acid to change the phenolphthalein color. The other sample required 17.90 mL for a color change using methyl orange as the indicator. Sample D: Two equal volumes of the sample were titrated with standardized HCl. Using phenolphthalein as the indicator, it took 15.00 mL of acid to reach the equivalence point; using methyl orange as the indicator required 30.00 mL HCl to achieve neutralization. Identify the solute in each of the solutions.arrow_forward
- You will often work with salts of Fe3+, Pb2+, and Al3+ in the laboratory. (All are found in nature, and all are important economically.) If you have a solution containing these three ions, each at a concentration of 0.10 M, what is the order in which their hydroxides precipitate as aqueous NaOH is slowly added to the solution?arrow_forwardCalculate the solubility in grams per 100 mL of BaF2 in a 0.10 M BaCl2 solution.arrow_forwardThe U.S. Public Health Service recommends the fluoridation of water as a means for preventing tooth decay. The recommended concentration is 1 mg F per liter. The presence of calcium ions in hard water can precipitate the added fluoride. What is the maximum molarity of calcium ions in hard water if the fluoride concentration is at the USPHS recommended level? (Ksp for CaF2 = 4.0 1011)arrow_forward
- Consider the reaction BaF2(s)+SO42(aq)BaSO4(s)+2 F(aq) (a) Calculate K for the reaction. (b) Will BaSO4 precipitate if Na2SO4 is added to a saturated solution of BaF2?arrow_forwardCH4(g) + 2 HS(g) = CS, (g) + 4 Ha(g) A reaction mixture initially contains 0.50 M CH, and 0.75 M HS. If the equilibrium concentration of H, is 0.44 M, find the equilibrium constant (K) for the reaction.arrow_forwardThe solubility product, Ksp, of PbCl2 is 1.6 × 10-5. What mass of KCl(s) must be dissolved in 150.00 mL of 1.15M Pb(NO3)2 to produce a solution that is just saturated in PbCl2?arrow_forward
- A solution contains 0.0430 M Ca2+ and 0.0990 M Ag+. If solid Na3PO4 is added to this mixture, which of the phosphate species would precipitate out of solution first? Ca3(PO4)2 O Ag3PO4 O NazPO4 When the second cation just starts to precipitate, what percentage of the first cation remains in solution?arrow_forward4. Calcium citrate is commonly used as a food additive (E333), usually as a preservative, but sometimes for flavor. The solubility of calcium citrate (Ca3(C6H5O7)2) in water is 0.105 g/L at 35°C, and its molecular weight is 498.46 g/mol. Calculate the solubility product constant for calcium citrate.arrow_forwardWhat mass of NaOHNaOH is needed to precipitate the Cd2+ ions from 30.0mL of 0.500 M Cd(NO3)2 solution?arrow_forward
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