Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 4, Problem
Would you agree to buy 1 trillion (1,000,000,000,000) gold atoms for $5? Explain why or why not. Find the current price of gold at http://money.cnn.com/data/commodities/ (1 troy ounce = 31.1 g)
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3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Show the mechanism for these reactions
Chapter 4 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 4 - What does it mean to say an equation is balanced?...Ch. 4 - Consider molecular, complete ionic, and net ionic...Ch. 4 - Balance the following equations: (a)...Ch. 4 - Balance the following equations: (a)...Ch. 4 - Write a balanced molecular equation describing...Ch. 4 - Write a balanced equation describing each of the...Ch. 4 - Colorful fireworks often involve the decomposition...Ch. 4 - Fill in the blank with a single chemical formula...Ch. 4 - Aqueous hydrogen fluoride (hydrofluoric acid) is...Ch. 4 - A novel process for obtaining magnesium from sea...
Ch. 4 - From the balanced molecular equations, write the...Ch. 4 - Use the following equations to answer the next...Ch. 4 - Indicate what type, or types, of reaction each of...Ch. 4 - Indicate what type, or types, of reaction each of...Ch. 4 - Silver can be separated from gold because silver...Ch. 4 - Determine the oxidation states of the elements in...Ch. 4 - Determine the oxidation states of the elements in...Ch. 4 - Determine the oxidation states of the elements in...Ch. 4 - Classify the following as acid-base reactions or...Ch. 4 - Identify the atoms that are oxidized and reduced,...Ch. 4 - Complete and balance the following acid-base...Ch. 4 - Complete and balance the following acid-base...Ch. 4 - Complete and balance the following...Ch. 4 - Complete and balance the following...Ch. 4 - Complete and balance the equations for the...Ch. 4 - When heated to 700—800 C, diamonds, which are pure...Ch. 4 - The military has experimented with lasers that...Ch. 4 - Write the molecular, total ionic, and net ionic...Ch. 4 - Great Lakes Chemical Company produces bromine,...Ch. 4 - In a common experiment in the general chemistry...Ch. 4 - Lithium hydroxide may be used to absorb carbon...Ch. 4 - Calcium propionate is sometimes added to bread to...Ch. 4 - Complete and balance the equations of the...Ch. 4 - Copper(II) sulfide is oxidized by molecular oxygen...Ch. 4 - Write balanced chemical equations for the...Ch. 4 - Calcium cyclamate Ca(C6H 11 NHSO3)2 is an...Ch. 4 - Complete and balance each of the following...Ch. 4 - Complete and balance each of the following...Ch. 4 - Balance each of the following equations according...Ch. 4 - Balance each of the following equations according...Ch. 4 - Balance each of the following equations according...Ch. 4 - Write the balanced equation, then outline the...Ch. 4 - Write the balanced equation, then outline the...Ch. 4 - Write the balanced equation, then outline the...Ch. 4 - Write the balanced equation, then outline the...Ch. 4 - H2 is produced by the reaction of 118.5 mL of a...Ch. 4 - Gallium chloride is formed by the reaction of 2.6...Ch. 4 - I2 is produced by the reaction of 0.4235 mol of...Ch. 4 - Silver is often extracted from ores such as...Ch. 4 - What mass of silver oxide, Ag2O, is required to...Ch. 4 - Carborundum is silicon carbide, SiC, a very hard...Ch. 4 - Automotive air bags inflate when a sample of...Ch. 4 - Urea, CO( NH2)2, is manufactured on a large scale...Ch. 4 - In an accident, a solution containing 2.5 kg of...Ch. 4 - A compact car gets 37.5 miles per gallon on the...Ch. 4 - What volume of 0.750 M hydrochloric acid solution...Ch. 4 - What volume of a 0.2089 M Kl solution contains...Ch. 4 - A mordant is a substance that combines with a dye...Ch. 4 - The toxic pigment called white lead, Pb3(OH)2(...Ch. 4 - The following quantities are placed in a...Ch. 4 - What is the limiting reactant in a reaction that...Ch. 4 - Which of the postulates of Dalton’s atomic theory...Ch. 4 - A student isolated 25 g of a compound following a...Ch. 4 - A sample of 0.53 g of carbon dioxide was obtained...Ch. 4 - Freon-12, CCl2F2, is prepared from CCl4 by...Ch. 4 - Citric acid, C6H5CH3, a component of jams,...Ch. 4 - Toluene, C6H5CH3, is oxidized by air under...Ch. 4 - In a laboratory experiment, the reaction of 3.0...Ch. 4 - Outline the steps needed to solve the following...Ch. 4 - Outline the steps needed to determine the limiting...Ch. 4 - Outline the steps needed to determine the limiting...Ch. 4 - What is the limiting reactant when 1.50 g of...Ch. 4 - Uranium can be isolated from its ores by...Ch. 4 - How many molecules of C2H4Cl2 can be prepared from...Ch. 4 - How many molecules of the sweetener saccharin can...Ch. 4 - The phosphorus pentoxide used to produce...Ch. 4 - Would you agree to buy 1 trillion...Ch. 4 - What volume of 0.0105-M HBr solution is required...Ch. 4 - Titration of a 20.0-mL sample of acid rain...Ch. 4 - What is the concentration of NaCl in a solution if...Ch. 4 - In a common medical laboratory determination of...Ch. 4 - Potatoes can be peeled commercially by soaking...Ch. 4 - A sample of gallium bromide, GaBr3, weighing 0....Ch. 4 - The principal component of mothballs is...Ch. 4 - A 0.025-g sample of a compound composed of boron...Ch. 4 - Sodium bicarbonate (baking soda), NaHCO3, can be...Ch. 4 - What volume of 0.600 M HCl is required to react...Ch. 4 - What volume of 0.08892 M HNO3 is required to react...Ch. 4 - What volume of a 0.3300-M solution of sodium...Ch. 4 - What volume of a 0.00945-M solution of potassium...Ch. 4 - A sample of solid calcium hydroxide, Ca(OH)2, is...Ch. 4 - What mass of Ca(OH)2 will react with 25.0 g of...Ch. 4 - How many milliliters of a 0.1500-M solution of KOH...Ch. 4 - Potassium acid phthalate, KNaC8H4O4, or KHP, is...Ch. 4 - The reaction of WCl6 with Al at ~400 C gives black...
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- Draw the stepwise mechanismarrow_forwardDraw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forward
- Draw stepwise mechanismarrow_forwardPart I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forward
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- Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forwardQ4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forwardProvide the correct IUPAC name for the compound shown here. Reset cis- 5- trans- ☑ 4-6- 2- 1- 3- di iso tert- tri cyclo sec- oct but hept prop hex pent yl yne ene anearrow_forward
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