Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 4, Problem 78E
Why is the H−N−H angle in NH3 smaller than the H−C−H bond angle in
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Students have asked these similar questions
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following
compounds. Please show your work. (8) SF2, CH,OH, C₂H₂
b) Based on your answers given above, list the compounds in order of their Boiling Point
from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water?
Group of answer choices
LiBr
LiI
LiF
LiCl
Chapter 4 Solutions
Chemistry Atoms First2e
Ch. 4 - Does a cation gain protons to form a positive...Ch. 4 - Iron(III) sulfate [Fe2( SO 4)3] is composed of...Ch. 4 - Which of the following atoms would be expected to...Ch. 4 - Which of the following atoms would be expected to...Ch. 4 - Predict the charge on the monatomic ions formed...Ch. 4 - Predict the charge on the monatomic ions formed...Ch. 4 - Write the electron configuration for each of the...Ch. 4 - Write the electron configuration for the monatomic...Ch. 4 - Write out the full electron configuration for each...Ch. 4 - From the labels of several commercial products,...
Ch. 4 - Why is it incorrect to speak of a molecule of...Ch. 4 - What information can you use to predict whether a...Ch. 4 - Predict which of the following compounds are ionic...Ch. 4 - Explain the difference between a nonpolar covalent...Ch. 4 - From its position in the periodic table, determine...Ch. 4 - From its position in the periodic table, determine...Ch. 4 - From their positions in the periodic able, arrange...Ch. 4 - From their positions in the periodic table,...Ch. 4 - Which atoms can bond to sulfur so as to produce a...Ch. 4 - Which is the most polar bond? (a) CC (b) CH (c) NH...Ch. 4 - Identify the more polar bond in each of the...Ch. 4 - Which of the following molecules or ions contain...Ch. 4 - Name the following compounds: (a) CsCl (b) BaO (c)...Ch. 4 - Name of the following compounds: (a) NaF (b) Rb2O...Ch. 4 - Write the formulas of the following compounds: (a)...Ch. 4 - Write the formulas of the following compounds: (a)...Ch. 4 - Write the formulas of the following compounds: (a)...Ch. 4 - Write the formulas of the following compounds: (a)...Ch. 4 - Each of the following compounds contains a metal...Ch. 4 - Each of the following compounds contains a metal...Ch. 4 - The following ionic compounds are found in common...Ch. 4 - The following ionic compounds are found in common...Ch. 4 - What are the IUPAC names of the following...Ch. 4 - Write the Lewis symbols for each of the following...Ch. 4 - Many monatomic ions are found in seawater,...Ch. 4 - Write the Lewis symbols of the ions in each of the...Ch. 4 - Iii (he Lewis structures listed here, M and X...Ch. 4 - Write the Lewis structure for the diatomic...Ch. 4 - Write Lewis structures for the following: (a) H2...Ch. 4 - Write Lewis structures for the following: (a) O2...Ch. 4 - Write Lewis structures for the following: (a) ClF3...Ch. 4 - Write Lewis structures for the following: (a) SeF6...Ch. 4 - Write Lewis structures for: (a) PO43 (b) ICl4 (c)...Ch. 4 - Correct the following statement: The bonds in...Ch. 4 - Write Lewis structures for the following molecules...Ch. 4 - Methanol, H3COH, is used as the fuel in some race...Ch. 4 - Many planets in our solar system contain organic...Ch. 4 - Carbon tetrachloride was formerly used in fire...Ch. 4 - Identify the atoms that correspond to each of the...Ch. 4 - The arrangement of atoms in several biologically...Ch. 4 - A compound with a molar mass of about 28 g/mol...Ch. 4 - A compound with a molar mass of about 42 g/mol...Ch. 4 - Two arrangements of atoms are possible for a...Ch. 4 - How are single, double, and triple bonds similar?...Ch. 4 - Write resonance forms that describe the...Ch. 4 - Write resonance forms that describe the...Ch. 4 - Write the resonance forms of ozone, Q3, the...Ch. 4 - Sodium nitrite, which has been used to preserve...Ch. 4 - In terms of the bonds present, explain why acetic...Ch. 4 - Write the Lewis structures for the following, and...Ch. 4 - Toothpastes containing sodium hydrogen carbonate...Ch. 4 - Determine the formal charge of each element in the...Ch. 4 - Determine the formal charge of each element in the...Ch. 4 - Calculate the formal charge of chlorine in the...Ch. 4 - 54. Calculate the formal charge of each element in...Ch. 4 - Draw all possible resonance structures for each of...Ch. 4 - Based on formal charge considerations, which of...Ch. 4 - Based on formal charge considerations, which of...Ch. 4 - Based on formal charge considerations, which of...Ch. 4 - Draw the structure of hydroxylamine, H3NO, and...Ch. 4 - Iodine forms a series of fluorides (listed here)....Ch. 4 - Write the Lewis structure and chemical formula of...Ch. 4 - Which of the following structures would we expect...Ch. 4 - Sulfuric acid is the industrial chemical produced...Ch. 4 - Explain why the HOH molecule is bent, whereas the...Ch. 4 - What feature of a Lewis structure can be used to...Ch. 4 - Explain the difference between electron-pair...Ch. 4 - Why is the HNH angle in NH3 smaller than the HCH...Ch. 4 - Explain how a molecule that contains polar bonds...Ch. 4 - As a general rule, MX molecules (where M...Ch. 4 - Predict the electron pair geometry and the...Ch. 4 - Identify the electron pair geometry and the...Ch. 4 - What are the electron-pair geometry and the...Ch. 4 - Predict the electron pair geometry and the...Ch. 4 - Identify the electron pair geometry and the...Ch. 4 - Predict the electron pair geometry and the...Ch. 4 - Which of the following molecules and ions contain...Ch. 4 - Which of these molecules and ions contain polar...Ch. 4 - Which of the following molecules have dipole...Ch. 4 - Identify the molecules with a dipole moment: (a)...Ch. 4 - The molecule XF3 has a dipole moment. Is X boron...Ch. 4 - The molecule XCl2 has a dipole moment. Is X...Ch. 4 - Is the Cl2BBCl2 molecule polar or nonpolar?Ch. 4 - There are three possible structures for PCl2F3...Ch. 4 - Describe the molecular structure around the...Ch. 4 - Draw the Lewis structures and predict the shape of...Ch. 4 - A molecule with the formula AB2, in which A and B...Ch. 4 - A molecule with the formula AB3, in which A and B...Ch. 4 - Draw the Lewis electron dot structures for these...Ch. 4 - What is the molecular structure of the stable form...Ch. 4 - A compound with a molar mass of about 42 g/mol...Ch. 4 - Use the simulation...Ch. 4 - Use the simulation...Ch. 4 - Use the Molecule Shape simulator...Ch. 4 - Use the Molecule Shape simulator...Ch. 4 - Use the Molecule Shape simulator...
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