Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 4, Problem 20E
Which is the most polar bond?
(a) C−C
(b) C−H
(c) N−H
(d) O−H
(e) Se−-H
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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed
a chemical structure shown below:
% Transmittance
4000
3500
3000
2500 2000
Wavenumber (cm-1)
1500
1000
(a) Explain why her proposed structure is inconsistent with the IR spectrum obtained
(b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure
and explain why it is more compatible with the obtained spectrum.
(C) what is the possible source for the fairly intense signal at
1621cm1
AE>AE₁ (Y/N)
AE=AE₁ (Y/N)
AE
Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and
gives compound A.
?
NH2
Br
Br
Propose a structural formula for compound A.
You do not have to explicitly draw H atoms.
You do not have to consider stereochemistry.
In cases where there is more than one answer, just draw one.
R3N
C14H19NO2
+ 2 R3NH*Br
A
Chapter 4 Solutions
Chemistry Atoms First2e
Ch. 4 - Does a cation gain protons to form a positive...Ch. 4 - Iron(III) sulfate [Fe2( SO 4)3] is composed of...Ch. 4 - Which of the following atoms would be expected to...Ch. 4 - Which of the following atoms would be expected to...Ch. 4 - Predict the charge on the monatomic ions formed...Ch. 4 - Predict the charge on the monatomic ions formed...Ch. 4 - Write the electron configuration for each of the...Ch. 4 - Write the electron configuration for the monatomic...Ch. 4 - Write out the full electron configuration for each...Ch. 4 - From the labels of several commercial products,...
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(a) CC (b) CH (c) NH...Ch. 4 - Identify the more polar bond in each of the...Ch. 4 - Which of the following molecules or ions contain...Ch. 4 - Name the following compounds: (a) CsCl (b) BaO (c)...Ch. 4 - Name of the following compounds: (a) NaF (b) Rb2O...Ch. 4 - Write the formulas of the following compounds: (a)...Ch. 4 - Write the formulas of the following compounds: (a)...Ch. 4 - Write the formulas of the following compounds: (a)...Ch. 4 - Write the formulas of the following compounds: (a)...Ch. 4 - Each of the following compounds contains a metal...Ch. 4 - Each of the following compounds contains a metal...Ch. 4 - The following ionic compounds are found in common...Ch. 4 - The following ionic compounds are found in common...Ch. 4 - What are the IUPAC names of the following...Ch. 4 - Write the Lewis symbols for each of the following...Ch. 4 - Many monatomic ions are found in seawater,...Ch. 4 - Write the Lewis symbols of the ions in each of the...Ch. 4 - Iii (he Lewis structures listed here, M and X...Ch. 4 - Write the Lewis structure for the diatomic...Ch. 4 - Write Lewis structures for the following: (a) H2...Ch. 4 - Write Lewis structures for the following: (a) O2...Ch. 4 - Write Lewis structures for the following: (a) ClF3...Ch. 4 - Write Lewis structures for the following: (a) SeF6...Ch. 4 - Write Lewis structures for: (a) PO43 (b) ICl4 (c)...Ch. 4 - Correct the following statement: The bonds in...Ch. 4 - Write Lewis structures for the following molecules...Ch. 4 - Methanol, H3COH, is used as the fuel in some race...Ch. 4 - Many planets in our solar system contain organic...Ch. 4 - Carbon tetrachloride was formerly used in fire...Ch. 4 - Identify the atoms that correspond to each of the...Ch. 4 - The arrangement of atoms in several biologically...Ch. 4 - A compound with a molar mass of about 28 g/mol...Ch. 4 - A compound with a molar mass of about 42 g/mol...Ch. 4 - Two arrangements of atoms are possible for a...Ch. 4 - How are single, double, and triple bonds similar?...Ch. 4 - Write resonance forms that describe the...Ch. 4 - Write resonance forms that describe the...Ch. 4 - Write the resonance forms of ozone, Q3, the...Ch. 4 - Sodium nitrite, which has been used to preserve...Ch. 4 - In terms of the bonds present, explain why acetic...Ch. 4 - Write the Lewis structures for the following, and...Ch. 4 - Toothpastes containing sodium hydrogen carbonate...Ch. 4 - Determine the formal charge of each element in the...Ch. 4 - Determine the formal charge of each element in the...Ch. 4 - Calculate the formal charge of chlorine in the...Ch. 4 - 54. Calculate the formal charge of each element in...Ch. 4 - Draw all possible resonance structures for each of...Ch. 4 - Based on formal charge considerations, which of...Ch. 4 - Based on formal charge considerations, which of...Ch. 4 - Based on formal charge considerations, which of...Ch. 4 - Draw the structure of hydroxylamine, H3NO, and...Ch. 4 - Iodine forms a series of fluorides (listed here)....Ch. 4 - Write the Lewis structure and chemical formula of...Ch. 4 - Which of the following structures would we expect...Ch. 4 - Sulfuric acid is the industrial chemical produced...Ch. 4 - Explain why the HOH molecule is bent, whereas the...Ch. 4 - What feature of a Lewis structure can be used to...Ch. 4 - Explain the difference between electron-pair...Ch. 4 - Why is the HNH angle in NH3 smaller than the HCH...Ch. 4 - Explain how a molecule that contains polar bonds...Ch. 4 - As a general rule, MX molecules (where M...Ch. 4 - Predict the electron pair geometry and the...Ch. 4 - Identify the electron pair geometry and the...Ch. 4 - What are the electron-pair geometry and the...Ch. 4 - Predict the electron pair geometry and the...Ch. 4 - Identify the electron pair geometry and the...Ch. 4 - Predict the electron pair geometry and the...Ch. 4 - Which of the following molecules and ions contain...Ch. 4 - Which of these molecules and ions contain polar...Ch. 4 - Which of the following molecules have dipole...Ch. 4 - Identify the molecules with a dipole moment: (a)...Ch. 4 - The molecule XF3 has a dipole moment. Is X boron...Ch. 4 - The molecule XCl2 has a dipole moment. Is X...Ch. 4 - Is the Cl2BBCl2 molecule polar or nonpolar?Ch. 4 - There are three possible structures for PCl2F3...Ch. 4 - Describe the molecular structure around the...Ch. 4 - Draw the Lewis structures and predict the shape of...Ch. 4 - A molecule with the formula AB2, in which A and B...Ch. 4 - A molecule with the formula AB3, in which A and B...Ch. 4 - Draw the Lewis electron dot structures for these...Ch. 4 - What is the molecular structure of the stable form...Ch. 4 - A compound with a molar mass of about 42 g/mol...Ch. 4 - Use the simulation...Ch. 4 - Use the simulation...Ch. 4 - Use the Molecule Shape simulator...Ch. 4 - Use the Molecule Shape simulator...Ch. 4 - Use the Molecule Shape simulator...
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