Study Guide/solutions Manual For Organic Chemistry

6th Edition

ISBN: 9781260475678

Author: Janice Gorzynski Smith Dr.

Publisher: McGraw-Hill Education

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Textbook Question

Chapter 4, Problem 68P

Hydrocarbons like benzene are metabolized in the body to arene oxides, which rearrange to form

phenols. This is an example of a general process in the body, in which an unwanted compound

(benzene) is converted to a more water-soluble derivative called a metabolite, so that it can be

excreted more readily from the body.

Chapter 4, Problem 68P, 4.65 Hydrocarbons like benzene are metabolized in the body to arene oxides, which rearrange to form

a. Classify each of these reactions as oxidation, reduction, or neither.

b. Explain why phenol is more water soluble than benzene. This means that phenol dissolves in urine, which is largely water, to a greater extent than benzene.

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Chapter 4, Problem 67P

Chapter 4, Problem 69P

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Chapter 4 Solutions

Study Guide/solutions Manual For Organic Chemistry

Ch. 4.1 - Prob. 1P Ch. 4.1 - Problem 4.2 Which of the following is not another...Ch. 4.1 - Problem 4.3 Draw the five constitutional isomers...Ch. 4.1 - Prob. 4P Ch. 4.1 - Prob. 5P Ch. 4.2 - Draw the five constitutional isomers that have...Ch. 4.4 - Problem 4.7 Give the IUPAC name for each...Ch. 4.4 - Give the IUPAC name for each compound. a....Ch. 4.4 - Problem 4.9 Give the structure corresponding to...Ch. 4.4 - Prob. 10P

Ch. 4.5 - Give the IUPAC name for each compound.Ch. 4.5 - Give the structure corresponding to each IUPAC...Ch. 4.8 - Arrange the following compounds in order of...Ch. 4.9 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4.9 - Prob. 15P Ch. 4.9 - Prob. 16P Ch. 4.10 - Problem 4.17 a. Draw the three staggered and...Ch. 4.10 - Problem 4.18 Rank the following conformations in...Ch. 4.10 - Problem 4.19 Consider rotation around the...Ch. 4.10 - Calculate the destabilization present in each...Ch. 4.12 - Problem 4.21 Classify the ring carbons as up or...Ch. 4.12 - Problem 4.22 Using the cyclohexane with the C’s...Ch. 4.13 - Draw a second chair conformation for each...Ch. 4.13 - Problem 4.24 Draw both conformations for and...Ch. 4.13 - Problem 4.25 Draw the structure for each compound...Ch. 4.13 - Prob. 26P Ch. 4.14 - Prob. 31P Ch. 4.14 - Prob. 32P Ch. 4.15 - Prob. 33P Ch. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 - 4.40 Draw the structure corresponding to each...Ch. 4 - 4.42 Give the IUPAC name for each compound. a....Ch. 4 - Prob. 42P Ch. 4 - 4.46 Considering rotation around the bond...Ch. 4 - 4.50 Calculate the barrier to rotation for each...Ch. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 66P Ch. 4 - 4.64 Draw the products of combustion of each...Ch. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Prob. 69P Ch. 4 - Prob. 70P Ch. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 72P Ch. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 74P Ch. 4 - Prob. 75P Ch. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...

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Solution Summary: The author explains that phenol is more water soluble than benzene.

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