Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Question
Chapter 4, Problem 4.64PAE
Interpretation Introduction
Interpretation:
To explain why oxygenated fuels increase the extent of combustion.
Concept introduction:
- The extent of reaction relates the total conversion of the reactants.
- Oxygen is required in combustion as well as a fuel.
- Incomplete combustion is typically obtained from low oxygen.
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(a) Write the chemical equation for the complete combustion of butane.
(b) Why is it not advisable to use a butane stove inside a tent?
To a test tube containing 5.0 ml of 1.00 M NaOH at 27°C in a calorimeter, 5.0 ml of 2.00 M HNO3 at the same temperature was added, the heat generated by the reaction was monitored. Which of the following is TRUE?
a.Reaction is exothermic; solution will turn pink upon addition of phenolphthalein.
b.Heat is absorbed by the system; no color change will be observed upon addition of phenolphthalein.
c.Heat is released by the system; no color change will be observed upon addition of phenolphthalein.
d.Reaction is endothermic; solution will turn pink upon addition of phenolphthalein.
4. An experiment is to be performed to determine the standard molar enthalpy of neutralization of a strong acid by a strong base. Standard school laboratory equipment and a supply of standardized 1.00 mol/L HCl and standardized 1.00 mol/L NaOH are available.
a. What equipment would be needed? List them.
b. What measurements should be taken? List them.
c. Without performing calculations, briefly describe how the resulting data should be used to obtain the standard molar enthalpy of neutralization.
d. When a class of students performed this experiment, the average of the results was -55.0 kJ/mol. The accepted value for the standard molar enthalpy of neutralization of a strong acid by a strong base is -57.7 kilojoules per mole. Briefly describe two likely sources of experimental error that could account for the result obtained by the class. Mistakes, blunders, or miscalculations are not types of experimental error.
Chapter 4 Solutions
Chemistry for Engineering Students
Ch. 4 - Describe the chemical composition of gasoline.Ch. 4 - Write balanced chemical equations for the...Ch. 4 - Prob. 3COCh. 4 - Calculate the amounts of reactants needed in a...Ch. 4 - Prob. 5COCh. 4 - Prob. 6COCh. 4 - Prob. 7COCh. 4 - 4.1 List at least two factors that make it...Ch. 4 - 4.2 What is an alkane?Ch. 4 - 4.3 Explain the difference between complete and...
Ch. 4 - 4.4 Automobile exhaust often contains traces of...Ch. 4 - 4.5 Methane, ethane, and propane are also...Ch. 4 - 4.6 Use the web to research prices of gasoline at...Ch. 4 - For the following reactions, write the ratios that...Ch. 4 - 4.8 In an experiment carried out at very low...Ch. 4 - 4.9 Sulfur, S8, combines with oxygen at elevated...Ch. 4 - 4.10 How many moles of oxygen can be obtained by...Ch. 4 - 4.11 MTBE, C5H12O, is one of the additives that...Ch. 4 - 4.12 In petroleum refining, hydrocarbons are often...Ch. 4 - 4.13 For the following reactions, determine the...Ch. 4 - 4.14 The combustion of liquid chloroethylene,...Ch. 4 - 4.15 What mass of the unknown compound is formed...Ch. 4 - 4.16 Many metals react with halogens to give metal...Ch. 4 - 4.17 Phosgene is a highly toxic gas that has been...Ch. 4 - Prob. 4.18PAECh. 4 - 4.19 How many metric tons of carbon are required...Ch. 4 - 4.20 Assuming a charcoal briquette is composed...Ch. 4 - 4.21 Ammonium nitrate, NH4NO3, will decompose...Ch. 4 - If 3.4 mol Al and 6.2 mol Fe2O3 are mixed, what is...Ch. 4 - If 8.4 moles of disilane, Si2H6, is combined with...Ch. 4 - 4.22 Generally, an excess of O2 is needed for the...Ch. 4 - 4.23 In the reaction of arsenic with bromine,...Ch. 4 - 4.24 Ammonia gas can be prepared by the reaction...Ch. 4 - 4.25 When octane is combusted with inadequate...Ch. 4 - 4.26 The equation for one of the reactions in the...Ch. 4 - 4.27 Copper reacts with sulfuric acid according to...Ch. 4 - 4.28 One of the steps in the manufacture of nitric...Ch. 4 - 4.29 When Al(OH)3 reacts with sulfuric acid, the...Ch. 4 - 4.30 Copper reacts with nitric acid via the...Ch. 4 - 4.31 How much HNO3 can be formed in the following...Ch. 4 - 4.32 Hydrogen and oxygen are reacted and the water...Ch. 4 - 4.33 Silicon carbide, an abrasive, is made by the...Ch. 4 - Prob. 4.36PAECh. 4 - Prob. 4.37PAECh. 4 - 4.36 Sometimes students in chemistry labs...Ch. 4 - 4.37 The theoretical yield and the actual yield...Ch. 4 - 4.38 A reaction that produced 4.8 mg of taxol, an...Ch. 4 - Methanol, CH3OH, is used in racing cars because it...Ch. 4 - 4.40 When iron and steam react at high...Ch. 4 - 4.41 The percentage yield of the following...Ch. 4 - 4.42 Sulfur hexafluoride is a very stable gas...Ch. 4 - 4.43 Magnesium nitride forms in a side reaction...Ch. 4 - 4.44 Industrial production of hydrogen gas uses...Ch. 4 - 4.45 If 21 g of H2S is mixed with 38 g of O2 and...Ch. 4 - 4.46 A mixture of 10.0 g of NO and 14.0 g of NO2...Ch. 4 - 4.47 Silicon carbide is, an abrasive used in the...Ch. 4 - 4.48 Elemental phosphorous is used in the...Ch. 4 - 4.49 Small quantities of hydrogen gas can be...Ch. 4 - Prob. 4.52PAECh. 4 - 4.51 What is the role of an indicator in a...Ch. 4 - 4.52 What volume of 0.812 M HCl, in milliliters,...Ch. 4 - Prob. 4.55PAECh. 4 - Prob. 4.56PAECh. 4 - Hydrazine, N2H4, is a weak base and can react with...Ch. 4 - Prob. 4.58PAECh. 4 - Prob. 4.59PAECh. 4 - Prob. 4.60PAECh. 4 - 4.59 Aluminum dissolves in HCI according to the...Ch. 4 - 4.60 Why are fuel additives used?Ch. 4 - 4.61 What is actually measured by the octane...Ch. 4 - Prob. 4.64PAECh. 4 - Prob. 4.65PAECh. 4 - 4.64 Using the web, find information about the...Ch. 4 - 4.65 Using the web, find out how lead “poisons”...Ch. 4 - Prob. 4.68PAECh. 4 - You have 0.954 g of an unknown acid, H2A, which...Ch. 4 - Prob. 4.70PAECh. 4 - 4.79 Phosphoric add (H3PO4) is important in the...Ch. 4 - 4.80 The reaction shown below is used to destroy...Ch. 4 - Prob. 4.73PAECh. 4 - One way of determining blood alcohol levels is by...Ch. 4 - Prob. 4.75PAECh. 4 - The pictures below show a molecular-scale view of...Ch. 4 - The pictures below show a molecular-scale view of...Ch. 4 - 4.84 Aluminum chloride (AlCl3) is used as a...Ch. 4 - 4.85 In the cold vulcanization of rubber, disulfur...Ch. 4 - Prob. 4.80PAECh. 4 - Prob. 4.81PAECh. 4 - 4.88 A quality control technician needs to...Ch. 4 - Prob. 4.83PAECh. 4 - 4.90 Iron metal can be refined (rom the mineral...Ch. 4 - Prob. 4.85PAECh. 4 - Prob. 4.86PAECh. 4 - 4.93 A mixture of methane (CH4) and propane (C3H8)...Ch. 4 - Prob. 4.88PAECh. 4 - Prob. 4.89PAECh. 4 - Prob. 4.90PAECh. 4 - Prob. 4.91PAECh. 4 - Prob. 4.92PAECh. 4 - Prob. 4.93PAECh. 4 - Prob. 4.94PAECh. 4 - Prob. 4.95PAECh. 4 - Prob. 4.96PAECh. 4 - Prob. 4.97PAECh. 4 - 4.104 When 2.750 g of the oxide Pb3O4 is heated to...Ch. 4 - Prob. 4.99PAECh. 4 - 4.106 An ore sample with a mass of 670 kg contains...Ch. 4 - 4.107 Existing stockpiles of the refrigerant...Ch. 4 - 4.108 Elemental analysis is sometimes carried out...Ch. 4 - Prob. 4.103PAECh. 4 - 4.110 Write the balanced chemical equation lot the...Ch. 4 - 4.111 Aluminum metal reacts with sulfuric acid to...Ch. 4 - 4.112 A metallurgical firm wishes to dispose of...
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