CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
8th Edition
ISBN: 9780135204634
Author: Robinson
Publisher: PEARSON
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Chapter 4, Problem 4.45CP
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Chapter 4 Solutions
CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2ACh. 4 - How many moles of solute are present in 125 mLof...Ch. 4 - Prob. 4.4ACh. 4 - Prob. 4.5PCh. 4 - APPLY 4.7 Sulfuric acid is normally purchased at a...Ch. 4 - Prob. 4.7PCh. 4 - Conceptual APPLY 4.9 Three different substances,...Ch. 4 - Write ne ionic equations for the following...Ch. 4 - Prob. 4.10A
Ch. 4 - Will a precipitation reaction occur when aqueous...Ch. 4 - APPLY 4.13 How might you use a precipitation...Ch. 4 - Conceptual PRACTICE 4.14 An aqueous solution...Ch. 4 - Conceptual APPLY 4.15 A solution containing the...Ch. 4 - Name the acids HI and HBrO2 .Ch. 4 - APPLY 4.17 Give likely chemical formulas...Ch. 4 - PRACTICE 4.18 Write a balanced ionic equation and...Ch. 4 - Milk of magnesia (active ingredient: magnesium...Ch. 4 - Prob. 4.19PCh. 4 - Prob. 4.20ACh. 4 - Prob. 4.21PCh. 4 - Assume that the buret contains H+ ions, the flask...Ch. 4 - PRACTICE 4.24 Assign an oxidation number to each...Ch. 4 - APPLY 4.25 Chlorine can have several different...Ch. 4 - Identify the oxidizing agent and reducing agent in...Ch. 4 - APPLY 4.27 Police often use a Breathalyzer test to...Ch. 4 - PRACTICE 4.28 Predict whether the following...Ch. 4 - Use the following reactions to arrange the...Ch. 4 - Prob. 4.29PCh. 4 - Prob. 4.30ACh. 4 - A viramin-fortified brand of a sports...Ch. 4 - The nutritional label on Power ade specifies that...Ch. 4 - Prob. 4.33PCh. 4 - One way to analyze a sports drink for the...Ch. 4 - To measure the concentration of chloride ions ina...Ch. 4 - The flavor of the first batch of Gatorade was...Ch. 4 - Prob. 4.37CPCh. 4 - Prob. 4.38CPCh. 4 - Assume that an aqueous solution Of a cation,...Ch. 4 - The following pictures represent aqueous solutions...Ch. 4 - Prob. 4.41CPCh. 4 - The concentration of an aqueous solution of NaOCl...Ch. 4 - Assume that the electrical conductivity of a...Ch. 4 - Based on the positions in the periodic table,...Ch. 4 - The following two redox reactions occur between...Ch. 4 - Prob. 4.46SPCh. 4 - How many grams of solute would you use to prepare...Ch. 4 - How many milliliters of a 0.45 M BaCl2 solution...Ch. 4 - How many milliliters of a 0.350 M KOH solution...Ch. 4 - The sterile saline solution used to rinse contact...Ch. 4 - Prob. 4.51SPCh. 4 - Copper reacts with dilute nitric acid according to...Ch. 4 - Prob. 4.53SPCh. 4 - How many grams of solute would you use to prepare...Ch. 4 - Prob. 4.55SPCh. 4 - How would you prepare 250 mL of a 0.100 M solution...Ch. 4 - Pennies minted after 1982 are mostly zinc (97.5%)...Ch. 4 - A bottle of 12.0 M hydrochloric acid has only 35.7...Ch. 4 - What is the volume of the solution that would...Ch. 4 - How would you prepare 250 mL of a 0.100 M solution...Ch. 4 - Prob. 4.61SPCh. 4 - The following aqueous solutions were tested with a...Ch. 4 - Prob. 4.63SPCh. 4 - Individual solutions of Ba(OH)2 and H2SO4 both...Ch. 4 - A solution of HCl in water conducts electricity,...Ch. 4 - Classify each of the following substances as a...Ch. 4 - Is it possible for a molecular substance to be a...Ch. 4 - What is the total molar concentration of ions in...Ch. 4 - What is the total molar concentration of ions in...Ch. 4 - Ringer’s solution, used in the treatment of burns...Ch. 4 - What is the molarity of each ion in a solution...Ch. 4 - Prob. 4.72SPCh. 4 - Prob. 4.73SPCh. 4 - Write net ionic equations for the reactions listed...Ch. 4 - Write net ionic equations for the reactions listed...Ch. 4 - Which of the following substances are likely to be...Ch. 4 - Which of the following substances are likely to be...Ch. 4 - Predict whether a precipitation reaction will...Ch. 4 - Predict whether a precipitation reaction will...Ch. 4 - hich of the following solutions will not form a...Ch. 4 - Which of the following solutions will not form a...Ch. 4 - How would you prepare the following substances by...Ch. 4 - How would you prepare the following substances by...Ch. 4 - What are the mass and the identity of the...Ch. 4 - What are the mass and the identity of the...Ch. 4 - Assume that you have an aqueous mixture of NaNO3...Ch. 4 - Assume that you have an aqueous mixture of BaCl2...Ch. 4 - Assume that you have an aqueous solution of an...Ch. 4 - Assume that you have an aqueous solution of an...Ch. 4 - How could you use a precipitation reaction to...Ch. 4 - How could you u a precipitation reaction to...Ch. 4 - The following three solutions are mixed: 100.0 mL...Ch. 4 - A 250.0 g sample of a white solid is known to be a...Ch. 4 - Assume that you are given a solution of an unknown...Ch. 4 - Why do we use a double arrow () to show the...Ch. 4 - Write balanced ionic equations for the following...Ch. 4 - Write balanced ionic equations for the following...Ch. 4 - Write balanced net ionic equations for the...Ch. 4 - Write balanced net ionic equations for the...Ch. 4 - A flask containing 450 mL of 0.500 M HBr was...Ch. 4 - The odor of skunks is caused by chemical compounds...Ch. 4 - Prob. 4.102SPCh. 4 - Prob. 4.103SPCh. 4 - How many milliliters of 1.00 M KOH must be added...Ch. 4 - How many milliliters of 2.00 M HCl must be added...Ch. 4 - If the following solutions are mixed, is the...Ch. 4 - If the following solutions are mixed, is the...Ch. 4 - Prob. 4.108SPCh. 4 - Assign oxidation numbers to each element in the...Ch. 4 - Assign oxidation numbers to each element in the...Ch. 4 - Assign oxidation numbers to each element in the...Ch. 4 - Nitrogen can have several different oxidation...Ch. 4 - Prob. 4.113SPCh. 4 - Prob. 4.114SPCh. 4 - Where in the periodic table are the most easily...Ch. 4 - In each of the following instances, tell whether...Ch. 4 - Tell for each of the following substances whether...Ch. 4 - Which element is oxidized and which is reduced in...Ch. 4 - Which element is oxidized and which is reduced in...Ch. 4 - Use the activity series of metals (Table 4.5) to...Ch. 4 - Neither strontium (Sr) nor antimony (Sb) is shown...Ch. 4 - (a) Use the following reactions to arrange the...Ch. 4 - Prob. 4.123SPCh. 4 - Iodine, I2 , reacts with aqueous thiosulfate ion...Ch. 4 - How many milliliters of 0.250MNa2S2O3 solution is...Ch. 4 - Dichromate ion, Cr2O72 reacts with aqueous...Ch. 4 - A volume of 18.72 mL of 0.1500MK2Cr2O7 solution...Ch. 4 - What is the molar concentration of As(III) in a...Ch. 4 - Standardized solutions of KBrO3 are frequently...Ch. 4 - The metal content of iron in ores can be...Ch. 4 - Prob. 4.131SPCh. 4 - Alcohol levels in blood can he determined by a...Ch. 4 - Calcium levels in blood can be determined by...Ch. 4 - Assume that you have 1.00 g of a mixture of...Ch. 4 - A compound with the formula XOCl2 , reacts with...Ch. 4 - Prob. 4.136MPCh. 4 - Some metals occur naturally in their elemental...Ch. 4 - A sample weighing 14.98 g and containing a small...Ch. 4 - The solubility of an ionic compound can be...Ch. 4 - Prob. 4.140MPCh. 4 - Prob. 4.141MPCh. 4 - Prob. 4.142MPCh. 4 - A sample of metal (M) reacted with both steam and...Ch. 4 - Prob. 4.144MPCh. 4 - Prob. 4.145MPCh. 4 - Iron content in ores can be determined by a redox...Ch. 4 - Prob. 4.147MPCh. 4 - Salicylic acid, used in the manufacture of...Ch. 4 - Compound X contains only the elements C, H, O, and...Ch. 4 - Prob. 4.150MPCh. 4 - Element M is prepared industrially by a two-step...Ch. 4 - Prob. 4.152MPCh. 4 - Four solutions are prepared and mixed in the...Ch. 4 - To 100.0 mL of a solution that contains 0.120MCr(...Ch. 4 - Sodium nitrite, NaNO2 , is frequently added to...Ch. 4 - Brass is an approximately 4:1 alloy of copper and...Ch. 4 - Prob. 4.157MPCh. 4 - Prob. 4.158MP
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- Write the net ionic equation for the reaction, if any, that occurs on mixing (a) solutions of sodium hydroxide and magnesium chloride. (b) solutions of sodium nitrate and magnesium bromide. (c) magnesium metal and a solution of hydrochloric acid to produce magnesium chloride and hydrogen. Magnesium metal reacting with HCl.arrow_forwardComplete and balance the equations for the following acid-base neutralization reactions. If water is used as a solvent, write the reactants and products as aqueous ions. In some cases, there may be more than one correct answer, depending on the amounts of reactants used. (a) Mg(OH)2(s)+HCl4(aq) (b) SO3(g)+H2O(l) (assume an excess of water and that the product dissolves) (c) SrO(s)+H2SO4(l)arrow_forwardWrite the balanced net ionic equation for the reaction that takes place when aqueous solutions of the following solutes are mixed. If no reaction is likely, explain why no reaction would be expected for that combination of solutes. l type='a'> potassium nitrate and sodium chloride calcium nitrate and sulfuric acid ammonium sulfide and lead(II) nitrate sodium carbonate and iron(III) chloride mercurous nitrate and calcium chloride silver acetate and potassium chloride i>phosphoric acid and calcium nitrate sulfuric acid and nickel(II) sulfatearrow_forward
- In each of the following cases, does a precipitation reaction occur when solutions of the two water-soluble reactants are mixed? Give the formula of any precipitate that forms, and write a balanced chemical equation for the precipitation reactions that occur. (a) sodium carbonate and copper(11) chloride (b) potassium carbonate and sodium nitrate (c) nickel(11) chloride and potassium hydroxidearrow_forwardMagnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?arrow_forward1. Sometimes a reaction can fall in more than one category. Into what category (or categories) does the reaction of Ba(OH)2(aq) + H+PO4(aq) fit? acid-base and oxidation-reduction oxidation-reduction acid-base and precipitation precipitationarrow_forward
- Xenon trioxide, XeO3, reacts with aqueous base to form the xenate anion, HXeO4. This ion reacts further with OH to form the perxenate anion, XeO64, in the following reaction: 2HXeO4(aq)+2OH(aq)XeO64(aq)+Xe(g)+O2(g)+2H2O(l) Identify the elements that are oxidized and reduced in this reaction. You will note that the equation is balanced with respect to the number of atoms on either side. Verify that the redox part of this equation is also balanced, that is, that the extents of oxidation and reduction are also equal.arrow_forwardTriiodide ions are generated in solution by the following (unbalanced) reaction in acidic solution: IO3(aq) + I(aq) I3(aq) Triiodide ion concentration is determined by titration with a sodium thiosulfate (Na2S2O3) solution. The products are iodide ion and tetrathionate ion (S4O6). a. Balance the equation for the reaction of IO3 with I ions. b. A sample of 0.6013 g of potassium iodate was dissolved in water. Hydrochloric acid and solid potassium iodide were then added. What is the minimum mass of solid KI and the minimum volume of 3.00 M HQ required to convert all of the IO3 ions to I ions? c. Write and balance the equation for the reaction of S2O32 with I3 in acidic solution. d. A 25.00-mL sample of a 0.0100 M solution of KIO. is reacted with an excess of KI. It requires 32.04 mL of Na2S2O3 solution to titrate the I3 ions present. What is the molarity of the Na2S2O3 solution? e. How would you prepare 500.0 mL of the KIO3 solution in part d using solid KIO3?arrow_forwardA 1.345-g sample of a compound of barium and oxygen was dissolved in hydrochloric acid to give a solution of barium ion, which was then precipitated with an excess of potassium chromate to give 2.012 g of barium chromate, BaCrO4. What is the formula of the compound?arrow_forward
- n general terms, what are the spectator ions in a precipitation reaction? Why are the spectator ions not included in writing the net ionic equation for a precipitation reaction? Does this mean that the spectator ions do not have to be present in the solution?arrow_forwardThe active ingredients of an antacid tablet contained only magnesium hydroxide and aluminum hydroxide. Complete neutralization of a sample of the active ingredients required 48.5 mL of 0.187 M hydrochloric acid. The chloride salts from this neutralization were obtained by evaporation of the filtrate from the titration; they weighed 0. 4200 g. What was the percentage by mass of magnesium hydroxide in the active ingredients of the antacid tablet?arrow_forward4.112 A metallurgical firm wishes to dispose of 1300 gallons of waste sulfuric acid whose molarity is 1.37 M. Before disposal, it will be reacted with calcium hydroxide (slaked lime), which costs $0.23 per pound. (a) Write the balanced chemical equation for this process. (b) Determine the cost that the firm will incur from this use of slaked lime.arrow_forward
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